Mechanical and dynamic mechanical studies of epoxy/VAc‐EHA/HMMM IPN–jute composite systems

Epoxy [50:50 mixture of Di‐Glycidyl Ether of Bis‐Phenol A (DGEBA) and Epoxidized Novolac (EPN)] was solution blended with Vinyl Acetate‐2‐ Ethylhexylacrylate (VAc‐EHA) resin in aqueous medium, in varying weight fractions, with Hexamethoxymethylmelamine (HMMM) as a crosslinker and data was compared with a control. The present work was aimed to optimize the tensile strength, dynamic mechanical strength, impact strength, and toughness by preparing a blend followed by jute composites of a semi‐ and full interpenetrating network (IPN). In control experiments epoxy alone was crosslinked (semi‐IPN), whereas the DGEBA‐EPN and VAc‐EHA/HMMM were crosslinked separately (full‐IPN), using jute as the substrate for making composites. Composites of full‐IPN systems of epoxy/VAc‐EHA system had higher moduli and UTS than the semi‐IPN systems. Dynamic mechanical study showed that full‐IPN systems have higher T_g values than semi‐IPN systems. The impact strength increases with increasing proportions of VAc‐EHA copolymer. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 958–963, 2004     

Constrained nonlinear optimization for solubility parameters of poly(lactic acid) and poly(glycolic acid)—validation and comparison

An optimization technique has been proposed to determine Hansen solubility parameters (HSP) and radius of interaction (R) of PLA and PGA; objective function to be minimized being radius of interaction (R), and the constraints being that the solvents should be within and nonsolvents outside the interaction sphere. The proposed method has been validated and found to be most reliable. The values of HSP (δ_d, δ_p, δ_h) and R for PLA have been obtained as ((18.50, 9.70, 6.00) and 10.50) (J/cc)^0.5 at 25 °C; and those of PGA as ((17.70, 6.21, 12.50) and 1.92) (J/cc)^0.5 at 80 °C. For formulating the nonlinear inequality constraints known HSP data for 20 solvents and seven nonsolvents have been used for PLA at 25 °C; similarly HSP data for three newly found solvents (phenol, m-cresol and 4-chlorophenol), and five nonsolvents have been used for PGA at 80 °C. Established methods have been used for comparison. HSP and R have been directly compared using the 3D intrinsic viscosity and classical methods. Indirectly the total solubility parameter δ has been compared with the values obtained from the intrinsic viscosity 1D approach and group contribution method using Fedors and van Krevelen correlations. The 1D approach has led to an empirical correlation for intrinsic viscosities of PLA and PGA.     

Symptotics: a framework for estimating the scalability of real-world wireless networks

We present a framework for non-asymptotic analysis of real-world multi-hop wireless networks that captures protocol overhead, congestion bottlenecks, traffic heterogeneity and other real-world concerns. The framework introduces the concept of symptotic scalability to determine the number of nodes to which a network scales, and a metric called change impact value for comparing the impact of underlying system parameters on network scalability. A key idea is to divide analysis into generic and specific parts connected via a signature—a set of governing parameters of a network scenario—such that analyzing a new network scenario reduces mainly to identifying its signature. Using this framework, we present the first closed-form symptotic scalability expressions for line, grid, clique, randomized grid and mobile topologies. We model both TDMA and 802.11, as well as unicast and broadcast traffic. We compare the analysis with discrete event simulations and show that the model provides sufficiently accurate estimates of scalability. We show how our impact analysis methodology can be used to progressively tune network features to meet a scaling requirement. We uncover several new insights, for instance, on the limited impact of reducing routing overhead, the differential nature of flooding traffic, and the effect real-world mobility on scalability. Our work is applicable to the design and deployment of real-world multi-hop wireless networks including community mesh networks, military networks, disaster relief networks and sensor networks.     

Probing properties of boron alpha-tubes by Ab Initio calculations

We investigate the properties of nanotubes obtained from recently described boron alpha-sheet, using density functional theory. Computations confirm their high stability and identify mechanical stiffness parameters. This allows one to further analyze the basic vibrations, including the radial breathing mode Raman frequency, fRBM = 210(nm/ d) cm (-1). Careful relaxation reveals the curvature-induced buckling of certain atoms off the original plane. This distortion changes the overlap of the orbitals near the Fermi level and opens up the gap in narrow tubes, rendering them semiconducting. Wider tubes with the diameter d greater, similar 1.7 nm retain original metallic character of the alpha-sheet. This combination of properties could make boron alpha-tubes (BT) an important material for electronic, bio- and chemical sensing, and optical applications.     

RoBiN: Random Access using Border Routers in Cellular Networks

Introducing Machine-to-Machine (M2M) communications over traditional 4G cellular networks make the cellular random access channel more congested and collision-prone. In order to resolve this random access congestion, we propose RoBiN - Random access using Border router in M2M cellular Networks. RoBiN proposes an architectural modification of introducing small cells, called Border Routers (BR), in cellular networks, with complete frequency reuse capability. We formulate the aforementioned challenge in terms of collision probability and system capacity. Subsequently, we propose an efficient solution for M2M communications in cellular networks. Exhaustive mathematical analysis shows that RoBiN significantly improves the random access success probability, by 50 % over existing 4G cellular systems. Simulation results on typical 4G networks corroborate our mathematical analysis and demonstrate almost 15 dB increase in Signal-to-Interference-plus-Noise Ratio (SINR) and 3 times throughput improvements over legacy 4G cellular systems. Furthermore, RoBiN also achieves 50 %?80 % improvement in collision probability over existing time alignment matching work.     

NEST: novel eMBMS scheduling technique

In order to meet the growing demand for mobile multimedia broadcast services 3GPP includes evolved multimedia broadcast and multicast (eMBMS) services in LTE systems. The high data rates, low latency and QoS provisioning makes LTE systems more suitable for mobile broadcast and multicast services than legacy wireless networks. However, the 3GPP standards has not specified any scheduling strategy for this broadcast and multicast services. In this paper, we propose a novel eMBMS scheduling technique (NEST) which focuses on reducing the average waiting time (latency) of the broadcast services offered by LTE system. This paper has twofold contributions. We proffer NEST considering two types of impatience that is user equipment (UE) departure and UE request repetition. Our proposed scheduling strategy estimates the effects originating from the departure of the mobile UEs and UE request repetition case. It intelligently combines the advantages of both flat scheduling and on-demand scheduling in such a way that the overall latency of the system is reduced. We design a suitable modeling framework to analyze the performance of the system. Simulation experiments on typical LTE systems support the performance analysis and demonstrates 10 % gains while comparing with existing eMBMS scheduling available in present LTE systems.     

Silica encapsulated Ni nanoparticles: variation of optical and magnetic properties with particle size

Ni nanoparticles embedded in SiO2 matrix were prepared by sol-gel process. The molar percentages of Ni were varied from 2 to 20% of total SiO2 present in the matrix. Transmission electron microscope (TEM) images revealed that particle sizes varied from 8.0-15.7 nm at an annealing temperature of 773 K with variation of concentration. The optical absorption spectra revealed that the surface plasmon resonance (SPR) peak in the UV region of the spectrum shifted with the particle diameter (D) from that at 247.3 nm for D = 8.0 nm to 250.7 nm for D = 15.7 nm. In hysteresis loop measurements the magnetizations (M) of the nanocomposites also increased with higher Ni content in the matrix and did not saturate in the measuring limit of the magnetic filed (H) of 4 KOe. The anhysteric curves for different samples were analyzed with the law of approach to saturation (LAS). The zero field cooled (ZFC) and field cooled (FC) magnetization measurements at 50 Oe showed increasing broadening of the ZFC curve with the higher Ni content. To calculate the average blocking temperature ((T(B a distribution of the blocking temperatures (T(B)) was assumed to initiate theoretical fittings and it was found to be increasing with the Ni concentration in the matrix.     

Use of an energy filter to improve the spatial resolution of electron backscatter diffraction

The electron backscatter diffraction (EBSD) analytical technique is invaluable for determining the crystallography of bulk alloys, thin films, and nanoparticles. However, our physical understanding of EBSD pattern generation is incomplete, which hinders our ability to push the limits of EBSD analysis. Here, by using an energy filter with better than 10 eV resolution, an improvement in the spatial resolution of the EBSD pattern was experimentally demonstrated. A signal depth of less than 15 nm for an aluminum film was achieved by controlling the cutoff energy of the energy filter. Additionally, a two‐fold improvement in the spatial resolution across a grain boundary was observed using the energy filter. SCANNING 31: 114–121, 2009. © 2009 Wiley Periodicals, Inc.     

Polymer‐induced improvements in ferroelectric liquid crystal

The chevron geometry in the SmC* phase of ferroelectric liquid crystals (FLC) has been a major obstacle in the use of FLC in displays as it results in poor electro‐optical performance. The present paper reports a novel method to overcome this problem, by doping a small amount of polymer in the FLC matrix. In addition to the improvement in smectic ordering, polymer doping is also found to be useful in improving the vital electro‐optical properties. The various electro‐optical parameters like switching time, tilt angle, contrast ratio etc. show improvement in polymer mixed guest host mixture of FLC samples. POLYM. COMPOS., 31:1776–1781, 2010. © 2010 Society of Plastics Engineers.