Mössbauer spectroscopic studies of Fe-substituted YIG

Compositional dependence of hyperfine parameters, determined through Mössbauer spectral analysis has been studied for Y_3−xFe_5+xO₁₂ (x = 0.0, 0.1, 0.3 and 0.5) garnet system at 300 K. The Mössbauer spectra have been fitted with three sextets in the ferrimagnetic state corresponding to Fe³⁺ ions at tetrahedral (d), octahedral (a) and dodecahedral (c) sites of the crystal structure. It is observed that isormershift, quadrupole shift and hyperfine field of d-site show no significant variation with Fe³⁺ concentration. The change in hyperfine fields of a- and c-sites with composition (x) has been explained on the basis of strength of exchange integrals, change in isomershift can be understood due to s-electron charge distribution and asymmetric displacement of oxygen ions surrounding the a- and c-sites seems to be responsible for observable quadrupole shift. The magneton number values obtained from magnetization and Mossbauer data are in agreement to those calculated using Neel's three sublattice model of ferrimagnetism.     

A novel method to study fluorescein staining of the ocular surface using the fluorescein angiogram setting of the fundus camera.

We present a case of a failed penetrating keratoplasty (PKP), comparing the fluorescein staining of the cornea with the conventional technique, and the new technique using the fluorescein filters of a standard fundus camera.     

Au and Au-Ag bimetallic nanoparticles synthesized by using 12-3-12 cationic Gemini surfactant as template

A seed-growth method has been applied to synthesize gold (Au) and Au-silver (Ag) bimetallic nanoparticles (NP) by using 12-3-12, a cationic Gemini surfactant, as a capping agent as well as micellar template. A systematic increase in the [12-3-12] from pre- to post-micellar region (up to 5 times the critical micelle concentration, cmc) produces Au NP from spherical to large plate like structures. Keeping [12-3-12] constant (equal to 1 / 2 cmc) and increasing ascorbic acid (AA) concentration lead to the formation of core shell type Au-Ag bimetallic NP. At maximum AA concentration (i.e. [AA] = 5.6 mM), fused bimetallic Au-Ag NP are obtained. The anisotropic growth of such materials is a key factor for various applications in nanotechnology.     

Degradation of Stiffness of Cemented Calcareous Soil in Cyclic Triaxial Tests

The deformation characteristics of artificially cemented calcareous soil subjected to undrained cyclic triaxial loading are investigated at different confining pressure and cyclic stress levels. The influence of cementation on the shear stiffness is investigated by comparing the behavior of cemented and uncemented soils with similar initial conditions. It is observed that the deviator stress and the deviatoric strain at yield reduced with increasing number of cycles for cemented sand due to progressive degradation of bond, which results in significant decrease in stiffness. On the other hand, a strain-hardening effect is observed in uncemented sand and this results in increasing yield stress and strain with progressive number of cycles. A linear relationship between degradation index and number of cycles is observed for cemented sand. This relationship has been synthesized in the form of an empirical equation by modifying a previously proposed equation for cohesive soils. This empirical equation was further used to evaluate the fatigue life of soils by adopting a failure criterion.     

Plastic Limit, Liquid Limit and Undrained Shear Strength of Soil—Reappraisal

The concept that plasticity index of soils can be defined as a range of water contents producing a 100-fold variation in undrained shear strength has been experimentally verified with the help of a large number of tests on soils of diverse nature. This has led to the redefinition of the plastic limit as the water content at which undrained shear strength is around 170 kN/m2. Undrained shear strength of a soil at the liquid limit can be considered to be around 1.7 kN/m2. Accordingly, both the liquid limit and the plastic limit have been determined in the present work by a single consistent method, i.e., the Swedish fall cone method. The undrained shear strength-water content relationship has been found to be log-linear for a wide range of water contents beginning from lower than the plastic limit to higher than the liquid limit. This resulted in the formulation of an expression for predicting undrained shear strength of a remolded soil at any water content based solely on its liquid limit and plastic limit.     

下一代SONET/SDH对网络部署的冲击

面对电信业的低迷,运营商和设备制造商都捏紧了钱袋,想方设法少花钱多办事。这就意味着,必须改进现有传输网(见图1),使话音和数据传输效率更高。从网络部署的角度来看,运营商需要:用一些有效的方法,将多协议数据转换到SONET/SDH信道上;用一种灵活的带宽适应机制,使SONET/SDH信道大小与在其中传输的数据的需求相一致;用一种机制,灵活并以理想的动态方式改变整个SONET/SDH网络的信道带宽。这就要求集成电路供应商提供有助于在SONET/SDH上有效传输数据的芯片。虽然现在有多种SONET/SDH信息包(PoS)产品,但是它们的转换效率都太…     

Transparent ultra-long-haul DWDM networks with "broadcast-and-select" OADM/OXC architecture

We describe an experimental realization of ultra-long-haul (ULH) networks with dynamically reconfigurable transparent optical add-drop multiplexers (OADMs) and optical cross-connects (OXCs). A simple new approach to dispersion management in ULH dense-wavelength-division-multiplexing (DWDM) transparent optical networks is proposed and implemented, which enables excellent transmission performance while avoiding dispersion compensation on a connection-by-connection basis. We demonstrate "broadcast-and-select" node architectures that take full advantage of this method. Our implementation of signal leveling ensures minimum variations of path-averaged power among the wavelength-division-multiplexing (WDM) channels between the dynamic gain-equalizing nodes and results in uniform nonlinear and spontaneous-emission penalties across the WDM spectrum. We achieve 80/spl times/10.7-Gb/s DWDM networking over 4160 km (52 spans/spl times/80 km each) of all-Raman-amplified symmetric dispersion-managed fiber and 13 concatenated OADMs or 320/spl times/320 wavelength-port OXCs with 320-km node spacing. The WDM channels use 50-GHz grid in C band and the simple nonreturn-to-zero (NRZ) modulation format. The measured Q values exhibit more than a 1.8-dB margin over the forward-error correction threshold for 10/sup -15/ bit-error-rate operation. We compare these results with point-to-point transmission of 80/spl times/10-Gb/s NRZ WDM signals over 4160 km without OADM/OXC and provide detailed characterization of penalties due to optical signal-to-noise-ratio degradation, filter concatenation, and crosstalk.     

Characterization of ZnS:Cu, Br electroluminescent phosphor prepared by new route

Synthesis of electroluminescent ZnS:Cu, Br phosphor by a number of routes has been presented along with their brightness-voltage, brightness-frequency, brightness-waveform and spectral energy distribution studies. The sample fired in N₂ atmosphere with aluminum and bromine shows predominantly green emission with a peak around 530 nm whereas the sample prepared under H₂S and HBr shows the broadest emission spectrum with multiple peaks. These peaks may arise out of different possible bands of copper, self-activated luminescence of ZnS and association of copper with some of the donor levels formed because of the higher reactivity of HBr. All the samples have been found to obey the relation B=B₀ exp.(−b/V^0.5) which has been discussed using bipolar tunnel emission model. The frequency variation of brightness is linear. Samples containing bromine show multiple secondary peaks indicating that bromine helps in formation of multiple shallow traps.     

Nanoweb Formation: 2D Self‐Assembly of Semiconductor Gallium Oxide Nanowires/Nanotubes

This paper reports a method to produce networks of crystalline gallium oxide comprised of one‐dimensional (1D) nanostructures. Because of the unique arrangement of wires, these crystalline networks are termed as ‘nanowebs’. Nanowebs are of great technological interest since they contain wire densities of the order of 10⁹ cm^–2. A possible mechanism for the fast self‐assembly of crystalline metal oxide nanowires involves multiple nucleation and coalescence via oxidation–reduction reactions at the molecular level. The preferential growth of nanowires parallel to the substrate enabled them to coalesce into regular polygonal networks. The individual segments of the polygonal network consist of both nanowires and nanotubules of β‐gallium oxide. Individual wire properties contribute to a nanoweb’s overall capacity and the implications for devices based on nanowebs are expected to be enormous.     

Anhydrous esterification of myristic acid with propylene: Ion exchange resin and acid-treated clay as catalysts

Anhydrous esterification of myristic acid with propylene was carried out in the temperature range of 110–145°C and pressure from 190–195 psig in the presence of Amberlyst-15 (cation exchange resin) and Filtrol-24 (acid-treated clay) as catalysts. The product ester, isopropyl myristate finds use in cosmetic and topical medicinal preparations where good absorption through the skin is desired. Filtrol-24 is the catalyst of choice, and the recommended operating temperature is 130°C with a pressure of 190 psig.