New inorganic–organic proton conducting membranes based on Nafion and [(ZrO2)·(SiO2)0.67] nanoparticles: Synthesis vibrational studies and conductivity

In this report is described the preparation of six nanocomposite membranes of formula {Nafion/_[(ZrO_2)⋅(SiO_2)0.67]ΨZrO₂}$\{\text{Nafion}/{[(\text{Zr}{\text{O}}_2)\cdot {(\text{Si}{\text{O}}_2)}_{0.67}]}_{{\Psi }_{\text{Zr}{\text{O}}_2}}\}$ with ΨZrO₂${\Psi }_{\text{Zr}{\text{O}}_2}$ ranging from 0 to 1.79 based on Nafion^® and [(ZrO₂)·(SiO₂)_0.67] nanofiller. Morphology investigations carried out by SEM measurements indicate that the composition of membranes is asymmetric. Indeed, with respect to the direction of the films after casting procedure, the top side (A-side) and bottom side (B-side) present a different nanofiller concentration. The concentration of nanofiller increases gradually from A to B side. The membranes present thicknesses ranging from 170 to 350 nm and are studied by FT-IR ATR and micro-Raman measurements.     

Slurry sampling in serum blood for mercury determination by CV-AFS

The heavy metal mercury (Hg) is a neurotoxin known to have a serious health impact even at relatively low concentrations. A slurry method was developed for the sensitive and precise determination of mercury in human serum blood samples by cold vapor generation coupled to atomic fluorescence spectrometry (CV-AFS). All variables related to the slurry formation were studied. The optimal hydrochloric concentration and tin(II) chloride concentration for CV generation were evaluated. Calibration within the range 0.1-10 microg L(-1) Hg was performed with the standard addition method, and compared with an external calibration. Additionally, the reliability of the results obtained was evaluated by analyzing mercury in the same samples, but submitted to microwave-assisted digestion method. The limit of detection was calculated as 25 ng L(-1) and the relative standard deviation was 3.9% at levels around of 0.4 microg L(-1)Hg.     

A flexible framework for evaluating user and item fairness in recommender systems

User Modeling and User-Adapted Interaction - One common characteristic of research works focused on fairness evaluation (in machine learning) is that they call for some form of parity (equality)...     

Medieval glazed ceramic from Caesar's Forum (Rome,Italy): Production technology

This study is focused on Medieval Roman heavy lead-glazed ceramics from the archaeological site of the Caesar's Forum (Rome, Italy), dated from the 10th and not beyond the first decades of the 11th century. Optical microscopy (OM), X-ray powder diffraction (XRPD), scanning electron microscopy (SEM-EDS) and electron microprobe analysis (EMPA) have been used for the archaeometric characterization of the ceramics. Petrographic analysis of the body indicated the occurrence of three petro-fabrics, mainly composed by abundant quartz, feldspars, nodules of iron oxides, rare fragments of siliceous rocks, very rare fragments of calcareous rocks, pyroxene, biotite and olivine. This mineralogical assemblage suggests that the ceramics were fired in the range 950–1050 °C, under oxidizing conditions. SEM and EMP analysis show that the ceramic body was produced with non-or moderately calcareous clays and the heavy glaze with lead oxide, silica, alumina and alkalis. The microstructure of the glaze and the relationship with the body suggest that for the production of the ceramic repertoire of the Caesar's Forum either the single or the double firing techniques were used.     

A heterogeneous and reconfigurable machine-vision system

This paper describes a new machine-vision system, a HERMIA heterogeneous and reconfigurable machine for image analysis. The architecture topology of the HERMIA machine is reconfigurable; moreover, the integration of its special modules allows a search for optimal strategies to solve vision problems. The general architecture and the hardware implementation are described. The software environment of the HERMIA machine provides a full iconic interface and a pictorial language oriented to vision in multiprocessor architectures. The preliminary system evaluation and applications are shown.     

Oxidation of ethyl alcohol in trickle bed reactors: Analysis of the conversion rate

The interpretation of results of a chemical reaction carried out in a trickle bed reactor is not immediate when the key reactants are volatile; in fact some authors state that the overall conversion rate increases at very low liquid flow rates, i.e. when the catalyst is unevenly wetted. In these conditions, the reactants may penetrate inside the catalyst pellets directly through the “dry” zones; therefore the mass transfer resistance is diminished and the conversion rate can be increased. To investigate this phenomenon tests on the catalytic oxidation of ethyl alcohol dissolved in water were performed at different operating conditions in a trickle bed reactor. An interpretation of the results was tried by using two different models based on partially wetted particles. This approach considers both the cases in which “dry” zones are active or not for mass transfer and mass transfer rates are affected or not by the chemical reaction.     

Near-recursive optical flow from weighted image differences.

This correspondence derives a formal link between temporally weighted frame differences, or disturbance fields, which carry limited information suitable for motion detection, and the optic flow (OF), which carries richer information on local image motion. We use this link to derive a novel, simple, near-recursive optic flow algorithm based on a recursive-filter formulation. Most quantities involved are computed recursively, using only data from the current and previous frame. We can limit expensive OF calculations to pixels where motion magnitude is sufficiently high using image differences which the algorithm computes anyway. Experimental results with well-known synthetic, ground-truthed test sequences and standard performance metrics indicate good quantitative performance. Tests with real sequences suggest similar or better performance than a well-known, similar algorithm due to Lucas and Kanade (LK).     

Surface Instability and Chemical Reactivity of ZrSiS and ZrSiSe Nodal‐Line Semimetals

Materials exhibiting nodal‐line fermions promise superb impact on technology for the prospect of dissipationless spintronic devices. Among nodal‐line semimetals, the ZrSiX (X = S, Se, Te) class is the most suitable candidate for such applications. However, the surface chemical reactivity of ZrSiS and ZrSiSe has not been explored yet. Here, by combining different surface‐science tools and density functional theory, it is demonstrated that the formation of ZrSiS and ZrSiSe surfaces by cleavage is accompanied by the washing up of the exotic topological bands, giving rise to the nodal line. Moreover, while the ZrSiS has a termination layer with both Zr and S atoms, in the ZrSiSe surface, reconstruction occurs with the appearance of Si surface atoms, which is particularly prone to oxidation. It is demonstrated that the chemical activity of ZrSiX compounds is mostly determined by the interaction of the Si layer with the ZrX sublayer. A suitable encapsulation for ZrSiX should not only preserve their surfaces from interaction with oxidative species, but also provide a saturation of dangling bonds with minimal distortion of the surface.     

Surface Reconstruction,Oxidation Mechanism,and Stability of Cd3As2

Cadmium arsenide (Cd₃As₂) has recently attracted considerable interest for the presence of 3D massless Dirac fermions with ultrahigh mobility and magnetoresistance. However, its surface properties are currently largely unexplored both theoretically and experimentally, due to the very large unit cell and the challenging growth of single‐crystal samples, respectively. Here, by combining ab initio calculations with surface‐science spectroscopic experiments, the presence of a surface reconstruction is unveiled in centimeter‐scale (112)‐oriented Cd₃As₂ single‐crystal foils produced by the self‐selecting vapor growth. Outermost Cd atoms descend into the As‐sublayer with a subsequent self‐passivation of the dangling bonds with As atoms, forming the triangle lattice previously imaged by scanning tunneling microscopy. Moreover, the oxidation mechanism of this reconstructed surface, dominated by the formation of As? O? Cd bonds, is revealed. Interestingly, it is found that the band structure of the reconstructed surface of Cd₃As₂ is quite robust against surface oxidation. Both computational and experimental findings point to a successful exploitation in technology of Cd₃As₂ single crystals.