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41.
In this work, we investigate the system of cold spin-1 atoms in a one dimensional optical lattice in relation with squeezing and entanglement. By using the corresponding Bose-Hubbard Hamiltonian, both superfluid and Mott-insulator phases are studied by using numerical methods in the mean-field approximation. To observe the presence of entanglement, we used a squeezing measure as a criterion for quantum correlations. We further investigate the two interaction regimes, namely ferromagnetic and antiferromagnetic in the case of zero and nonzero but very small angle between the counterpropagating laser beams that form the optical lattice. States in the superfluid phase are calculated analytically by using the perturbation theory. 相似文献
42.
It is shown that the infrared irradiation decreases the content of β-carotene and lycopene carotenoids in human skin. A decrease
in the content of β-carotene and lycopene may indicate that the IR radiation, as well as the UV radiation, is capable of forming
free radicals in human skin. The investigations were performed in vivo using the technique of resonance Raman scattering developed
by us for the noninvasive determination of antioxidant potential in skin. 相似文献
43.
Gordana S. Risti? Milan S. Trtica Nebojša ?. Rom?evi? 《Applied Surface Science》2007,253(12):5233-5239
Diamond coatings were deposited by synergy of the hot filament CVD method and the pulse TEA CO2 laser, in spectroactive and spectroinactive diamond precursor atmospheres. Resulting diamond coatings are interpreted relying on evidence of scanning electron microscopy as well as microRaman spectroscopy. Thermal synergy component (hot filament) possesses an activating agent for diamond deposition, and contributes significantly to quality and extent of diamond deposition. Laser synergy component comprises a solid surface modification as well as the spectroactive gaseous atmosphere modification. Surface modification consists in changes of the diamond coating being deposited and, at the same time, in changes of the substrate surface structure. Laser modification of the spectroactive diamond precursor atmosphere means specific consumption of the precursor, which enables to skip the deposition on a defined substrate location. The resulting process of diamond coating elimination from certain, desired locations using the CO2 laser might contribute to tailoring diamond coatings for particular applications. Additionally, the substrate laser modification could be optimized by choice of a proper spectroactive precursor concentration, or by a laser radiation multiple pass through an absorbing medium. 相似文献
44.
?. Fischer 《Applied physics. B, Lasers and optics》1978,16(1):1-28
The many unusual properties of the ternary molybdenum chalcogenides of the type MMo6X8 (M=Metal, X=Chalcogen) are reviewed. Special emphasis is put on the superconducting properties like critical temperature,
critical field and the problem of coexistence of magnetism and superconductivity. 相似文献
45.
Komsta L 《Chromatographia》2011,73(7-8):721-731
The article is intended to introduce and discuss a new quantile regression method for baseline detrending of chromatographic signals. It is compared with current methods based on polynomial fitting, spline fitting, LOESS, and Whittaker smoother, each with thresholding and reweighting approach. For curve flexibility selection in existing algorithms, a new method based on skewness of the residuals is successfully applied. The computational efficiency of all approaches is also discussed. The newly introduced methods could be preferred to visible better performance and short computational time. The other algorithms behave in comparable way, and polynomial regression can be here preferred due to short computational time. 相似文献
46.
Daniela ?. Popovi? Jelena Miladinovi? Milica D. Todorovi? Milorad M. Zrili? Joseph A. Rard 《The Journal of chemical thermodynamics》2011,43(12):1877-1885
The osmotic coefficients of aqueous mixtures of KCl and K2HPO4 have been measured at T = (298.15 ± 0.01) K by the isopiestic vapor pressure method over the range of ionic strengths from (2.3700 to 11.250) mol · kg−1 using CaCl2(aq) as the reference solution. Our new experimental results were modeled with an extended form of Pitzer’s ion-interaction model equations, both with the usual mixing terms and with Scatchard’s neutral–electrolyte mixing terms, and with the Clegg–Pitzer–Brimblecombe equations based on the mole-fraction-composition scale. There is a dearth of previously published isopiestic data for mixtures containing salts of and, consequently, no previous measurements are available for comparison with the present results. The present study yields mixing parameters for these three models that are needed for modeling the thermodynamic activities of solute components of natural waters and other complex aqueous electrolyte mixtures. 相似文献
47.
Martina C. Meinke Felicia Syring Sabine Schanzer Stefan F. Haag Rüdiger Graf Manuela Loch Ingo Gersonde Norbert Groth Frank Pflücker Jürgen Lademann 《Photochemistry and photobiology》2013,89(5):1079-1084
Modern sunscreens are well suited to provide sufficient protection in the UV range because the filter substances absorb or scatter UV radiation. Although up to 50% of radicals are formed in the visible and infrared spectral range during solar radiation protection strategies are not provided in this range. Previous investigations of commercially available products have shown that in addition to physical filters, antioxidants (AO) are necessary to provide protective effects in the infrared range by neutralizing already formed radicals. In this study, the efficacy of filter substances and AO to reduce radical formation in both spectral ranges was investigated after UV/VIS or IR irradiation. Optical properties and radical protection were determined for the investigated creams. It was found that organic UV filters lower radical formation in the UV/VIS range to 35% compared to untreated skin, independent of the presence of AO. Further reduction to 14% was reached by addition of 2% physical filters, whereas physical filters alone were ineffective in the UV/VIS range due to the low concentration. In contrast, this filter type reduced radical formation in the IR range significantly to 65%; similar effects were aroused after application of AO. Sunscreens which contain organic UV filters, physical filters and AO ensure protection in the complete solar spectrum. 相似文献
48.
?. Urban D. Papou?ek S.P. Belov A.F. Krupnov M.Yu. Tretyakov Koichi Yamada G. Winnewisser 《Journal of Molecular Spectroscopy》1983,101(1):16-29
The submillimeterwave spectra of the pure inversion and inversion-rotation transitions in the ν2 excited state (79 transitons) and the diode laser spectra of the ν2 band (83 transitions) of 15NH3 have been measured. A simultaneous least squares analysis has been carried out of these data together with previously published wavenumbers of the pure inversion transitions and inversion-rotation transitions in the ground state measured by the microwave and Fourier spectroscopy, and the ν2 band transition frequencies obtained by the infrared-microwave two-photon technique. A theory of the Δk = ±3n interactions in the ground and ν2 excited states of ammonia (?. Urban, V. ?pirko, D. Papou?ek, J. Kauppinen, S. P. Belov, L. I. Gershtein, and A. F. Krupnov, J. Mol. Spectrosc.88, 274–282 (1981)) has been used in the analysis. The “smoothed” values of the ν2 band wavenumbers can be used for calibration purposes with better than 1 × 10?3 cm?1 precision. 相似文献
49.
Homogenization in finite thermoelasticity 总被引:1,自引:0,他引:1
A homogenization framework is developed for the finite thermoelasticity analysis of heterogeneous media. The approach is based on the appropriate identifications of the macroscopic density, internal energy, entropy and thermal dissipation. Thermodynamical consistency that ensures standard thermoelasticity relationships among various macroscopic quantities is enforced through the explicit enforcement of the macroscopic temperature for all evaluations of temperature dependent microscale functionals. This enforcement induces a theoretical split of the accompanying micromechanical boundary value problem into two phases where a mechanical phase imposes the macroscopic deformation and temperature on a test sample while a subsequent purely thermal phase on the resulting deformed configuration imposes the macroscopic temperature gradient. In addition to consistently recovering standard scale transition criteria within this framework, a supplementary dissipation criterion is proposed based on alternative identifications for the macroscopic temperature gradient and heat flux. In order to complete the macroscale implementation of the overall homogenization methodology, methods of determining the constitutive tangents associated with the primary macroscopic variables are discussed. Aspects of the developed framework are demonstrated by numerical investigations on model microstructures. 相似文献
50.
?. Kment I. Gregora H. Kmentová P. Novotná Z. Hubi?ka J. Krysa P. Sajdl A. Dejneka M. Brunclíková L. Jastrabík M. Hrabovsky 《Journal of Sol-Gel Science and Technology》2012,63(3):294-306
The photoinduced self-cleaning and super-hydrophilic properties of titania (TiO2) coated glasses are considered to be utilized in many applications. The photocatalytic activity of titania is inherent to the glass composition and to the deposition method. Particularly sodium ions diffused to the titania film from the substrate have tremendous impact on its crystallinity. The deposition method influences surface, structure, and the density of the film. This study aims to provide new findings regarding the mechanism of crystallization of sol?Cgel synthesized titania and its thin films deposited by means of two different methods (dip-coating and spin-coating) onto the glass substrate with a high content of sodium ions (soda-lime glass) and without sodium ions (quartz glass). The main attention is devoted to Raman spectroscopy and Raman point-to-point mapping of the films. The content and the chemical state of the sodium ions were judged using the XPS. It is shown that the dip-coating method led to dense compact material. In this case the crystallization is localized in randomly distributed centers of nucleation. Contrary the spin-coated samples embodied a web-like pattern of cracks, from which the crystallization proceeds throughout the film. Additionally SEM, AFM, XRD, GDS, UV?CVIS methods were performed to support the results. 相似文献