Experimental exploration of damage propagation in rocks using acoustic emission

Bulletin of Engineering Geology and the Environment - The formation of geological disasters, such as earthquakes and rock bursts, is a process similar to avalanches. These sudden disasters are...     

The effect of CO2 saturation on mechanical properties of Australian black coal using acoustic emission

Acoustic emission (AE) methods are now widely used for damage evaluation. For a better understanding of the damage mechanics of materials such as rocks, AE has been used to monitor stresses which induce crack closure, crack initiation and crack damage. In the present study, an AE system was used to study the damage behaviour of some Australian black coal samples subjected to uniaxial compression. Several samples were left in a container filled with 100% carbon dioxide (CO₂) at a certain pressure for 72 h prior to testing. The results were compared with samples which had only been exposed to the atmosphere to see if CO₂ had any adverse effect on the strength of coal. Strain gauges were installed on the samples and the measured axial and volumetric strains were studied in conjunction with the AE counts.The AE method was successfully used for detecting the onset of crack initiation and the crack damage stress threshold of the black coal samples. Of the coal samples examined, crack initiation and crack closure of the samples subjected to saturation with CO₂ occurred at stress corresponding to a higher percentage of the peak strength when compared to the samples which had only been exposed to atmospheric conditions. However, crack damage occurred at a higher percentage of peak strength and the average peak strength showed a higher value for samples in atmospheric condition when compared to CO₂ saturated samples. The results show that sorption of CO₂ can cause a reduction in strength of the black coal samples when tested under uniaxial compression. As the coal samples were highly inhomogeneous more tests are required in order to be able to confirm whether the adsorption of CO₂ will cause strength reduction in coal and to identify the actual underlying mechanisms.     

Pt-MoOx-carbon nanotube redox couple based electrocatalyst as a potential partner with polybenzimidazole membrane for high temperature Polymer Electrolyte Membrane Fuel Cell applications

A redox couple based electrocatalyst comprising of Pt-Multi Wall Carbon NanoTube (Pt-MWCNT) promoted with molybdenum oxide (MoO_x, 2 < x < 3) nanoparticles was prepared. The objective was to effectively organize the Pt-MoO_x interface on the smooth MWCNT surface to overcome the practical difficulties associated with establishing such interface with Pt dispersed on carbon morphologies possessing surface irregularities. The present study revealed the importance of stringent controlling of the additive level for maintaining a balanced bifunctional behavior of the catalyst combination through the synergistic effects by the components and the need of a proton conducting membrane operable at high temperature to get better output from the Polymer Electrolyte Membrane Fuel Cell (PEMFC) systems. An indigenously developed polybenzimidazole (PBI) membrane was used to fabricate a membrane electrode assembly (MEA) as it can be operated at higher temperatures compared to that of Nafion membranes. MoO_x additive level was carefully controlled by monitoring the active Pt area by cyclic voltammetry. All prepared electrocatalysts were characterized by using HRTEM, XRD and XPS to get information on dispersion and morphology, crystalinity and oxidation state of different elements, respectively. The system prepared with 5% MoO_x addition with respect to Pt (hereafter Pt-MoO_x(5%)-MWCNT) displayed balanced active Pt area and excellent oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) activities. Rotating Disk Electrode (RDE) system was extensively utilized to understand the ORR kinetics and the favorable role of MoO_x as the promoter in the reaction. The kinetic current (j_k) measured at 0.02 V vs. Hg/Hg₂SO₄ electrode from the Koutecky-Levich plots was 9 times higher and the apparent activation energy during single cell evaluation was 27 kJ/mol lower for the MoO_x promoted system, compared to the system without the additive. A higher operating temperature significantly favored the cell performance by a combined effect of enhancement in proton conductivity of the PBI membrane and possible kinetic benefit by the well postulated oxygen spill over effect by the MoO_x type systems in some combinations involving such systems.     

Effect of Biopolymer Blend Matrix on Structural,Optical and Biological Properties of Chitosan–Agar Blend ZnO Nanocomposites

The present research is focused on the development of ecofriendly biopolymer blend based nanocomposites to enhance the effect of cytotoxic activity. Novel eco-friendly synthesis of pure Chitosan–Agar blend and Chitosan–Agar/ZnO nanocomposites was successfully synthesized by in-situ chemical synthesis method. The influence of Chitosan–Agar (1:1 wt/wt%) concentrations (0.1, 0.5, 1 and 3 g) was studied. The presence of ZnO nanoparticles in Chitosan–Agar polymer matrix was confirmed by UV, FTIR, XRD, FESEM, EDAX and TEM. The crystallite size of the nanocomposites in the range of 12–17 nm is observed from XRD analysis. PL and UV reveal that Nanocomposites shows an blue shift by increase in the blend concentrations. TEM analysis shows that 0.1 and 3 g of Chitosan–Agar/ZnO Nanocomposites are in spindle and spherical shape with polycrystalline nature. The prepared Nanocomposites shows the respectable Antibacterial activity against Gram-positive (Staphylococcus aureus and Bacillus subtilis) and Gram-negative (Pseudomonas aureginosa and Klebsilla pneumonia) bacteria. The potential toxicity of Chitosan–Agar/ZnO nanocomposites was studied for normal (L929) and breast cancer cell line (MB231). The result of this investigation shows that the Chitosan–Agar/ZnO nanocomposites deliver a dose dependent toxicity in normal and cancer cell line.     

An optimal weighted HEVC coding for video compression

Multimedia Tools and Applications - In recent years, the applications of multimedia are rising in greedy mode and hence the amount of video transactions are also increasing exponentially. It has...     

Asymptotic and finite element analyses of mode III dynamic crack growth at a ductile-brittle interface

In this work, dynamic crack growth along a ductile-brittle interface under anti-plane strain conditions is studied. The ductile solid is taken to obey the J ₂ flow theory of plasticity with linear isotropic strain hardening, while the substrate is assumed to exhibit linear elastic behavior. Firstly, the asymptotic near-tip stress and velocity fields are derived. These fields are assumed to be variable-separable with a power singularity in the radial coordinate centered at the crack tip. The effects of crack speed, strain hardening of the ductile phase and mismatch in elastic moduli of the two phases on the singularity exponent and the angular functions are studied. Secondly, full-field finite element analyses of the problem under small-scale yielding conditions are performed. The validity of the asymptotic fields and their range of dominance are determined by comparing them with the results of the full-field finite element analyses. Finally, theoretical predictions are made of the variations of the dynamic fracture toughness with crack velocity. The influence of the bi-material parameters on the above variation is investigated.     

Two-Phase (Air and Water) Flow through Rock Joints: Analytical and Experimental Study

This research study deals with the characterization of two-phase flow in a fractured rock mass. A comprehensive mathematical model with which to predict the quantity of each flow component in a single joint is developed. A joint with two parallel walls filled with layers of water and air (stratified) is analyzed. The effects of mechanical deformation of the joint, the compressibility of fluids, the solubility of air in water, and the phase change between fluids have been taken into account to develop analytical expressions which describe the behavior at the air–water interface. The model was calibrated using a newly designed two-phase (high-pressure) triaxial cell. Tests were conducted on fractured hard rock samples for different confining pressures with inlet water and inlet air pressures. As in single-phase flow, it was found both experimentally and theoretically, that the flow quantities of each phase decreases considerably with an increase in confining stress. The results also confirm that the effect of joint deformation and compressibility of fluids governs the flow volume of two-phase flow. Good agreement was obtained between the experimental data and numerical predictions.     

Solvothermal‐assisted green synthesis of hybrid Chi‐Fe3 O4 nanocomposites: a potential antibacterial and antibiofilm material

In this present study, a hybrid Chi‐Fe₃ O₄ was prepared, characterised and evaluated for its antibacterial and antibiofilm potential against Staphylococcus aureus and Staphylococcus marcescens bacterial pathogens. Intense peak around 260 nm in the ultraviolet–visible spectrum specify the formation of magnetite nanoparticles. Spherical‐shaped particles with less agglomeration and particle size distribution of 3.78–46.40 nm were observed using transmission electron microscopy analysis and strong interaction of chitosan with the surface of magnetite nanoparticles was studied using field emission scanning microscopy (FESEM). X‐ray diffraction analysis exhibited the polycrystalline and spinel structure configuration of the nanocomposite. Presence of Fe and O, C and Cl elements were confirmed using energy dispersive X‐ray microanalysis. Fourier transform infrared spectroscopic analysis showed the reduction and formation of Chi‐Fe₃ O₄ nanocomposite. The antibacterial activity by deformation of the bacterial cell walls on treatment with Chi‐Fe₃ O₄ nanocomposite and its interaction was visualised using FESEM and the antibiofilm activity was determined using antibiofilm assay. In conclusion, this present study shows the green synthesis of Chi‐Fe₃ O₄ nanocomposite and evaluation of its antibacterial and antibiofilm potential, proving its significance in medical and biological applicationsInspec keywords: visible spectra, particle size, magnetic particles, nanocomposites, nanoparticles, X‐ray diffraction, nanofabrication, transmission electron microscopy, X‐ray chemical analysis, nanomagnetics, microorganisms, antibacterial activity, iron compounds, ultraviolet spectra, biomedical materials, field emission scanning electron microscopy, Fourier transform infrared spectra, filled polymers, crystal growth from solution, polymer structureOther keywords: potential antibacterial material, antibiofilm potential, magnetite nanoparticles, solvothermal‐assisted green synthesis, hybrid Chi‐Fe₃ O₄ nanocomposites, staphylococcus aureus, staphylococcus marcescens, bacterial pathogens, ultraviolet–visible spectrum, spherical‐shaped particles, particle size, transmission electron microscopy, FESEM, field emission scanning electron microscopy, X‐ray diffraction, spinel structure, polycrystalline structure, energy dispersive X‐ray microanalysis, Fourier transform infrared spectroscopic analysis, deformation, bacterial cell walls, Fe₃ O₄      

Characterization of two-phase flow in a single rock joint

An experimental study using a triaxial apparatus was used to analyze the two-phase flow patterns in jointed rock specimens. Rock specimens having a single natural fracture were tested for two-phase flow of water and air. Triaxial tests were conducted to characterize the two-phase flow through fractured granite specimens at low confining pressures. It was found that for a relatively smooth joint (JRC<6), bubble flow pattern occurred within the rock joint when the gas velocity is below 15 m/s. The average velocity of water usually varied between 0.1 and 0.5 m/s for bubble flow patterns. In this velocity range, air bubbles were able to form along the joint walls or to be randomly displaced within the water phase. When the gas velocity inside the rock joint exceeded 22 m/s, the flow patterns took annular form for non-zero capillary pressures (i.e., injected gas pressure is not equal to injected water pressure). At elevated (>0.25 MPa) gas injection pressures, the gas occupied the main part of the fracture and the liquid was able to flow as an unstable film forming an annular flow along the joint. When the annular flow developed, the mixture flow pattern was independent of the air flow velocity. This was due to the fact that once the injected air velocity reached a critical value (i.e., 20 m/s), water velocity inside the joint was negligible for a given confining pressure and injected water pressure. Further increase in inlet air pressures developed a single-phase air flow with no water flow.     

Some aspects of unsaturated flow in jointed rock

The applicability of Darcy's Law to two-phase flow has been discussed. Specialised triaxial equipment has been employed to separately inject two pore fluid components (air and water) into fractured rock specimens, so that two-phase flow behaviour can be studied at high axial and confining stresses. Improvements to recently developed two-phase high-pressure triaxial apparatus have enabled the authors to continue their study of air–water (i.e. unsaturated) flow in intact and fractured rock specimens under a wide range of stress conditions, similar to those encountered in underground mining operations. In this paper, a simplified stratified two-phase flow model is also presented that satisfactorily predicts flow behaviour in an inclined rock fracture over a range of linear laminar flow for particular capillary pressure relationships. The mathematical model is based upon the principles of conservation of mass and momentum, and relates the fracture aperture (e_t) to phase permeability (k_i) using Poiseuille's law and the proposed ‘phase height’, h_i(t), for water and air phases. The experimental approach used to verify the model predictions is described and the predicted results compared with the measurements. The experimental data confirmed the relationship between relative permeability and flow rate, with respect to two-phase flow conditions.