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991.
Jaime S. Valente Francisco Tzompantzi Julia Prince Jose G.H. Cortez Ricardo Gomez 《Applied catalysis. B, Environmental》2009,90(3-4):330-338
Mg–Zn–Al layered double hydroxides (LDHs) with varying amounts of zinc were prepared by the coprecipitation method. Solids were analyzed by XRD and N2 physisorption, confirming the formation of pure LDH phase; and the production of mixed oxides with high specific surface areas (182–276 m2 g−1) after calcination. Band gap energy was also determined, presenting the expected decreasing tendency on increasing zinc amounts. These mixed oxides were tested both for the adsorption of 2,4 dichlorophenoxiacetic acid (2,4-d) and for the photocatalytic degradation of 2,4-d and phenol. Nearly total (97%) degradation of initial 1.45 mmol L−1 of 2,4-d, with 1 g calcined LDH per liter, was accomplished in 9 h, while phenol half-life was as short as 3.5 h, with the catalyst with lowest zinc amount (5 wt.%). Langmuir adsorption isotherms are presented. Solids were also characterized by XRD and FTIR analysis after photocatalytic and adsorption activity, to determine the presence of 2,4-d. The versatility of LDH decomposition products in the elimination of different contaminants by different mechanisms puts them forward as a viable alternative for environmental remediation. 相似文献
992.
Castro FJ Pollo C Meuli R Maeder P Cuisenaire O Cuadra MB Villemure JG Thiran JP 《IEEE transactions on medical imaging》2006,25(11):1440-1450
Validation of image registration algorithms is a difficult task and open-ended problem, usually application-dependent. In this paper, we focus on deep brain stimulation (DBS) targeting for the treatment of movement disorders like Parkinson's disease and essential tremor. DBS involves implantation of an electrode deep inside the brain to electrically stimulate specific areas shutting down the disease's symptoms. The subthalamic nucleus (STN) has turned out to be the optimal target for this kind of surgery. Unfortunately, the STN is in general not clearly distinguishable in common medical imaging modalities. Usual techniques to infer its location are the use of anatomical atlases and visible surrounding landmarks. Surgeons have to adjust the electrode intraoperatively using electrophysiological recordings and macrostimulation tests. We constructed a ground truth derived from specific patients whose STNs are clearly visible on magnetic resonance (MR) T2-weighted images. A patient is chosen as atlas both for the right and left sides. Then, by registering each patient with the atlas using different methods, several estimations of the STN location are obtained. Two studies are driven using our proposed validation scheme. First, a comparison between different atlas-based and nonrigid registration algorithms with a evaluation of their performance and usability to locate the STN automatically. Second, a study of which visible surrounding structures influence the STN location. The two studies are cross validated between them and against expert's variability. Using this scheme, we evaluated the expert's ability against the estimation error provided by the tested algorithms and we demonstrated that automatic STN targeting is possible and as accurate as the expert-driven techniques currently used. We also show which structures have to be taken into account to accurately estimate the STN location. 相似文献
993.
This work investigates the feasibility of ozonation for destroying phenol and removing organic matter in saline media. The reaction lumped kinetics was followed using the GLKM (General Lumped Kinetic Model). The main intermediate compounds were: catechol, hydroquinone, 4,4'-dihydroxybiphenyl, and 4-bromophenol. It could be noted no significant differences in phenol degradation, mineralization rates, and toxicity removal up to 2 g L(-1) of salt. So, ozonation appears to be a technology that can be used in low salinity media, which is characteristic of waters destined to reuse and recycling programs inside industries. 相似文献
994.
Francisco Andrs Peralta J. Pablo Huidobro-Toro Raúl Mera-Adasme 《International journal of molecular sciences》2021,22(14)
To ascertain the role of Zn(II) as an allosteric modulator on P2X4R, QM/MM molecular dynamic simulations were performed on the WT and two P2X4R mutants suggested by previous electrophysiological data to affect Zn(II) binding. The Gibbs free energy for the reduction of the putative P2X4R Zn(II) binding site by glutathione was estimated at −22 kcal/mol. Simulations of the WT P2X4R head domain revealed a flexible coordination sphere dominated by an octahedral geometry encompassing C126, N127, C132, C149, C159 and a water molecule. The C132A mutation disrupted the metal binding site, leading to a coordination sphere with a majority of water ligands, and a displacement of the metal ion towards the solvent. The C132A/C159A mutant exhibited a tendency towards WT-like stability by incorporating the R148 backbone to the coordination sphere. Thus, the computational findings agree with previous experimental data showing Zn(II) modulation for the WT and C132A/C159A variants, but not for the C132A mutant. The results provide molecular insights into the nature of the Zn(II) modulation in P2X4R, and the effect of the C132A and C132A/C159A mutations, accounting for an elusive modulation mechanism possibly occurring in other extracellular or membrane protein. 相似文献
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998.
Robert H Clewley John M Guckenheimer Francisco J Valero-Cuevas 《IEEE transactions on bio-medical engineering》2008,55(2):430-442
Studies of the degrees of freedom and "synergies" in musculoskeletal systems rely critically on algorithms to estimate the "dimension" of kinematic or neural data. Linear algorithms such as principal component analysis (PCA) are the most popular. However, many biological data (or realistic experimental data) may be better represented by nonlinear sets than linear subspaces. We evaluate the performance of PCA and compare it to two nonlinear algorithms [Isomap and our novel pointwise dimension estimation (PD-E)] using synthetic and motion capture data from a robotic arm with known kinematic dimensions, as well as motion capture data from human hands. We find that PCA can lead to more accurate dimension estimates when considering additional properties of the PCA residuals, instead of the dominant method of using a threshold of variance captured. In contrast to the single integer dimension estimates of PCA and Isomap, PD-E provides a distribution and range of estimates of fractal dimension that identify the heterogeneous geometric structure in the experimental data. A strength of the PD-E method is that it associates a distribution of dimensions to the data. Since there is no a priori reason to assume that the sets of interest have a single dimension, these distributions incorporate more information than a single summary statistic. Our preliminary findings suggest that fewer than ten DOFs are involved in some hand motion tasks. Contrary to common opinion regarding fractal dimension methods, PD-E yielded reasonable results with reasonable amounts of data. Given the complex nature of experimental and biological data, we conclude that it is necessary and feasible to complement PCA with methods that take into consideration the nonlinear properties of biological systems for a more robust estimation of their DOFs. 相似文献
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Daniel Morató Javier Aracil Juan Pedro Fernández-Palacios Óscar González de Dios Jesús-Felipe Lobo Poyo 《Photonic Network Communications》2008,15(2):159-169
This article presents capacity planning rules for the control plane of all-optical networks featuring GMPLS and RSVP-TE as
a connection setup protocol. As per RSVP standard, a refresh message mechanism is incorporated to RSVP such that the state
is periodically refreshed on a link per link basis. We provide analytical expressions for the bandwidth and buffer sizes to
be provided such that no flows are torn down due to lack of refresh messages. Our findings show that small buffers (several
KBytes) suffice to sustain the signaling load for as much as 400 RSVP flows per link, with the simplest RSVP refresh mechanism
(neither using link bundling nor acknowledgments). On the other hand, we also find the packet drop probability per link for
a given network topology for the case that the flow survival probability is larger than a given threshold. We provide numerical
examples based on the COST 239 european network topology and real RSVP traffic traces from early-commercial switching equipment.
相似文献
Jesús-Felipe Lobo PoyoEmail: |