The main purpose of the study was to develop a model using ASPEN and Excel simulation method to establish optimum CO2 separation process utilizing hollow fiber membrane modules to treat exhaust gas from LNG combustion. During the simulation,
optimum conditions of each CO2 separation scenario were determined while operating parameters of CO2 separation process were varied. The characteristics of hollow fibers membrane were assigned as 60 GPU of permeability and
25 of selectivity for the simulation. The simulation results illustrated that 4 stage connection of membrane module is required
in order to achieve over 99% of CO2 purity and 90% of recovery rate. The resulted optimum design and operation parameters throughout the simulation were also
correlated with the experimental data from the actual CO2 separation facility which has a capacity of 1,000 Nm3/day located in the Korea Research Institute of Chemical Technology. Throughout the simulation, the operating parameters of
minimum energy consumption were evaluated. Economic analysis of pilot scale of CO2 separation plant was done with the comparison of energy cost of CO2 recovery and equipment cost of the plant based on the simulation model.
This work was presented at the 6th Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006. 相似文献
Hydrogenation of acetylene has been investigated on Au/TiO2, Pd/TiO2 and Au-Pd/TiO2 catalysts at high acetylene conversion levels. The Au/TiO2 catalyst (avg. particle size: 4.6 nm) synthesized by the temperature-programmed reduction-oxidation of an Au-phosphine complex on TiO2 showed a remarkably high selectivity to ethylene formation even at 100% acetylene conversion. Au/TiO2 prepared by the conventional incipient wet impregnation method (avg. particle size: 30 nm), on the other hand, showed negligible activity for acetylene hydrogenation. Although the Au catalysts showed a high selectivity for ethylene, the acetylene conversion activity and catalyst stability were inferior to the Pd-based catalysts. Au-Pd catalysts prepared by the redox method showed high acetylene conversions as well as high selectivity for ethylene. Interestingly Au-Pd catalysts prepared by depositing Pd via the incipient wetness method on Au/TiO2 showed very poor selectivity (comparable to mono-metallic Pd catalysts) for ethylene. High-resolution transmission electron microscopy (TEM) studies coupled with energy dispersive X-ray spectroscopy (EDS) showed that while the redox method produced bimetallic Au-Pd catalysts, the latter method produced individual Pd and Au particles on the support. 相似文献
Epoxidized 10-undecenoic acid triglyceride, an experimental seed oil derivative that has a terminal epoxy group on each of
the three acyl glyceride segments, has been found to have good reactivity with amine curatives and allows room temperature
cures to be obtained. Coatings based on epoxidized 10-undercenoic acid triglyceride have also shown excellent UV stability.
As an example, coatings samples placed in a QUVA chamber exhibit no loss in gloss after 3000 hr of a cycled exposure to high
intensity UV lamps and moisture at temperatures of 50–60°C. In comparison, coatings based on standard liquid epoxy resins
(LERs) and commercially available hydrogenated LERs lose gloss due to chalking/decomposition within 200–800 hr.
Presented at the 81 st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献
The pulsed arc discharge to the surface of wastewater was applied to the degradation of a textile azo dye (Acid Red 27). A
high-voltage electrode (discharging electrode) was vertically placed above the surface of the wastewater while the wastewater
itself was grounded. The pulsed arc discharge occurred between the tip of the discharging electrode and the surface of the
wastewater, producing various oxidative species. Oxygen was used as the working gas instead of air to prevent nitrogen oxides
from forming. The effect of several parameters on the chromaticity and chemical oxygen demand (COD) removal was examined.
The results obtained showed that the chromaticity of the wastewater was completely removed by this process and the COD also
decreased significantly. It has been found that ozone formed in the gas phase mainly affects the removal of the dye. The contribution
of other effects such as ultraviolet light emission and OH radical formation during the arc discharge to the degradation of
the dye was found to be less than 15%. For the present reactor system, the optimum pH, pulse repetition rate and agitation
speed were found to be 3.0, 110 Hz and 300 rpm, respectively. 相似文献
The rapidly increasing population and associated quest for food and feed in China has led to increased soil cultivation and
nitrogen (N) fertilizer use, and as a consequence to increased wind erosion and unbalanced crop nutrition. In the study presented
here, we explored the long-term effects of various combinations of maize stover, cattle manure and nitrogen (N) and phosphorus
(P) fertilizer applications on maize (Zea mays L.) yield and nutrient and water use efficiencies under reduced tillage practices. In a companion paper, we present the effects
on nutrient balances and soil fertility characteristics. The ongoing factorial field trial was conducted at Shouyang Dryland
Farming Experimental Station in northern China from 1993 onwards. The incomplete, determinant-optimal design comprised 12
treatments, including a control treatment, in duplicate. Grain yields and N, P, and potassium (K) uptakes and N, P and K use
efficiencies were greatly influenced by the amount of rain during the growing season (GSR), and by soil water at sowing (SWS).
There were highly significant interactions between GSR and added stover and manure, expressed in complex annual variations
in grain yield and N, P and K use efficiencies. Annual mean grain yields ranged from 3,000 kg ha−1 to 10,000 kg ha−1 and treatment mean yields from 4,500 kg ha−1 to 7,000 kg ha−1. Balanced combination of stover (3,000–6,000 kg), manure (1,500–6,000 kg) and N fertilizer (105 kg) gave the highest yield.
Stover and manure were important for supplying K, but the effects differed greatly between years. Overall mean N recovery
efficiency (NRE) ranged from 28% to 54%, depending on N source. NRE in wet years ranged from 50% to 90%. In conclusion, balanced
combinations of stover, manure and NP fertilizer gave the highest yield and NRE. Reduced tillage with adding stover and manure
in autumn prior to ploughing is effective in minimizing labor requirement and wind erosion. The potentials of split applications
of N fertilizer, targeted to the need of the growing crop (response farming), should be explored to further increase the N
use efficiency. 相似文献
−Purification of 2-mercaptobenzothiazole (91.9% purity) by solvent extraction was studied. The extraction of impurities present
in crude 2-MBT (e.g. benzothiazole, sulfides and sulfur containing compounds) was carried out at temperatures between 70-180°C
using various solvents and their mixtures of different polarity. The highest purity of 2-MBT, above 99% was obtained using
nitrobenzene, toluene and ethanol, even at a concentration of 2-MBT above 50 wt%. Increasing temperature and decreasing concentration
of the raw material have a positive influence on the purification process. A comparable efficiency of purification was observed
also with mixed solvents, (toluene with ethanol, acetone and aniline) possessing the same polarities. A correlation between
the polarity indexes (PI) of mixed solvents and experimentally obtained purity of 2-MBT was found. The highest purity of 2-MBT
provides extraction of the raw material with mixed solvents having PI 3.8-4.4. 相似文献
Modification of chitosan by grafting of vinyl butyrate was carried out in homogeneous phase using potassium persulfate as
redox initator and 1.5% acetic acid as solvent. The percent grafting and grafting efficiency were analysed and the high grafting
efficiency up to 94% was observed. The effects of reaction variables such as monomer concentration, initiator concentration,
temperature and reaction time were investigated. It was observed that the solubility of chitosan was markedly reduced after
grafting with vinyl butyrate. The grafted product is insoluble in common organic solvents as well in dilute organic and inorganic
acids. Characterization of the graft copolymers were carried out by using Fourier Transform Infrared Spectroscopy (FTIR),
Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM) technics. Characteristic signal of carbonyl
group was observed at 1,731 cm−1 which belongs to the poly vinyl butyrate segments in the graft copolymer. The melting transition of the chitosan main chain
in the copolymer shifted to 124°C from its original value 101°C. In addition to these, we have also studied topology of the
graft copolymer and the SEM micrograph showed continuous homogenous matrix which means there is no phase separation. 相似文献
Multimedia Tools and Applications - Present era is marked by exponential growth in transfer of multimedia data through internet. Most of the Internet-of-Things(IoT) applications send images to... 相似文献
The development of digital technology is utilized by people to capture and share video frames. At present, rather than capturing images, people are interested in recording video footage for exploring information. Here, retrieval of video from large databases is challenging due to the continuous frame count. To overcome these challenges associated with the retrieval of video from available databases, this research proposed a likelihood-based regression approach for video processing. To improve the retrieval accuracy of video sequences, the proposed method utilizes a likelihood estimation technique integrated with a regression model. The likelihood estimate measures the pixel level roughly for estimating the pixel range, after which the regression approach measures the pixel level for transforming certainly blurred and unwanted pixels. In the proposed likelihood regression approach, the video is converted into a video frame and stored in a database. Query frames are taken into account by the generated database depending on the features which are used for a given video to be retrieved. The significant video retrieval performance obtained from the simulation results for the proposed likelihood-based regression model shows that the proposed model performs well over the other state-of-the-art techniques.
Multimedia Tools and Applications - A new cryptographic model is proposed incorporating intertwining logistic map based confusion process and two dimensional Brownian Motion based diffusion... 相似文献