The electronic and magnetic properties of wurtzite Mn∶CdS,Cr∶CdS and Mn∶Cr∶CdS∶ first principles calculations

In this article, density functional theory (DFT) based on generalized gradient approximation (GGA) and GGA+U, U is Hubbard term, is used to study the electronic properties of CdS doped with different dopants (Cr, Mn). The calculations are carried out for Mn-doped CdS, Cr-doped CdS, and co-doping of Mn/Cr in CdS simultaneously. It is found that hopping of electrons is possible with Cr:CdS and Mn:Cr:CdS while Mn:CdS does not allow the hopping of electrons. Moreover, double exchange interactions are observed in Cr:CdS and d-d super-exchange interactions are observed in Mn:CdS. Now the problem becomes interesting when one magnetic ion (Cr) supporting double exchange interactions and another ion (Mn) supporting d-d super-exchange interactions are doped simultaneously in the same system (CdS). The co-doped CdS is more stable even at high Curie temperature due to p-d double exchange interactions and d-d super exchange interactions. Furthermore, the Cr-3d and Mn-3d states present in-between the band gap are responsible for inner shell transitions and hence for optical properties. Therefore, the co-doped system is taken into account to enhance its applications in the field of spintronic and magneto-optical devices.     

Hydrogen production by Chlamydomonas reinhardtii in a two-stage process with and without illumination at alkaline pH

This work presents the results of a two-stage (carbon fixation and hydrogen production) experimental study for hydrogen production from microalgae using optical fiber as an internal light source. Effect of absence and presence of light on Chlamydomonas reinhardtii culture’s pH shift is also evaluated. The culture pH value is a function of light intensity; the pH in the alkaline range changes from 7.5 to 9.5 in the presence and absence of optical fiber respectively. The maximum rate of hydrogen production in the presence of exogenic glucose and optical fiber is 6 mL/L_cult/hour, which is higher than other reported values. This study has also revealed that the presence of light reduces the lag time for hydrogen production from 12 to 5 h.     

Simulating cortical networks on heterogeneous multi-GPU systems

Recent advances in neuroscientific understanding have highlighted the highly parallel computation power of the mammalian neocortex. In this paper we describe a GPGPU-accelerated implementation of an intelligent learning model inspired by the structural and functional properties of the neocortex. Furthermore, we consider two inefficiencies inherent to our initial implementation and propose software optimizations to mitigate such problems. Analysis of our application’s behavior and performance provides important insights into the GPGPU architecture, including the number of cores, the memory system, atomic operations, and the global thread scheduler. Additionally, we create a runtime profiling tool for the cortical network that proportionally distributes work across the host CPU as well as multiple GPGPUs available to the system. Using the profiling tool with these optimizations on Nvidia’s CUDA framework, we achieve up to 60× speedup over a single-threaded CPU implementation of the model.     

Controlled release of aspirin from pH‐sensitive chitosan/poly(vinyl alcohol) hydrogel

The aim of this study was to develop a cheap, pH‐sensitive enteric coating of aspirin with biocompatible polymers. A novel approach was used to develop enteric coating from chitosan (CS) and poly(vinyl alcohol) (PVA). Solutions of CS and PVA (5 : 1 mol ratio) were mixed and selectively crosslinked with tetraethoxysilane. IR analysis confirmed the presence of the incorporated components and the existence of siloxane linkages between CS and PVA. The crosslinking percentage and thermal stability increased with increasing amount of crosslinker. The response of the developed coating in different media, such as water, pH (nonbuffer and buffer), and ionic media showed hydrogel properties. All hydrogels showed low swelling in acidic and basic pH media, whereas maximum swelling was exhibited at neutral pH. This pH sensitivity of the hydrogel has been exploited as enteric coating for commercial aspirin tablets. The dissolution test of enteric‐coated aspirin tablet in simulated gastric fluid (pH 1.2) showed 7.11% aspirin release over a period of 2 h, whereas a sustained release of remaining aspirin (83.25%) was observed in simulated intestinal fluid (pH 6.8). © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Vitamin d and metabolic syndrome risk factors: evidence and mechanisms

The metabolic syndrome develops in an individual with any three of the following risk factors: obesity, diabetes, inflammation, hypertension, dyslipidemia, and thrombosis. Recent evidence suggests that vitamin D may play a role in the development of some of these risk factors. The metabolic syndrome is more common in western societies than the underdeveloped countries. Individuals in western societies usually consume a high calorie diet that lacks essential nutrients and, by virtue of being located in the northern hemisphere, they have limited sun exposures which restrict their vitamin D synthesis. Moreover, the lifestyle of these societies is considered sedentary. These dietary and environmental factors coupled with the sedentary lifestyle predispose them to metabolic syndrome risk factors. Active research revealed the role of vitamin D in the development of obesity, diabetes, inflammation, and hypertension. On the other hand, limited research has been done on the role of vitamin D in other risk factors such as dyslipidemia and thrombosis. The scientific community proposes to increase the current vitamin D fortification level in foods to reduce the risk factors of the metabolic syndrome.     

Electrical actuation and readout in a nanoelectromechanical resonator based on a laterally suspended zinc oxide nanowire

In this paper, we present experimental results describing enhanced readout of the vibratory response of a doubly clamped zinc oxide (ZnO) nanowire employing a purely electrical actuation and detection scheme. The measured response suggests that the piezoelectric and semiconducting properties of ZnO effectively enhance the motional current for electromechanical transduction. For a doubly clamped ZnO nanowire resonator with radius ~10 nm and length ~1.91 μm, a resonant frequency around 21.4 MHz is observed with a quality factor (Q) of ~358 in vacuum. A comparison with the Q obtained in air (~242) shows that these nano-scale devices may be operated in fluid as viscous damping is less significant at these length scales. Additionally, the suspended nanowire bridges show field effect transistor (FET) characteristics when the underlying silicon substrate is used as a gate electrode or using a lithographically patterned in-plane gate electrode. Moreover, the Young's modulus of ZnO nanowires is extracted from a static bending test performed on a nanowire cantilever using an AFM and the value is compared to that obtained from resonant frequency measurements of electrically addressed clamped–clamped beam nanowire resonators.     

Glycoalkaloids (α-chaconine and α-solanine) contents of selected Pakistani potato cultivars and their dietary intake assessment

Glycoalkaloids (α-solanine and α-chaconine) are naturally occurring toxic compounds in potato tuber (Solanum tuberosum L.) that cause acute intoxication in humans after their consumption. Present research was conducted to evaluate α-chaconine, α-solanine, and total glycoalkaloids (TGAs) contents in the peel and flesh portions by high-performance liquid chromatography method in selected Pakistani potato cultivars. The α-solanine content varies 45.98 ± 1.63 to 2742.60 ± 92.97 mg/100 g of dry weight (DW) in peel and from 4.01 ± 0.14 to 2466.56 ± 87.21 mg/100 g of DW in flesh. Similarly, α-chaconine content varied from 4.42 ± 0.16 to 6818.40 ± 211.07 mg/100 g of DW in potato peel and from 3.94 ± 0.14 to 475.33 ± 16.81 mg/100 g DW in flesh portion. The TGA concentration varied from 177.20 ± 6.26 to 5449.90 ± 192.68 mg/100 g of DW in peel and from 3.08 ± 0.11 to 14.69 ± 0.52 mg/100 g of DW in flesh portion of all the potato cultivars tested. All the potato cultivars contained lower concentration of TGA than the limits recommended as safe, except 2 cultivars, that is FD8-3 (2539.18 ± 89.77 mg/100 g of DW) and Cardinal (506.16 ± 17.90 mg/kg). The dietary intake assessment of potato cultivars revealed that Cardinal, FD 35-36, FD 8-3, and FD 3-9 contained higher amount of TGA in whole potato, although FD 8-3 only possessed higher content of TGA (154.93 ± 7.75) in its flesh portion rendering it unfit for human consumption. Practical Application: This paper was based on the research conducted on toxic compounds present in all possible potato cultivars in Pakistan. Actually, we quantify the toxic compounds (glycoalkaloids) of potato cultivars through HPLC and their dietary assessment. This paper revealed safety assessment and their application in food industries especially potato processing.     

Towards developing skylight design tools for thermal and energy performance of atriums in cold climates

This paper presents an analysis of the impact of selected design alternatives on the thermal and energy performance of atriums based on the methodology outlined in the accompanying paper. Computer simulation programs were used to predict the impact of the selected design alternatives on the design performance outputs of atriums. Design alternatives focused on fenestration glazing types, fenestration surface area, skylight shape, atrium type, and interaction of the atrium with its adjacent spaces. Design performance outputs, evaluated with respect to a basecase design, included seasonal solar heat gain ratio, cooling and heating peak load ratios and annual cooling, heating and total energy ratios. Design tools were developed to quantify the impact of the design alternatives on the performance outputs. The design tools were cast into two-dimensional linear relationships with the glazing U-value and SHGC ratios as independent parameters. The results for enclosed atriums showed that the annual cooling energy ratio increased at a rate of 1.196 per unit of SHGC ratio and decreased at a rate of 0.382 per unit of U-value ratio. However, the annual heating energy ratio increased at a rate of 1.954 per unit of U-value ratio and decreased at a rate of 1.081 per unit of SHGC ratio. Similar trends were also found for the three-sided and linear atriums. Pyramidal/pitched skylights increased the solar heat gain ratio by up to 25% in the heating season compared to flat skylights. The effect of the skylight shape on the annual cooling and heating energy may be positive or negative, depending on the glazing U-value and SHGC ratios and the atrium type. Atriums open to their adjacent spaces reduced the annual cooling energy ratio by up to 76% compared to closed atrium spaces. However, open atrium spaces increased the annual heating energy ratio by up to 19%.     

Distributed adaptive consensus control of Lipschitz nonlinear multi-agent systems using output feedback

This paper addresses output-feedback-based distributed adaptive consensus control of multi-agent systems having Lipschitz nonlinear dynamics. Distributed dynamic protocols are designed based on the relative outputs of neighbouring agents and the adaptive coupling weights, under which consensus is reached between the nonlinear systems for all undirected connected communication topologies. Extension to the case of Lipschitz nonlinear multi-agent systems subjected to external disturbances is further studied, and a robust adaptive fully distributed consensus protocol is suggested. By application of a decoupling technique, necessary and sufficient conditions for the existence of these consensus protocols are provided in terms of linear matrix inequalities. Finally, numerical simulation results are demonstrated to validate the effectiveness of the theoretical results.     

Data mining based job dispatching using hybrid simulation-optimization approach for shop scheduling problem

A data mining based approach to discover previously unknown priority dispatching rules for job shop scheduling problem is presented. This approach is based on seeking the knowledge that is assumed to be embedded in the efficient solutions provided by the optimization module built using tabu search. The objective is to discover the scheduling concepts using data mining and hence to obtain a set of rules capable of approximating the efficient solutions for a job shop scheduling problem (JSSP). A data mining based scheduling framework is presented and implemented for a job shop problem with maximum lateness as the scheduling objective.