An infrared spectroscopic study of the mechanism of chloromethane conversion to higher hydrocarbons on HZSM5 catalyst

Investigation of the reaction mechanism of chloromethane on ZSM5 is a new topic. In this work an in situ FTIR technique was employed to study the conversion processes of chloromethane, the active sites on HZSM5, and the desorption state of surface species. The catalytic conversion of chloromethane to higher hydrocarbons was also studied. It is demonstrated that chloromethane can be reversibly adsorbed on acidic sites of HZSM5 at room temperature. At 100°C chloromethane is irreversibly and dissociatively adsorbed on the strong acidic sites of HZSM5, on which surface methoxyl is formed as proved by infrared characteristic C-H stretchings of-CH₃ at 2960 and 2870 cm^–1. Alkoxyls are produced and adsorbed on the catalyst surface as characterized by the infrared absorption bands of -CH₂-groups at 1460 and 2930 cm^–1. At 100°C the adsorbed methoxyl and alkoxyls are the main surface species, and a small amount of aromatics might exist as detected by a characteristic absorption band at 1510 cm^–1. Between 100 and 200°C the adsorbed surface methoxyl and alkoxyls are converted to aromatics, and the occupied OH groups partially appear. At temperature higher than 300°C the adsorbed aromatics are thermally desorbed into the gas phase. Aromatics and alkanes are the main products in catalytic conversion. These results reveal that the formation of aromatics from methoxyl and alkoxyls is easier than the desorption of aromatics from HZSM5 catalyst. An alkoxyl mechanism is proposed for the conversion of chloromethane on HZSM5 based upon the experimental results and the three assumptions: (a) The primary C-C bond is formed from surface methoxyl groups via the methoxyl group polarization and C-H bond weakening, (b) The adsorbed alkoxyls are converted to aromatics via hydrogen transfer and bond rearrangement similar to the conventional carbenium ion mechanism for the aromatization of olefins and alkanes on HZSM5. The hydrogen atoms from the aromatization stimulate the desorption of alkoxyls to alkanes. (c) At temperature higher than 300°C surface reactions and desorption of adsorbed species take place simultaneously, determining the product distribution in the catalytic conversion.     

Study on phase behavior–impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network

The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties.     

A CLASS OF BAND-LIMITED CHIP WAVEFORMS FOR DS-CDMA SYSTEMS

In Direct Sequence Code Division Multiple Access （DS-CDMA） systems, the chip waveform affects the implementation, system bandwidth, envelope uniformity, eye pattern and Multiple user Access Interference （MAI）. In this paper, based on an elementary density function of a second order polynomial, a class of second order continuity pulses is proposed. From this class of pulses, we can find some members having faster decaying rate, bigger eye opening, more uniform envelope and stronger anti-MAI capability than the Nyquist waveform. The normalized-bandwidth-pulseshape-factor product, the decaying rate of the tail of the time waveform, the opening of the eye diagram, and the envelope uniformity of the second order continuity pulses are addressed in the paper that provide the basic information for the selection of the chip pulse for CDMA systems.     

海洋丝状真菌转化石油烃的研究

研究从湄洲湾海域分离的4株丝状真菌MF1，MF2，MF3，MF4的生长特性及去除油污的过程，观察在温度26℃，初始油浓度在3g/l,培养12d的过程中培养液的变化，分析培养液的pH值及原油的去除率与时间的关系，结果表明，丝状真菌去除原油的[过程是生物吸附与生物降解相结合的生物转化过程，比较革兰氏阴性细菌与丝状真菌细胞壁组成，结构，得出海洋微生物的脱油作用与其细胞壁有直接的关系。     

Exploiting 2D compressed sensing and information entropy for secure color image compression and encryption

Neural Computing and Applications - Compared to 1D compressed sensing (CS), 2D CS is more efficient for compressing the plaintext image from two directions, but security level of current 2D...     

有源电光调制式高功率瞬态电场传感器的研制

瞬态电场防护及应用技术的研究离不开瞬态电场测试系统;文中基于有源电光调制法,研制了一种高功率瞬态电场传感器;通过建立该传感器的等效电路模型,并借助CST仿真建模,分别从频域和时域角度分析了传感器的接收特性,并得到了一致的结果;最后利用脉冲噪声模拟器和吉赫兹横电磁波小室对研制的传感器性能进行了测试;结果表明:接收天线为单极子天线,天线负载采用高阻时响应电压与被测电场场强成正比;研制的传感器带宽为10kHz～314MHz,可用于纳秒级高功率瞬态电场的时域测试。     

A novel adaptive cooperative location algorithm for wireless sensor networks

To overcome the disadvantages of the location algorithm based on received signal strength indication(RSSI) in the existing wireless sensor networks(WSNs),a novel adaptive cooperative location algorithm is proposed.To tolerate some minor errors in the information of node position,a reference anchor node is employed.On the other hand,Dixon method is used to remove the outliers of RSSI,the standard deviation threshold of RSSI and the learning model are put forward to reduce the ranging error of RSSI and improve the positioning precision effectively.Simulations are run to evaluate the performance of the algorithm.The results show that the proposed algorithm offers more precise location and better stability and robustness.     

一种制做三维牙——颌骨光弹性模型的新方法

本文提出一种用“整体浇注法”制做三维牙——颌骨光弹性模型的新方法,即用价格便宜的石膏做阴模,先制出与真实牙几何相似的牙光弹性模型和模拟牙周膜的乳胶套,将它们粘接好,然后将其放入颌骨石膏阴模的适当位置,浇入环氧树脂混合液,用“二次固化法”进行固化,即可制成三维牙——颌骨整体光弹性模型。此法能保证模型与实物的严格几何相似和牙周的边界条件相似,使实验精度大大提高且工艺简单、成本低。     

基于IPv6技术的网络家电控制电路设计

随着信息技术的发展,计算机网络越来越深入平时的生产生活中,家用电器网络化已经成为一种发展趋势。本文实现一种基于IPv6技术的家电网络控制电路的硬件设计。应用该方法设计的家电系统在智能化及网络化具有较好性能。