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11.
Christophe Roussel Loc Dayon Henrik Jensen Hubert H. Girault 《Journal of Electroanalytical Chemistry》2004,570(2):187-199
A series of electrogenerated selective electrophiles based on substituted benzoquinones has been characterized as tags for l-cysteine and cysteine residues in proteins. The electrophiles are generated electrochemically from the corresponding hydroquinones. It is shown from mass spectrometry analysis that the electrogenerated benzoquinone can tag the biomolecules. The rate constants pertaining to the addition of l-cysteine onto the electrogenerated benzoquinones have been determined using electrochemical techniques. The substitution patterns have been unraveled leading to the assessment of site-specific rate constants. It is shown that the rate constants are primarily dependent on the electronic nature of the substituents as expressed by the Hammett substitution constant. The apparent tagging yields observed for l-cysteine in nanospray mass spectrometry experiments do not correspond to the yields expected from the electrochemical study, as the ionisation efficiencies are highly dependent on the tag. Finally, the on-line tagging has been tested using β-lactoglobulin A and myoglobin. Based on these results, it is concluded that the tagging reaction is selective towards cysteine when it takes place in the nanospray interface. The results show that the methodology presented can be used for a rapid characterization and identification of reactive sites in biomolecules. 相似文献
12.
Journal of the Operational Research Society - Serious environmental problems have accompanied China's remarkable economic growth for decades, which also have direct and indirect impacts on its... 相似文献
13.
Aït Hmaïdouch L. Mançour Billah S. El Hadek M. 《Journal of Thermal Analysis and Calorimetry》2002,69(2):659-667
The solid—liquid equilibria of the ternary system H2O—Al(NO3)3—Mg(NO3)2 were studied at –30, –20, –10 and 0°C by using a synthetic method which allows to detemine all the characteristic points of isothermal sections. The stable solid phases which appear are respectively: ice, Al(NO3)3·9H2O, Mg(NO3)2·9H2O and Mg(NO3)2·6H2O. Neither double salts nor mixed crystals are observed in the temperature and composition field studied. Polytherm diagram layout show two invariant transformations correspond with an eutectic point and a peritectic point.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
14.
G. Baldsiefen H. Hübel W. Korten U. J. van Severen J. A. Cizewski N. H. Medina D. R. Napoli C. Rossi Alvarez G. Lo Bianco S. Signorelli 《Zeitschrift für Physik A Hadrons and Nuclei》1996,355(1):337-338
High-spin states in196Pb have been populated using the reaction170Er(30Si,4n). The previously observed shears bands in this nucleus have been extended and some of their transitions have been reordered. They now form regular bands with band crossings. One of the bands splits into two pathways at high spin. 相似文献
15.
Nonlinear and chaotic oscillations of a constrained cantilevered pipe conveying fluid: A full nonlinear analysis 总被引:2,自引:0,他引:2
In this paper, the planar dynamics of a nonlinearly constrained pipe conveying fluid is examined numerically, by considering the full nonlinear equation of motions and a refined trilinear-spring model for the impact constraints—completing the circle of several studies on the subject. The effect of varying system parameters is investigated for the two-degree-of-freedom (N=2) model of the system, followed by less extensive similar investigations forN=3 and 4. Phase portraits, bifurcation diagrams, power spectra and Lyapunov exponents are presented for a selected set of system parameters, showing some rather interesting, and sometimes unexpected, results. The numerical results are compared with experimental ones obtained previously. It is found that in the parameter space that includesN, there exists a subspace wherein excellent qualitative, and reasonably good (N=2) to excellent (N=4) quantitative agreement with experiment. In the latter case, excellent agreement is not only obtained in the threshold flow velocities (u) for the key bifurcations, but the inclusion of the nonlinear terms improves agreement with experiment in terms of amplitudes of motion and by capturing features of behaviour not hitherto predicted by theory. 相似文献
16.
Given disjoint setsP
1,P
2, ...,P
d
inR
d
withn points in total, ahamsandwich cut is a hyperplane that simultaneously bisects theP
i
. We present algorithms for finding ham-sandwich cuts in every dimensiond>1. Whend=2, the algorithm is optimal, having complexityO(n). For dimensiond>2, the bound on the running time is proportional to the worst-case time needed for constructing a level in an arrangement
ofn hyperplanes in dimensiond−1. This, in turn, is related to the number ofk-sets inR
d−1
. With the current estimates, we get complexity close toO(n
3/2
) ford=3, roughlyO(n
8/3
) ford=4, andO(n
d−1−a(d)
) for somea(d)>0 (going to zero asd increases) for largerd. We also give a linear-time algorithm for ham-sandwich cuts inR
3 when the three sets are suitably separated.
A preliminary version of the results of this paper appeared in [16] and [17]. Part of this research by J. Matoušek was done
while he was visiting the School of Mathematics, Georgia Institute of Technology, Atlanta, and part of his work on this paper
was supported by a Humboldt Research Fellowship. W. Steiger expresses gratitude to the NSF DIMACS Center at Rutgers, and his
research was supported in part by NSF Grants CCR-8902522 and CCR-9111491. 相似文献
17.
18.
19.
A. I. Golovashkin G. N. Izmaïlov G. V. Kuleshova T. Q. Khánh A. M. Tskhovrebov L. N. Zherikhina 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(3):243-249
A scheme of magnetic calorimeter for registration of rare events
characterized by small energy release (cosmic rays, WIMPs, solitary X-ray
quanta) is proposed. The calorimeter is brought to operation by adiabatic
demagnetization, and its magnetic response is measured by a quantum
interferometer (SQUID, A. Barone and G. Paterno, Physics and applications of Josephson Effect). Special consideration is given to the specific
features of calorimeter operation in the ferromagnetic transition region.
The trigger registration of ultrasmall energy release by a ferromagnetic
system in the metastable state is described. 相似文献
20.
Loïc Foissy 《Journal of Pure and Applied Algebra》2007,209(2):439-459
We introduce bidendriform bialgebras, which are bialgebras such that both product and coproduct can be split into two parts satisfying good compatibilities. For example, the Malvenuto-Reutenauer Hopf algebra and the non-commutative Connes-Kreimer Hopf algebras of planar decorated rooted trees are bidendriform bialgebras. We prove that all connected bidendriform bialgebras are generated by their primitive elements as a dendriform algebra (bidendriform Milnor-Moore theorem) and then is isomorphic to a Connes-Kreimer Hopf algebra. As a corollary, the Hopf algebra of Malvenuto-Reutenauer is isomorphic to the Connes-Kreimer Hopf algebra of planar rooted trees decorated by a certain set. We deduce that the Lie algebra of its primitive elements is free in characteristic zero (G. Duchamp, F. Hivert and J.-Y. Thibon conjecture). 相似文献