Economic feasibility of bifacial silicon solar cells

Bifacial solar cells and modules are a promising approach to increase the energy output of photovoltaic systems, and therefore decrease levelized cost of electricity (LCOE). This work discusses the bifacial silicon solar cell concepts PERT (passivated emitter, rear totally diffused) and BOSCO (both sides collecting and contacted) in terms of expected module cost and LCOE based on in‐depth numerical device simulation and advanced cost modelling. As references, Al‐BSF (aluminium back‐surface field) and PERC (passivated emitter and rear) cells with local rear‐side contacts are considered. In order to exploit their bifacial potential, PERT structures (representing cells with single‐sided emitter) are shown to require bulk diffusion lengths of more than three times the cell thickness. For the BOSCO concept (representing cells with double‐sided emitter), diffusion lengths of half the cell thickness are sufficient to leverage its bifacial potential. In terms of nominal LCOE, BOSCO cells are shown to be cost‐competitive under monofacial operation compared with an 18% efficient (≙ p_MPP = 18 mW/cm²) multicrystalline silicon (mc‐Si) Al‐BSF cell and a 19% mc‐Si PERC cell for maximum output power densities of p_MPP ≥ 17.3 mW/cm² and p_MPP ≥ 18.1 mW/cm², respectively. These values assume the use of $10/kg silicon feedstock for the BOSCO and $20/kg for the Al‐BSF and PERC cells. For the PERT cell, corresponding values are p_MPP ≥ 21.7 mW/cm² and p_MPP ≥ 22.7 mW/cm², respectively, assuming the current price offset (≈50%, at the time of October 2014) of n‐type Czochralski‐grown silicon (Cz‐Si) compared with mc‐Si wafers. The material price offset of n‐type to p‐type Cz‐Si wafers (≈15%, October 2014) currently accounts for approximately 1 mW/cm², which correlates to a conversion efficiency difference of 1%_abs for monofacial illumination with 1 sun. From p‐type mc‐Si to p‐type Cz‐Si (≈30% wafer price offset, October 2014), this offset is approximately 2.5 mW/cm² for a PERT cell. When utilizing bifacial operation, these required maximum output power densities can be transformed into required minimum rear‐side illumination intensities for arbitrary front‐side efficiencies η_front by means of the performed numerical simulations. For a BOSCO cell with η_front = 18%, minimum rear‐side illumination intensities of ≤ 0.02 suns are required to match a 19% PERC cell in terms of nominal LCOE. For an n‐type Cz‐Si PERT cell with η_front = 21%, corresponding values are ≤ 0.11 suns with 0.05 suns being the n‐type to p‐type material price offset. This work strongly motivates the use of bifacial concepts to generate lowest LCOE. Copyright © 2016 John Wiley & Sons, Ltd.     

Radiant Ignition of Polyurethane Foam: The Effect of Sample Size

Although smouldering ignition of upholstery items remains a leading cause of residential fire deaths, relatively little research is conducted on the topic. An experimental investigation of the effect of sample size on the ignition and spread of smouldering and flaming in polyurethane foam under natural flow conditions is reported here. Polyurethane foam samples are used because this is a common material in modern, residential environments and one for which there exists significant quantities of previous experimental data in the literature. Samples of different square cross-section size and a fixed height of 150 mm are insulated on all sides except the top which is exposed to a radiant heat flux and is open to the air. Samples with side lengths of 50 mm, 100 mm, and 140 mm are studied. Ignition and spread dynamics are diagnosed using thirteen thermocouples located along the vertical centre line. The onset of smouldering ignition (13  $\hbox{kW}\, \hbox{m}^{-2}$ , 8  $\hbox{kW}\, \hbox{m}^{-2}$ and $7\,\hbox{kW}\, \hbox{m}^{-2}$ for 50 mm, 100 mm and 140 mm sample sizes respectively) is observed at significantly lower heat fluxes that flaming (45  $\hbox{kW}\,\hbox{m}^{-2}$ , 32  $\hbox{kW}\,\hbox{m}^{-2}$ and $30\,\hbox{kW}\,\hbox{m}^{-2}$ respectively). Critical heat fluxes for smouldering and flaming ignition increase with decreasing sample size, with smouldering ignition being significantly more sensitive to sample size than flaming ignition under the size range studied. Smouldering spread rates are measured in the range from 3  $\hbox{mm}\, \hbox{min}^{-1}$ to $25\,\hbox{mm}\, \hbox{min}^{-1}$ and found to be a strong function of the heat flux and depth of the smoulder front. The effect of sample size on smouldering has been theoretically proposed before but this is the first time that this effect has been demonstrated experimentally for ignition. The fact that large samples result in the lowest critical heat flux could have implications for testing procedures and translation of results from small-scale testing to real-scale in the built environment.     

Comparison of Mass Transfer Efficiency and Energy Consumption in Static Mixers

The aim of this study was to compare the pressure drop (Δp) generated by a static mixer with sieve plates in two-phase downflow (water as a continuous phase), and the mass transfer efficiency (k_La, a) with the performance of other static mixers (Sulzer, Kenics, Karman, etc.). The relationships for Δp, k_La and interfacial area (a) calculation depending on liquid and gas phase velocities and geometry of the plates (sieves) in this static mixer are presented. k_La was found to be strictly proportional to the power consumption (P/V) and its values were quite close to those obtained in Sulzer & Kenics mixers with an 8-element mesh. Enhancement factors for oxygen absorption in the sodium sulphite solution and for ozone absorption in Lake Ülemiste water were calculated and the plausible values of the interfacial area (a) were estimated.     

Elaboration of Ultra‐High Molecular Weight Polyethylene/Carbon Nanotubes Electrospun Composite Fibers

Micron‐sized fibers of UHMWPE reinforced with CNT were fabricated by the electrospinning process. Conditions for a metastable mutual solution of UHMWPE and CNTs were found at elevated temperature. These solutions were used for electrospining using a device having controlled temperature and gaseous environment around the electrospun liquid jet. The fabricated micron‐sized fibers exhibited the reinforcing CNTs as self‐organized nano‐ropes embedded within them. A post‐spinning drawing process enhanced the mechanical properties of the composite fibers to the level of 6.6 GPa strength and elongation at break of 6%. The CNT nano‐ropes form spontaneously in the liquid jet during electrospinning, and provide the reinforcement framework which is amenable for post‐drawing of the fibers for subsequent utilization as composite nanofibers. The experimental results exhibit the highest strength value reported to date for electrospun fibers.

     

SiGe Bipolar VCO With Ultra-Wide Tuning Range at 80 GHz Center Frequency

A SiGe millimeter-wave VCO with a center frequency around 80 GHz and an extremely wide (continuous) tuning range of 24.5 GHz ( ap 30%) is presented. The phase noise at 1 MHz offset is -97 dBc/Hz at the center frequency (and less than -94 dBc/Hz in a frequency range of 21 GHz). The maximum total output power is about 12 dBm. A cascode buffer improves decoupling from the output load at reasonable VCO power consumption (240 mW at 5 V supply voltage). A low-power frequency divider (operating up to 100 GHz) provides, in addition, a divided-by-four signal. As a further intention of this paper, the basic reasons for the limitation of the tuning range in millimeter-wave VCOs are shown and the improvement by using two (instead of one) varactor pairs is demonstrated.     

Development and validation of a fluorescence method to follow the build-up of short peptide sequences on solid 2D surfaces

The modification of material surfaces with short peptide sequences has become an essential step in many biotechnological and biomedical applications. Due to their simple architecture compared to more complex 3D substrates, 2D surfaces are of particular interest for high throughput applications and as model surfaces for dynamic or responsive surface modifications. The decoration of these surfaces with peptides is commonly accomplished by synthesizing the peptide first and subsequently transferring it onto the surface of the substrate. Recently, several procedures have been described for the synthesis of peptides directly onto a 2D surface, thereby simplifying and accelerating the modification of flat surfaces with peptides. However, the wider use of these techniques requires a routine method to monitor the amino acid build-up on the surface. Here, we describe a fast, inexpensive and nondestructive fluorescence based method which is readily accessible to follow the amino acid build-up on solid 2D samples.     

Ultrasonically induced degradation of microcystin-LR and -RR: identification of products, effect of pH, formation and destruction of peroxides

Microcystins (MCs) are a family of toxic peptides produced by a number of cyanobacteria commonly found in lakes, water reservoirs, and recreational facilities. The increased eutrophication of freshwater supplies has led to an increase in the incidence of cyanobacterial harmful algal blooms and concerns over the public health implications of these toxins in the water supply. Conventional water treatment methods are ineffective at removing low concentrations of cyanotoxins, hence specialized treatment is usually recommended for treatment of contaminated water. In this study, the products of ultrasonically induced degradation of microcystin-LR (MC-LR) and microcystin-RR (MC-RR) were analyzed by LC-MS to elucidate the probable pathways of degradation of these toxins. Results indicate preliminary products of sonolysis of MCs are due to the hydroxyl radical attack on the benzene ring and diene of the Adda peptide residue and cleavage of the Mdha-Ala peptide bond. The effect of pH on the toxin degradation was evaluated since the pH of the solution changes upon ultrasonic irradiation and varies with the water quality of treatable waters. The initial rate of MC-LR degradation is greater at acidic pH and coincides with the change in hydrophobic character of MC-LR as a function of pH. Hydrogen and organic peroxides are formed during ultrasonic irradiation, but can be eliminated by adding Fe(II). The addition of Fe(II) also accelerates the degradation of MC-LR, presumably by promoting the formation of hydroxyl radicals via conversion of ultrasonically produced H2O2. These findings suggest that sonolysis can effectively degrade MCs in drinking water.     

杭州RAFFLES城

杭州Raffles城发展坐落于浙江省省会杭州市的钱塘江边，是嘉德置地继新加坡、上海、北京、成都和巴林之后的第六栋，将零售店、办公楼、住户和酒店设施融于一体，成为新城区的文化地标。     

Modeling substrate effects in the design of high-speed Si-bipolarICs

In the design of high-speed IC's, the influence of the substrate on circuit performance must be considered carefully. Therefore, in this paper the contribution of the p^- substrate and channel stopper to the equivalent circuits of Si-bipolar transistors and bond pads are theoretically and experimentally investigated up to very high frequencies. Improved equivalent substrate circuits, well suited for standard circuit simulators (e,g., SPICE), are derived and checked by numerical simulation using a new simulator (called SUSI). The validity of both the numerical simulation results and the equivalent circuits are verified by on-wafer measurements up to 20 GHz. Finally, the simulator was successfully applied to investigate noise coupling via the substrate