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To understand the anaerobic degradation pathway of domestic sewage,three lab-scale upflow anaerobic sludge blanked reactors(UASB)were employed to study the degradation pathway of different particle size and the effect of temperature on this process.Under the operation conditions of the hydraulic retention time of 24 h,the MI,VSS of approximate 11200 mg· L-1 and the water temperature at 10,15 and 20℃,the overall degradation pathway of soluble fraction was characterized according to zero-order kinetics.As for the colloidal fraction(between 0.45 and 4.5 μm),the degradation processes followed a first-order kinetic,and should firstly disintegrated into soluble fraction before finally degrading.In contrast,suspended solids(bigger than 4.5 μm)degraded to soluble and colloidal fractions according to first-order kinetics,and the colloidal fraction originating from suspended solids further degraded into soluble fraction which had the same degradation kinetics as the original soluble fraction.There existed the difference of temperature effect on different fraction degradation.Under the temperature at 20,15 and 10 ℃,the first-order rate constant of suspended solids depredating into collide was 4.97,3.01 and 1.01 d-1 respectively.Whereas the degradation of collide to soluble fraction was slightly affected by the temperature change.On the other hand,the zero-order degradation rate constant of soluble fraction was 0.26,0.18 g and 0.12 gCOD · gVSS-1d-1,respectively. 相似文献
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核电站循环冷却水系统的消毒是核电水系统的研究重点.以法国丹皮尔核电站冷却塔模型为研究对象,进行一氯胺消毒剂的消耗动力学研究,确定以天然原水为循环水介质的一氯胺消耗动力学符合一级反应的动力学模型,其反应速率常数为0.002min^-1;以人工模拟投加Fe^3+进行一氯胺消耗分析表明,Fe^3+对一氯胺的消耗无显著影响. 相似文献
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臭氧化-生物活性炭技术试验研究 总被引:16,自引:0,他引:16
根据我国地表水源普遍受到污染的现状 ,通过人工配水 ,考察了臭氧化 生物活性炭与普通生物活性炭两种不同工艺的处理效果。试验结果表明 ,臭氧生物活性炭比普通生物活性炭能够更有效地去除有机物 ,其脱色、除浊能力亦优于普通生物活性炭 ,证明了臭氧化、生物氧化、活性炭吸附的三者协同作用的有效性。 相似文献
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为解决污泥减量化处理过程中药耗或能耗过高、污泥量增加等问题,提出利用污泥自身胞外聚合物(EPS)产生的自絮凝调理来促进其脱水性能,通过正交实验和单因素实验考察污泥质量浓度、搅拌强度和搅拌时间对污泥自絮凝特性的影响,分析污泥毛细吸水时间(tCST)、污泥容积指数(SVI)、污泥粒径和Zeta电位的变化规律.结果表明,自絮凝可增大污泥粒径,提高污泥疏水性,减少絮体表面Zeta电位的影响,从而改善污泥脱水性能和沉降性能.在最佳参数(污泥质量浓度18 g·L-1、搅拌强度200 r/min、搅拌时间3.5 min)条件下,自絮凝后污泥体积平均粒径增加11.4%,Zeta电位升高19.0%,tCST降低17.1%,SVI降低8.1%,效果显著.所考察的因素对自絮凝作用的影响程度依次为:污泥质量浓度搅拌时间搅拌强度.较高的污泥质量浓度、搅拌强度和搅拌时间均有利于提高自絮凝效果,而当污泥质量浓度、搅拌强度或搅拌时间大于最佳参数时,自絮凝效果则逐渐减弱.研究成果提供了利用污泥自身特性进行调理的新思路,可为优化污泥调理方式、降低调理药耗和减少污泥产量提供技术支持. 相似文献