Copper Assisted Inverted Pyramids Texturization of Monocrystalline Silicon in a Nitrogen Bubbling Bath for Highly Efficient Light Trapping

Silicon - Inverted pyramid (IP) texturization on silicon wafers has recently attracted attention for the structure’s light trapping ability and low specific surface area. The later property...     

Accuracy test of five-axis CNC machine tool with 3D probe–ball. Part I: design and modeling

The error model of CNC machine tool describes the relationship between the individual error source and its effects on the overall position errors. A practical problem in applying this technique to five-axis machine tool is that the predicted position errors cannot be justified. This paper, the first in a set of two, presents a new measurement device, the probe–ball, which can be used to measure the overall position errors of five-axis machine tools directly. To perform the accuracy test, a three-degree-of-freedom (3D) measuring probe is installed in the main spindle and a base plate is fixed on the turntable. The kinematic chain of the five-axis machine tool is then closed through connecting the central ball on the base plate with the extension bar of the probe. To generate simultaneous axes motion under the condition of closed kinematic chain, the central ball is defined as origin of the workpiece coordinate frame and the probe is driven along a path on a spherical test surface with the central ball as center. The overall position errors are measured with the 3D measuring probe. A theoretical model is derived to explain the nature of the probe–ball error measurements.     

THERMODYNAMICS OF MARTENSITIC TRANSPORMATION IN β-Cu BASE ALLOYS

提出对β-Cu基合金热弹性马氏体相变的热力学处理。计算了Cu-Zn,Cu-Al及Cu-Zn-Al合金马氏体相变驱动力,T_0温度及M_s温度,M_s的计算值与实验值符合很好。母相有序降低Cu-Zn和Cu-Zn-Al的M_s,但升高Cu-Al的M_s(T_0)。并简介了两种估算非化学自由能的方法。     

Antiplatelet Effect and Selective Binding to Cyclooxygenase (COX) by Molecular Docking Analysis of Flavonoids and Lignans

The known flavonoids ginkgetin (1), taiwanhomoflavone A (2), taiwanhomoflavone B (3), and taiwanhomoflavone C (4) and eight known lignans: justicidin B (9), justicidin C (10), justicidin D (11), chinensinaphthol methyl ether (12), procumphthalide A (13), procumbenoside A (15), and ciliatosides A (16) and B (17) were isolated from Cephalotaxus wilsoniana and Justicia species, respectively. The antiplatelet effects of the above constituents on human platelet-rich plasma (PRP) were evaluated. Of the compounds tested on human PRP, compounds 1, 4, 9, and 11 showed inhibition of secondary aggregation induced by adrenaline. Compound 1 had an inhibitory effect on cyclooxygenase-1 (COX-1). Molecular docking studies revealed that 1 and the related compounds apigenin (5), cycloheterophyllin (6), broussoflavone F (7), and quercetin (8) were docked near the gate of active site of COX-1. It indicated that the antiplatelet effect of 1, 4, 9, and 11 is partially owed to suppression of COX-1 activity and reduced thromboxane formation. Flavonoids, 1, 5, 6, 7, and 8 may block the gate of the active site of COX-1 and interfere the conversion of arachidonic acid to prostaglandin (PG) H₂ in the COX-1 active site.     

Bending-beam measurement of solvent diffusions in polyimides: Theoretical and experimental

A general formula correlating the bending curvature variation ratio of a layered structure caused by solvent-induced swelling in its polymer overcoat with diffusion time under case II diffusion has been presented. In the event of case II diffusion, the diffusion front velocity, v, can be calculated by using this formula and measured by a bending-beam apparatus. At room temperature, the diffusion of n-methyl-pyrrolidone (NMP) solvent in the film of pyromellitic phenylene diamine (PMDA-PDA) is case II. While in PMDA-B (-benzidine) and benzophenone tetracarboxylic dianhydride (BPDA-PDA), no diffusion progress can be observed. But, the diffusion in 6F-dianhydride- (6FDA-PDA) is case I with D = 0.85 × 10^?9 cm²/s. It becomes anomalous when mixing with 25% PMDA-B, but becomes case II diffusion with more PMDA-B. The preabsorbed moisture in the films does not affect the v value. In PMDA-PDA, v = 7.3 × 10^?8 cm/s. In the 25/75 and 50/50 6FDA-PDA/PMDA-B blends, v = 6.3 and 11.3 × 10^?8 cm/s.     

Measuring individual corrective reaction time using the intermittent illumination model

The corrective reaction time (t_cr) is an essential motor property when modelling hand control movements. Many studies designed experiments to estimate t_cr, but reported only group means with inconsistent definitions. This study proposes an alternative methodology using Drury's (1994) intermittent illumination model. A total of 24 participants performed circular tracking movements under five levels of visual information delay using a modified monitor in a darkened room. Measured movement speeds and the manipulated delays were used with the model to estimate t_cr of individuals and test effects of gender and path width. The results showed excellent model fits and demonstrated individual differences of t_cr, which was 273 ms on average and ranged from 87 to 441 ms. The wide range of t_cr values was due to significant effects of gender and path width. Male participants required shorter t_cr compared to female participants, especially for narrow path widths.     

A novel microneedle array for the treatment of hydrocephalus

We present a microfabricated 10 by 10 array of microneedles for the treatment of a neurological disease called communicating hydrocephalus. Together with the previously reported microvalve array, the current implantable microneedle array completes the microfabricated arachnoid granulations (MAGs) that mimic the function of normal arachnoid granulations. The microneedle array was designed to enable the fixation of the MAGs through dura mater membrane in the brain and thus provide a conduit for the flow of cerebrospinal fluid. Cone-shaped microneedles with hollow channels were fabricated using a series of microfabrication techniques: SU-8 photolithography for tapered geometry, reactive ion etching for sharpening the microneedles, 248 nm deep UV excimer laser machining for creating through-hole inside the microneedles, and metal sputtering for improved rigidity. Puncture tests were conducted using porcine dura mater and the results showed that the fabricated microneedle array is strong enough to pierce the dura mater. The in vitro biocompatibility test result showed that none of the 100 outlets of the microneedles exposed to the bloodstream were clogged significantly by blood cells. We believe that these test results demonstrate the potential use of the microneedle array as a new treatment of hydrocephalus.     

Synthesis and characterization of novel polyesterimides

A series of soluble novel polyesterimides was synthesized from diamines [a mixture of 2,2‐bis(4‐(4‐aminophenoxy)phenyl)propane (BAPP) with amine‐terminated polysiloxane (ATPS) in various mole ratios] and the ester‐group‐containing dianhydrides. The ester group containing dianhydrides in turn was synthesized by the transesterification reaction of trimellitic anhydride (TMA) with diacetate ester of hydroquinone (HQ), 4,4′‐dihydrophenyl (BP), 1,6‐hexanediol, or ethylene glycol. The resulted polyesterimides were characterized by using Fourier‐transform infrared spectroscopy, inherent viscosity, solubility, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The polyesterimides of BP and HQ had relatively high glass transition temperatures in the range of 214.7–227.2 and 195.7–210.5°C, respectively. The glass transitions decreased rather slowly with the increase in polysiloxane content. Thermal stability and the weight‐loss behavior of polyesterimides were studied by TGA. All polyesterimides of BP and HQ (BPI and HQI) showed no significant weight loss below 500°C in a N₂ environment, and the decomposition temperatures (T_d5%) of BPI and HQI were >520°C. Most polyesterimides were soluble in polar aprotic solvents and m‐cresol. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 730–738, 2004     

Competitive online adaptive scheduling for sets of parallel jobs with fairness and efficiency

We study online adaptive scheduling for multiple sets of parallel jobs, where each set may contain one or more jobs with time-varying parallelism. This two-level scheduling scenario arises naturally when multiple parallel applications are submitted by different users or user groups in large parallel systems, where both user-level fairness and system-wide efficiency are of important concerns. To achieve fairness, we use the well-known equi-partitioning algorithm to distribute the available processors among the active job sets at any time. For efficiency, we apply a feedback-driven adaptive scheduler that periodically adjusts the processor allocations within each set by consciously exploiting the jobs’ execution history. We show that our algorithm achieves asymptotically competitive performance with respect to the set response time, which incorporates two widely used performance metrics, namely, total response time and makespan, as special cases. Both theoretical analysis and simulation results demonstrate that our algorithm improves upon an existing scheduler that provides only fairness but lacks efficiency. Furthermore, we provide a generalized framework for analyzing a family of scheduling algorithms based on feedback-driven policies with provable efficiency. Finally, we consider an extended multi-level hierarchical scheduling model and present a fair and efficient solution that effectively reduces the problem to the two-level model.     

Correlation between crystallization kinetics and melt phase behavior of crystalline-amorphous block copolymer/homopolymer blends

We show that the phase behavior of the strongly segregated blend consisting of a crystalline-amorphous diblock copolymer (C-b-A) and an amorphous homopolymer (h-A), which depends on the degree of wetting of A blocks by h-A, can be probed by the crystallization kinetics of the C block. A lamellae-forming poly(ethylene oxide)-block-polybutadiene (PEO-b-PB) was blended with PB homopolymers (h-PB) of different molecular weights to yield the blends exhibiting ‘wet brush’, ‘partially dry brush’, and ‘dry brush’ phase behavior in the melt state. The crystallization rate of the PEO blocks upon subsequent cooling, as manifested by the freezing (crystallization) temperature (T_f), was highly sensitive to the morphology and spatial connectivity of the microdomains governed by the degree of wetting of PB blocks. As the weight fraction of h-PB reached 0.48, for instance, T_f experienced an abrupt rise as the system entered from the wet-brush to the dry-brush regime, because the crystallization in the PEO cylindrical domains in the former required very large undercooling due to a homogeneous nucleation-controlled mechanism while the process could occur at the normal undercooling in the latter since PEO domains retained lamellar identity with extended spatial connectivity. Our results demonstrate that as long as the C block is present as the minor constituent the melt phase behavior of C-b-A/h-A blends can also be probed using a simple cooling experiment operated under differential scanning calorimetry (DSC).