Electrokinetic and antibacterial properties of needle like‐TiO2/polyrhodanine core/shell hybrid nanostructures

The aim of this study was to fabricate needle like‐TiO₂/polyrhodanine nanostructures by polymerizing rhodanine monomer on the TiO₂ nanoparticles' surfaces and investigate their antibacterial activities. The structural, thermal, morphological, surface and electrical properties of non‐covalently functionalized nanoparticles were characterized by using FTIR, XPS, elemental analysis, TGA, XRD, SEM‐EDX, TEM, contact angle, and conductivity measurements. Characterization results confirmed the formation of needle like‐TiO₂/polyrhodanine (PRh) core/shell hybrid nanostructures. Alterations on the surface and electrokinetic properties of the materials were characterized by zeta (ζ)‐potential measurements with the presence of various salts and surfactants. The ζ‐potential of needle like‐TiO₂ was observed to increase from ?7.6 mV to +28.4 mV after forming a core/shell needle like‐TiO₂/PRh nanocomposite structure and with the presence of cetyltrimethyl ammonium bromide (CTAB) surfactant. Thereby colloidally more stable dispersions were formed. Antibacterial properties of needle like‐TiO₂/PRh were also tested against Staphylococcus aureus, Klebsiella pneumoniae, and Escherichia coli by various methods and they showed good antibacterial activity. The highest killing efficiency was determined for needle like‐TiO₂/PRh against E. coli by colony‐counting method as 0.95. TEM experiments also showed the immobilizations of the nanoparticles on E. coli and revealed the interactions between E. coli and the nanoparticles. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41554.     

Synthesis and characterization of polypropiolate sodium (PPNa)-Fe3O4 nanocomposite

Polypropiolate sodium (PPNa)-Fe₃O₄ nanocomposites were successfully synthesized by the precipitation of Fe₃O₄ in the presence of sodium polypropiolate and followed by reflux route. Structural, morphological, electrical and magnetic properties evaluation of the nanocomposite were performed by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), vibrating scanning magnetometry (VSM) and conductivity measurements. Crystalline phase was identified as magnetite with an average crystallite size of 7 ± 3 nm as estimated from X-ray line profile fitting. Particle size estimated from TEM, by log-normal fitting, is ∼9 ± 1 nm. FT-IR analysis shows that the binding of PPNa on the surface of iron oxide is through bidentate linkage of carboxyl group. TGA analysis showed the presence of 20% PPNa around 80% magnetic core (Fe₃O₄)…PPNa-Fe₃O₄ nanocomposite show superparamagnetic characteristics at room temperature. It is found that the a.c. conductivity of the nanocomposites obeys the well-known power law of frequency in which it also depends on temperature. Additionally, its d.c. conductivity showed that two operating regions of the activation energy. Both real and imaginary parts of either permittivity exhibit almost the same attitudes which are the indication of the same ability in the stored energy, and dissipation of energy within the PPNa and PPNa-Fe₃O₄ nanocomposites.     

A team-oriented design methodology for mixed model assembly systems

Team-oriented approaches are widely being used in modern real life assembly systems, as are other modern systems. In this paper, first the literature of single and mixed model assembly line balancing, which plays an important role for the design of assembly systems, is reviewed. The associated literature matrixes reveal that team-oriented approaches do not have an intensive research area. Second, a team-oriented mathematical programming model for creating assembly teams (physical stations) in mixed model assembly lines is devised. Owing to the fact that this model is NP hard, a scheduling based heuristic algorithm is developed. The mixed model assembly line design methodology, which includes a team-oriented algorithm as a step, is proposed. Both model sequencing and worker transfer systems are included in the methodology. The algorithms for each step of the methodology are also coded by using MATLAB and MS Excel is used as the user interface. Furthermore, the presented methodology was applied in a chosen segment of a real life mixed model tractor assembly system.     

A randomized prospective trial comparing 45 and 90-ml oral sodium phosphate with X-Prep in the preparation of patients for colonoscopy

Incontinentia pigmenti is an uncommon genodermatosis that occurs in female infants. The characteristic dental defects are partial anodontia and the presence of some peg-shaped teeth. This report describes a patient with incontinentia pigmenti who exhibited multiple missing teeth in both arches. The patient had malpositioned teeth and decreased occlusal vertical dimension associated with the missing teeth. Orthodontic treatment was required for prosthetic purposes. The dental anomalies of incontinentia pigmenti and the treatment procedure are presented.     

A dwell time approach to the stability of switched linear systems based on the distance between eigenvector sets

In this article, a sufficient condition on the minimum dwell time that guarantees the stability of switched linear systems is given. The proposed method interprets the stability of switched linear systems through the distance between the eigenvector sets of subsystem matrices. Thus, an explicit relation in view of stability is obtained between the family of the involved subsytems and the set of admissible switching signals.     

Modeling of heat and mass transfer in accelerator targets during postulated accidents

The modeling of thermal-chemical behavior of targets used in accelerator applications is an important part of safety analysis. Tungsten is considered as a target material to produce tritium in a linear proton accelerator. The prediction of the chemical reactivity of tungsten in a steam flow at high temperatures is the most important part of a safety analysis of target design. The oxidation and volatilization of tungsten in steam at high temperatures is a complex phenomenon that involves various mechanisms (depending on the temperature), steam pressure, and steam velocity. A simple diffusion model that considers chemical equilibrium at the reaction interface and effective diffusion thickness, including the boundary and oxide layers, is proposed for predicting the volatilization rate. The proposed simple model predicts the available data reasonably well. The proposed model is implemented into a computer program that is developed to predict the radiological releases during postulated loss-of-coolant accidents (LOCAs). The computer program models heat production, heat transfer, and oxidation reactions in the multiple radiation enclosures representing the accelerator target elements. It treats each element of the radiation enclosures as a lumped control volume, or heat structure. Each heat structure may generate or lose heat by conduction, convection, or radiation and is subject to mass loss as a result of oxidation, melting, and volatilization. Postulated beyond-design-basis LOCAs are simulated with this computer program for the accelerator-production-of-tritium target. Sample calculations demonstrate oxidation/volatilization model capabilities and sensitivity to the assumptions selected.     

Evaluation of Disturbance Weighting Parameter of Minimax Attenuation Problems

Abstract:   This article presents a simple evaluation of the disturbance weighting parameter of well-known minimax disturbance attenuation problems derived for earthquake-excited structures. It is concluded from a careful analysis of the derived closed form solutions that linear quadratic regulator (LQR) performance which corresponds to white noise assumption is the best performance of the sub-optimal minimax control (OMC) although it is also the worst performance of the OMC and the disturbance weighting parameter is as a measure of the system stability. For the completeness of the article, OMC is also compared to LQR and unimplementable optimal control.