Origin,distribution, and alteration of asphalts at Chapopote Knoll,Southern Gulf of Mexico

Following the discovery of asphalt volcanism in the Campeche Knolls a research cruise was carried out in 2006 to unravel the nature of the asphalt deposits at Chapopote. The novel results support the concept that the asphalt deposits at the seafloor in 3000 m of water depth originate from the seepage of heavy petroleum with a density slightly greater than water. The released petroleum forms characteristic flow structures at the seafloor with surfaces that are ‘ropy’ or ‘rough’ similar to magmatic lava flows. The surface structures indicate that the viscosity of the heavy petroleum rapidly increases after extrusion due to loss of volatiles. Consequently, the heavy petroleum forms the observed asphalt deposit and solidifies. Detailed survey with a remotely operated vehicle revealed that the asphalts are subject to sequential alterations: e.g. volume reduction leading to the formation of visible cracks in the asphalt surface, followed by fragmentation of the entire deposit. While relatively fresh asphalt samples were gooey and sticky, older, fragmented pieces were found to be brittle without residual stickiness. Furthermore, there is evidence for petroleum seepage from below the asphalt deposits, leading to local up-doming and, sometimes, to whip-shaped extrusions. Extensive mapping by TV-guided tools of Chapopote Asphalt Volcano indicates that the main asphalt deposits occur at the south-western rim that borders a central, crater-like depression. The most recent asphalt deposit at Chapopote is the main asphalt field covering an area of ∼2000 m². Asphalt volcanism is distinct from oil and gas seepage previously described in the Gulf of Mexico and elsewhere because it is characterized by episodic intrusions of semi-solid hydrocarbons that spread laterally over a substantial area and produce structures with significant vertical relief. As Chapopote occurs at the crest of a salt structure it is inferred that asphalt volcanism is a secondary result of salt tectonism.     

On the linear response of tropical African climate to SST changes deduced from regional climate model simulations

Summary Previous studies have highlighted the crucial role of sea surface temperature (SST) anomalies in the tropical Atlantic region in forcing the summer monsoon rainfall over subsaharan West Africa. Understanding the physical processes, relating SST variations to changes in the amount and distribution of African rainfall, is a key factor in improving weather and climate forecasts in this highly vulnerable region. Here, we present sensitivity experiments from a regional climate model with prescribed warmer tropical SSTs, according to enhanced greenhouse conditions at the end of the 21st century. This dynamical downscaling approach provides information about the nonlinear response of the atmosphere to oceanic heating. It has been suggested that the response is at least partly accounted for by the linear theory of tropical dynamics, involving a Kelvin and Rossby wave response to a tropical heat source. We compute the major modes of the linear Matsuno-Gill model for geopotential height and horizontal wind components and project the simulated response patterns onto these linear modes, in order to evaluate to which extent the simple linear theory may explain the SST-induced climate anomalies over Africa. A multivariate Hotelling T² test is used to evaluate whether these anomalies are statistically significant. Forcing the regional climate model by warmer SSTs leads to substantial climate anomalies over tropical Africa: Rainfall is increases over the Guinea Coast region (GCR) and tropical East Africa, but decreases over the Congo Basin and the Sahel Zone (SHZ). At the 850 hPa level, a trough develops over southern West Africa and the Gulf of Guinea, and is associated with stronger surface wind convergence over the GCR. These changes in the atmospheric dynamics strongly project onto the leading modes of the linear Matsuno-Gill model at various zonal wave numbers. The corresponding atmospheric heating pattern is highly reminiscent of the simulated nonlinear model reponse. The T² test statistics reveal that the SST forcing induces a statistically significant climate anomaly over tropical Africa if the climate state vector is reduced by projecting the simulated data onto the leading 10 linear modes. It is also shown that the linear response prevails in a long-term simulation with more realistic lower and lateral boundary conditions. Thus, linear tropical dynamics are assumed to be a major physical process on the ground of the prominent SST-African rainfall relationship.     

Greenhouse-gas versus aerosol forcing and African climate response

There are many indicators that human activity may change climate conditions all around the globe through emissions of greenhouse gases. In addition, aerosol particles are emitted from various natural and anthropogenic sources. One important source of aerosols arises from biomass burning, particularly in low latitudes where shifting cultivation and land degradation lead to enhanced aerosol burden. In this study the counteracting effects of greenhouse gases and aerosols on African climate are compared using climate model experiments with fully interactive aerosols from different sources. The consideration of aerosol emissions induces a remarkable decrease in short-wave solar irradiation near the surface, especially in winter and autumn in tropical West Africa and the Congo Basin where biomass burning is mainly prevailing. This directly leads to a modification of the surface energy budget with reduced sensible heat fluxes. As a consequence, temperature decreases, compensating the strong warming signal due to enhanced trace gas concentrations. While precipitation in tropical Africa is less sensitive to the greenhouse warming, it tends to decrease, if the effect of aerosols from biomass burning is taken into account. This is partly due to the local impact of enhanced aerosol burden and partly to modifications of the large-scale monsoon circulation in the lower troposphere, usually lagging behind the season with maximum aerosol emissions. In the model equilibrium experiments, the greenhouse gas impact on temperature stands out from internal variability at various time scales from daily to decadaland the same holds for precipitation under the additional aerosol forcing. Greenhouse gases and aerosols exhibit an opposite effect on daily temperature extremes, resulting in an compensation of the individual responses under the combined forcing. In terms of precipitation, daily extreme events tend to be reduced under aerosol forcing, particularly over the tropical Atlantic and the Congo basin. These results suggest that the simulation of the multiple aerosol effects from anthropogenic sources represents an important factor in tropical climate change, hence, requiring more attention in climate modelling attempts.     

Geo-/Object-Coding for Local-Change Assessment

Missing availability of reliable and specific landscape data may pose substantial restrictions to successful exploitation of remote sensing data and fast implementation of GIS (Geo-Information Systems). The possibilities to document conditions with high spacial resolution at a given time and to review changing aspects by different disciplines represent opportunities for complex environmental programs.The article covers: geodata acquisition and processing, research, execution, and ergonomical/cognitive aspects. Application in inpenetrable terrain for research, landuse, and engineering requirements proved the feasibility especially in areas with high demand for timely, accurate, and comprehensive surveys.Airborne close-range sensing was developed to survey localities and regions. It is no competition to global-change monitoring and large area are mapping programs possible with remote sensing. Substituting only the bulk of field-work, leaving time for in-depth review in the field or in the office, the system provides a possibility to restudy points of interest.Exploitation of advanced metric cameras, specialized airborne platforms, and spatial overlay, recognition, and discrimination techniques form the backbone of the TOPOGRAMM approach. Multi-sectoral, multi-temporal, multi-spectral survey and processing methods rely basically on enlarged image scales additional to conventional aero-photogrammetry and analytic plotting. Measurements and identification, not primarily interpretation, allow to establish high-fidelity and high resolution geo-frameworks. Focussing on micro- and mesoscales, no emphasis is given to highest geometric accuracy used for geodetic surveys. Drawing near to the object allows extraction of thematical and semantical information, dimensions, and phenomelogy of objects hitherto only singularily available.

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Distribution patterns and stable carbon isotopic composition of alkanes and alkan-1-ols from plant waxes of African rain forest and savanna C3 species

Leaf wax components of terrestrial plants are an important source of biomass in the geological records of soils, lakes and marine sediments. Relevant to the emerging use of plant wax derived biomarkers as proxies for past vegetation composition this study provides key data for C₃ plants of tropical and subtropical Africa. We present analytical results for 45 savanna species and 24 rain forest plants sampled in their natural habitats. Contents and distribution patterns of long chain n-alkanes (n-C₂₅ to n-C₃₅) and n-alkan-1-ols (n-C₂₄ to n-C₃₄) as well as bulk and molecular carbon isotopic data are presented. The variations of the analysed parameters among different growth forms (herb, shrub, liana and tree) are small within the vegetation zones, whereas characteristic differences occur between the signatures of rain forest and savanna plants. Therefore, we provide averaged histogram representations for rain forest and savanna C₃ plants.The findings were compared to previously published data of typical C₄ grass waxes of tropical and subtropical Africa. Generally, trends to longer n-alkane chains and less negative carbon isotopic values are evident from rain forest over C₃ savanna to C₄ vegetation. For n-alkanols of rain forest plants the maximum of the averaged distribution pattern is between those of C₃ savanna plants and C₄ grasses. The averaged presentations for tropical and subtropical vegetation and their characteristics may constitute useful biomarker proxies for studies analysing the expansion and contraction of African vegetation zones.     

The application of caesium‐137 measurements to investigate floodplain deposition in a large semi‐arid catchment in Queensland,Australia: a low‐fallout environment

Floodplains comprise geomorphologically important sources and sinks for sediments and associated pollutants, yet the sedimentology of large dryland floodplains is not well understood. Processes occurring on such floodplains are often difficult to observe, and techniques used to investigate smaller perennial floodplains are often not practical in these environments. This study assesses the utility of ¹³⁷Cs inventory and depth‐profile techniques for determining relative amounts of floodplain sedimentation in the Fitzroy River, northeastern Australia; a 143 000 km² semi‐arid river system. Caesium‐137 inventories were calculated for floodplain and reference location bulk soil cores collected from four sites. Depth profiles of ¹³⁷Cs concentration from each floodplain site and a reference location were recorded. The areal density of ¹³⁷Cs at reference locations ranged from 13 to 978 Bq m^–2 (0–1367 Bq m^–2 at the 95% confidence interval), and the mean value ± 2 (standard error of the mean) was 436 ± 264 Bq m^–2, similar to published data from other Southern Hemisphere locations. Floodplain inventories ranged from 68 to 1142 Bq m^–2 (0–1692 Bq m^–2 at the 95% confidence interval), essentially falling within the range of reference inventory values, thus preventing calculation of erosion or deposition. Depth‐profiles of ¹³⁷Cs concentration indicate erosion at one site and over 66 cm of deposition at another since 1954. Analysis of ^239+240Pu concentrations in a depositional core substantiated the interpretation made from ¹³⁷Cs data, and depict a more tightly constrained peak in concentration. Average annual deposition rates range from 0 to 15 mm. The similarity between floodplain and reference bulk inventories does not necessarily indicate a lack of erosion or deposition, due to low ¹³⁷Cs fallout in the region and associated high measurement uncertainties, and a likely influence of gully and bank eroded sediments with no or limited adsorbed ¹³⁷Cs. In this low‐fallout environment, detailed depth‐profile data are necessary for investigating sedimentation using ¹³⁷Cs. Copyright © 2009 John Wiley & Sons, Ltd.     

Indoor Air Quality Monitoring Improving Air Quality Perception

Energy‐efficient ventilation strategies relating to good indoor air quality (IAQ) are a major task for building performance according to the requirements set by the energy performance of buildings directive (EPBD) in 2010. Applying demand‐controlled ventilation (DCV) in buildings, using sensors for IAQ control that enables variable airflow rates adapted to the actual indoor load conditions is one possibility to fulfill the requirements of adequate IAQ while reducing the energy consumption at the same time. CO₂ concentrations above outdoors are generally used as an indicator for occupancy generated indoor air pollution and corresponding ventilation rates. The objective of this study is focused on a micromachined metal oxide semiconductor gas sensor module developed for IAQ control, based on volatile organic compound (VOC) detection. The sensor output was correlated with measured CO₂ concentrations and quantified VOCs in 15 field scenarios. Energy demand and IAQ, applying the sensor module for DCV in an office, were compared to natural and time‐scheduled ventilation in the office. The study accentuates the need for DCV and proves the functionality of the sensor module for IAQ control at adequate comfort levels. Compared to time‐scheduled ventilation, 15% heating energy and 70% power consumption were saved with DCV.     

A review of calcareous nannofossil astrobiochronology encompassing the past 25 million years

This paper presents a review of (astrobiochronological) calibration of Recent to late Oligocene calcareous nannofossil datum events. Biohorizons included in the paper are those of the widely used “standard” nannofossil zonations of Martini, E. [1971. Standard Tertiary and Quaternary calcareous nannoplankton zonation. In: Farinacci, A. (Ed.), Proceedings of the Second International Conference on Planktonic Microfossils Roma. Rome, Ed. Tecnosci. vol. 2, pp. 739–785], and Okada, H., and Bukry, D. [1980. Supplementary Modification and Introduction of Code Numbers to the Low-Latitude Coccolith Biostratigraphy Zonation (Bukry, 1973, 1975). Marine Micropaleontology 51, 321–325], as well as supplementary biohorizons proposed in the literature. The biohorizons have been selected on the basis of the unambiguous taxonomy of the index taxa and their biostratigraphic usefulness. We emphasise the application of rigorous methodology in nannofossil studies which permits an evaluation of biohorizons in terms of reliability, and calibrates their potential correlatability. Astrochronological age estimates rely on the Geologic timescale developed by the ICS in 2004, with some new calibrations included. We provide an overview of the relative position of biohorizons versus the astronomically calibrated ages of magnetic reversals and reference isotope stratigraphies. Surprisingly, there are still few high-resolution quantitative biostratigraphic studies of astrochronologically tuned sections in spite of the central role of such studies in addressing fundamental problems such as the tempo and mode of plankton evolution.     

On the relationship between vegetation and climate in tropical and northern Africa

Vegetation cover is a crucial component of the Earth’s climate system but, still, our understanding of the mechanisms governing the reciprocal influence between atmosphere and vegetation is limited. In this study, we investigate the unilateral atmospheric impact on vegetation cover in tropical and northern Africa, differentiated into regions with different circulation regimes and into detailed land-cover classes. In contrast to former studies, climate predictors from a regional climate model are used as input for a multiple regression model. Climate models provide consistent data without gaps at high spatial resolution, a considerably larger set of available climate variables and the perspective to transfer the statistical relationships to future projections, e.g., in the context of anthropogenic climate change. Indeed, robust climate predictors which drive up to 70 % of observed interannual vegetation variability could be extracted from the climate model. Besides precipitation and temperature, global radiation, and relative humidity play an important role. The statistical transfer functions are plausible in terms of the affected regions and land-cover classes and draw a rather complex picture of the atmosphere–vegetation relation in Africa.     

The scarp lands of Saudi Arabia

In central Saudi Arabia, the combination of rock types and sedimentary bedding created a unique scarp landscape. The escarpments were formed during Late Miocene through Early Quaternary times. At present, cuesta formation and migration are restricted to the actual escarpments as a consequence of negligible sediment removal. The plains between the escarpments are sealed through periodically active fluvial processes and through eolian sedimentation. In this publication, the major escarpments of central Saudi Arabia are described. The interactions between tectonics, climate, and morphogenesis which created this unique landscape are reviewed.