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81.
82.
Solov’ev V. P. Tsivadze A. Yu. 《Protection of Metals and Physical Chemistry of Surfaces》2015,51(1):1-35
Stability constants and formation enthalpies of supramolecular complexes of crown ethers and their cyclic and acyclic analogues are determined on the basis of experimental data obtained by different physicochemical methods in the terms of a general approach developed and implemented in the ChemEqui software package. The established regularities of variation of stability of complexes are discussed as dependent on the ligand structure, nature of the cation, solvent, and anion. The applicability of the suggested method of determining complexation selectivity is shown for multicomponent equilibria in solutions.
相似文献83.
V. E. Gromov A. M. Glezer K. V. Morozov Yu. F. Ivanov K. V. Volkov 《Russian Metallurgy (Metally)》2015,2015(13):1094-1097
A layer-by-layer analysis of the structures, the phase compositions, and the defect substructures of differentially hardened rails has been carried by optical and transmission electron microscopy. It is found that the material volume of the rail head fillet is cooled faster than the volume located along the central axis. 相似文献
84.
C. Doga Demirhan William W. Tso Joseph B. Powell Efstratios N. Pistikopoulos 《American Institute of Chemical Engineers》2019,65(7):e16498
Current ammonia production technologies have a significant carbon footprint. In this study, we present a process synthesis and global optimization framework to discover the efficient utilization of renewable resources in ammonia production. Competing technologies are incorporated in a process superstructure where biomass, wind, and solar routes are compared with the natural gas-based reference case. A deterministic global optimization-based branch-and-bound algorithm is used to solve the resulting large-scale nonconvex mixed-integer nonlinear programming problem (MINLP). Case studies for Texas, California, and Iowa are conducted to examine the effects of different feedstock prices and availabilities. Results indicate that profitability of ammonia production is highly sensitive to feedstock and electricity prices, as well as greenhouse gas (GHG) restrictions. Under strict 75% GHG reductions, biomass to ammonia route is found to be competitive with natural gas route, whereas wind and solar to ammonia routes require further improvement to compete with those two routes. © 2018 American Institute of Chemical Engineers AIChE J, 65: e16498 2019 相似文献
85.
86.
Strength of Materials - The statistical analysis performed on the defectiveness of rails in the Kiev subway railway shows that the main cause of the occurrence of most defects is the contact... 相似文献
87.
Loboda P. I. Minitsky A. V. Byba Ye. G. Sysoev M. O. Radchuk S. V. 《Powder Metallurgy and Metal Ceramics》2020,58(11-12):651-656
Powder Metallurgy and Metal Ceramics - The infiltration of aluminum melts into porous metal skeletons produced by powder metallurgy methods, including 3D printing, under a pressure gradient was... 相似文献
88.
Strength of Materials - Methodical aspects of experimental investigation of brittle materials under local edge loading by scratching the specimen surface with a Rockwell indenter to its edge... 相似文献
89.
Measurement Techniques - A method is proposed for transferring the unit of mean power of laser radiation by means of measuring high-intensity power (kilowatts), with the possibility of constant... 相似文献