全文获取类型
收费全文 | 72313篇 |
免费 | 5523篇 |
国内免费 | 2719篇 |
学科分类
工业技术 | 80555篇 |
出版年
2024年 | 198篇 |
2023年 | 1197篇 |
2022年 | 1742篇 |
2021年 | 2787篇 |
2020年 | 2142篇 |
2019年 | 1904篇 |
2018年 | 2245篇 |
2017年 | 2469篇 |
2016年 | 2051篇 |
2015年 | 2683篇 |
2014年 | 3419篇 |
2013年 | 4196篇 |
2012年 | 4344篇 |
2011年 | 4853篇 |
2010年 | 4169篇 |
2009年 | 3949篇 |
2008年 | 3847篇 |
2007年 | 3709篇 |
2006年 | 3793篇 |
2005年 | 3430篇 |
2004年 | 2283篇 |
2003年 | 2082篇 |
2002年 | 1868篇 |
2001年 | 1636篇 |
2000年 | 1804篇 |
1999年 | 2037篇 |
1998年 | 1757篇 |
1997年 | 1406篇 |
1996年 | 1397篇 |
1995年 | 1176篇 |
1994年 | 939篇 |
1993年 | 710篇 |
1992年 | 539篇 |
1991年 | 420篇 |
1990年 | 323篇 |
1989年 | 249篇 |
1988年 | 219篇 |
1987年 | 138篇 |
1986年 | 101篇 |
1985年 | 89篇 |
1984年 | 60篇 |
1983年 | 34篇 |
1982年 | 43篇 |
1981年 | 28篇 |
1980年 | 22篇 |
1979年 | 13篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1975年 | 5篇 |
1945年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
62.
63.
64.
340管线矫直机是太原重工成熟产品,在国内占有较大市场,并出口印度、印尼、缅甸、埃及等国际市场。出口印度矫直机在质保期内出现主缸裂纹问题,为探明问题原因并杜绝类似情况发生,快开机构设计静强度分析、疲劳强度分析及生产加工过程等方面探查裂纹原因并提出几点预防措施。 相似文献
65.
66.
Qiang Xia Tao Feng Xiaowei Lou Ying Wang Yangying Sun Daodong Pan Jinxuan Cao 《International Journal of Food Science & Technology》2020,55(2):669-680
As a decisive attribute, flavour could be influenced by HP treatments through multiple physical and chemical pathways within the high pressure (HP)-assisted meat curing process. This investigation aimed to identify the major pathway influencing volatile flavour patterns of two representative vinasse-cured duck (VCD) products with HP treatments (150–300 MPa/15 min), including wet and dry types, by employing headspace fingerprinting as an untargeted approach. Results suggested that HP treatments greatly lowered moisture contents and increased Warner-Bratzler shear force and thiobarbituric acid reactive substances of the cured samples. According to multivariate models, the volatile flavour patterns of the HP-processed VCD could be clearly separated from the unprocessed samples, but the VCD pressurised at different intensities represented similar volatile fingerprinting, which was validated by e-nose analysis. The discriminant analysis (OPLS-DA) model outlined vinasse-derived ethanol, acetic acid, 3-methyl-1-butanol, 2-methyl-1-butanol, phenethyl alcohol and 2-methyl-3-octanone as the major discriminant aromas across the unpressurised and pressurised samples. 相似文献
67.
WeiJia Luo LingXia Li Shihui Yu Qianyu Guo Bowen Zhang Zheng Sun 《Ceramics International》2018,44(11):12414-12419
Low-loss (Zn1-xNix)ZrNbTaO8 (0.02?≤?x?≤?0.10) ceramics possessing single wolframite structure are initiatively synthesized by solid-state route. Based on the results of Rietveld refinement, complex chemical bond theory is used to establish the correlation between structural characteristics and microwave performance in this ceramic system. A small amount of Ni2+ (x?=?0.06) in A-site with the fixed substitution of Ta5+ in B-site can effectually raise the Q?×?f value of ZnZrNb2O8 ceramic, embodying a dense microstructure and high lattice energy. The dielectric constant and τf are mainly affected by bond ionicity and the average octahedral distortion. The (Zn0.94Ni0.06)ZrNbTaO8 ceramic sample sintered at 1150?°C for 3?h exhibits an outstanding combination of microwave dielectric properties: εr =?27.88, Q?×?f?=?128,951?GHz, τf =?–39.9?ppm/°C. Thus, it is considered to be a candidate material for the communication device applications at high frequency. 相似文献
68.
Mani Balamurugan Hui‐Yun Jeong Venkata Surya Kumar Choutipalli Jung Sug Hong Hongmin Seo Natarajan Saravanan Jun Ho Jang Kang‐Gyu Lee Yoon Ho Lee Sang Won Im Venkatesan Subramanian Sun Hee Kim Ki Tae Nam 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(25)
The electrochemical reduction of carbon dioxide (CO2) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO2 to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO2 to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO2 in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions. 相似文献
69.
70.
Sowoon Seo Yunjeong Song Sun Mi Gu Hyun Kyu Min Jin Tae Hong Hye Jin Cha Jaesuk Yun 《International journal of molecular sciences》2020,21(23)
Background: Epilepsy is a chronic neurological disorder characterized by the recurrence of seizures. One-third of patients with epilepsy may not respond to antiseizure drugs. Purpose: We aimed to examine whether D-limonene, a cyclic monoterpene, exhibited any antiseizure activity in the pentylenetetrazole (PTZ)-induced kindling mouse model and in vitro. Methods: PTZ kindling mouse model was established by administering PTZ (30 mg/kg) intraperitoneally to mice once every 48 h. We performed immunoblot blots, immunohistochemistry (IHC), and high-performance liquid chromatography (HPLC) analysis after the behavioral study. Results: An acute injection of PTZ (60 mg/kg) induced seizure in mice, while pretreatment with D-limonene inhibited PTZ-induced seizure. Repeated administration of PTZ (30 mg/kg) increased the seizure score gradually in mice, which was reduced in D-limonene (10 mg/kg)-pretreated group. In addition, D-limonene treatment increased glutamate decarboxylase-67 (GAD-67) expression in the hippocampus. Axonal sprouting of hippocampal neurons after kindling was inhibited by D-limonene pretreatment. Moreover, D-limonene reduced the expression levels of Neuronal PAS Domain Protein 4 (Npas4)-induced by PTZ. Furthermore, the adenosine A2A antagonist and ZM241385 inhibited anticonvulsant activity and gamma-aminobutyric acid (GABA)ergic neurotransmission-induced by D-limonene. Conclusion: These results suggest that D-limonene exhibits anticonvulsant activity through modulation of adenosine A2A receptors on GABAergic neuronal function. SCH58261相似文献