Sputtered Titanium Carbide Thick Film for High Areal Energy on Chip Carbon‐Based Micro‐Supercapacitors

The areal energy density of on‐chip micro‐supercapacitors should be improved in order to obtain autonomous smart miniaturized sensors. To reach this goal, high surface capacitance electrode (>100 mF cm^?2) has to be produced while keeping low the footprint area. For carbide‐derived carbon (CDC) micro‐supercapacitors, the properties of the metal carbide precursor have to be fine‐tuned to fabricate thick electrodes. The ad‐atoms diffusion process and atomic peening effect occurring during the titanium carbide sputtering process are shown to be the key parameters to produce low stress, highly conductive, and thick TiC films. The sputtered TiC at 10^?3 mbar exhibits a high stress level, limiting the thickness of the TiC‐CDC electrode to 1.5 µm with an areal capacitance that is less than 55 mF cm^?2 in aqueous electrolyte. The pressure increase up to 10^?2 mbar induces a clear reduction of the stress level while the layer thickness increases without any degradation of the TiC electronic conductivity. The volumetric capacitance of the TiC‐CDC electrodes is equal to 350 F cm^?3 regardless of the level of pressure. High values of areal capacitance (>100 mF cm^?2) are achieved, whereas the TiC layer is relatively thick, which paves the way toward high‐performance micro‐supercapacitors.     

Assessment of contaminant diffusivities in building materials from porosimetry tests

Recent studies have shown that surface and gaseous contaminant interactions may play an important role in indoor air quality. Modeling is an important tool to improve our knowledge about the phenomena involved and define appropriate ventilation strategies. However, data for sorption isotherms and diffusion in building materials remain woefully lacking. This paper deals with the latter point. It aims at investigating a methodology based on an analysis of the material porosity first and then the application of Carniglia's mathematical model to determine the effective diffusivity of gaseous species in building materials. This methodology, whose main principles are presented in the first part of the paper, was applied to seven commonly found materials. Mercury intrusion porosimetry (MIP) tests, and the calculations using Carniglia's model, reveal typical total porosities and tortuosity factors for these materials. The analysis of pore size distributions (PSDs) also draws one's attention to the possible differences in the pore structures that may exist between two samples of the same type of material and the differences in the effective diffusivities of contaminants that may result from them. The computed effective diffusivities were subsequently compared to data from experiments carried out in the frame of the EC project MATHIS. An agreement was obtained, thus validating Carniglia's methodology - a methodology that offers many practical advantages compared to diffusion-cell methods.     

Composites realized by hand lay-up process in a civil engineering environment: initial properties and durability

The repair, the reinforcement as well as the setting in safety of buildings and existing reinforced and/or pre-stressed concrete structure is a real technological stake and a socio-economic problem for the near future. The introduction of composites in civil engineering is an interesting answer to these goals, but they brought an important amount of new problems that have to be solved for safe structural applications under combined mechanical and environmental loadings. In fact during the past five years, we have witnessed exponential growth in research or field demonstrations of fiber-reinforced composites in civil engineering. Manufacturers and designers have now access to a wide range of composite materials. However, they face great problems with forecasting the reliability of composite materials. Their introduction in civil engineering applications is a difficult operation due to working environment and weathering conditions. The objective of this paper is to study the effect of these conditions and their consequences on the mechanical properties of the final composite. An analysis of the rheological (viscoelastic) properties was carried out in order to observe the glass transition temperature evolution according to reactive mixture stoichiometry and weathering conditions.     

Common pattern of gene expression in response to hypoxia or cadmium in the gills of the European glass eel (Anguilla anguilla)

European eel (Anguilla anguilla) populations are in decline. Glass eel recruitment has fallen 10-fold since the early 1980s. Estuaries play a fundamental role in the life history of eels because glass eels must pass through them to reach freshwater ecosystems. Unfortunately, because of their geographical position at the upstream basin slopes, estuaries accumulate metals like cadmium and are important sites of hypoxia events. In this context, we studied the effect of the oxygen level on the ventilation of the glass eel. In parallel, glass eels were submitted to different dissolved cadmium concentrations (0, 2, and 10 microg L(-1)) under two oxygen levels (normoxia PO2 = 21 kPa and Hypoxia PO2 = 6 kPa). The expression level of various genes involved in the mitochondrial respiratory chain, in the cellular response to metal and oxidative stresses, was investigated. Our results showed that hypoxia enhances (1) ventilation of the postlarval stage and (2) Cd accumulation in gills only at the lowest metal water concentration tested (2 microg Cd L(-1)). At the gene level, Cd exposure mimics the effect of hypoxia since we observed a decrease in expression of genes involved in the respiratory chain and in the defense against oxidative stress.     

Temperature-insensitive polarimetric vibration sensor based on HiBi microstructured optical fiber

A new type of highly birefringent microstructured optical fiber has been tested for vibration measurements using a polarimetric technique. This technique takes advantage of the stress-induced phase shift between the two orthogonally polarized fiber eigenmodes. Comparison of three different fiber types shows that standard single-mode fibers do not provide stable measurements and that conventional polarization-maintaining fibers lead to a significant cross-sensitivity to temperature. However, for highly birefringent microstructured fibers specifically designed to provide a temperature-independent birefringence, our experiments show repeatable vibration measurements over a frequency range extending from 50?Hz to 1?kHz that are unaffected by temperature variations (up to 120?°C).     

Out-of-plane reflection and refraction of light by anisotropic optical antenna metasurfaces with phase discontinuities

Experiments on ultrathin anisotropic arrays of subwavelength optical antennas display out-of-plane refraction. A powerful three-dimensional (3D) extension of the recently demonstrated generalized laws of refraction and reflection shows that the interface imparts a tangential wavevector to the incident light leading to anomalous beams, which in general are noncoplanar with the incident beam. The refracted beam direction can be controlled by varying the angle between the plane of incidence and the antenna array.     

Association of indigo with zeolites for improved color stabilization

The durability of an organic color and its resistance against external chemical agents and exposure to light can be significantly enhanced by hybridizing the natural dye with a mineral. In search for stable natural pigments, the present work focuses on the association of indigo blue with several zeolitic matrices (LTA zeolite, mordenite, MFI zeolite). The manufacturing of the hybrid pigment is tested under varying oxidizing conditions, using Raman and ultraviolet-visible (UV-Vis) spectrometric techniques. Blending indigo with MFI is shown to yield the most stable composite in all of our artificial indigo pigments. In the absence of defects and substituted cations such as aluminum in the framework of the MFI zeolite matrix, we show that matching the pore size with the dimensions of the guest indigo molecule is the key factor. The evidence for the high color stability of indigo@MFI opens a new path for modeling the stability of indigo in various alumino-silicate substrates such as in the historical Maya Blue pigment.     

Coagulase-negative staphylococci species affect biofilm formation of other coagulase-negative and coagulase-positive staphylococci

Coagulase-negative staphylococci (CNS) are considered to be commensal bacteria in humans and animals, but are now also recognized as etiological agents in several infections, including bovine mastitis. Biofilm formation appears to be an important factor in CNS pathogenicity. Furthermore, some researchers have proposed that CNS colonization of the intramammary environment has a protective effect against other pathogens. The mechanisms behind the protective effect of CNS have yet to be characterized. The aim of this study was to evaluate the effect of CNS isolates with a weak-biofilm phenotype on the biofilm formation of other staphylococcal isolates. We selected 10 CNS with a weak-biofilm phenotype and 30 staphylococcal isolates with a strong-biofilm phenotype for this study. We measured biofilm production by individual isolates using a standard polystyrene microtiter plate assay and compared the findings with biofilm produced in mixed cultures. We confirmed the results using confocal microscopy and a microfluidic system with low shear force. Four of the CNS isolates with a weak-biofilm phenotype (Staphylococcus chromogenes C and E and Staphylococcus simulans F and H) significantly reduced biofilm formation in approximately 80% of the staphylococcal species tested, including coagulase-positive Staphylococcus aureus. The 4 Staph. chromogenes and Staph. simulans isolates were also able to disperse pre-established biofilms, but to a lesser extent. We also performed a deferred antagonism assay and recorded the number of colony-forming units in the mixed-biofilm assays on differential or selective agar plates. Overall, CNS with a weak-biofilm phenotype did not inhibit the growth of isolates with a strong-biofilm phenotype. These results suggest that some CNS isolates can negatively affect the ability of other staphylococcal isolates and species to form biofilms via a mechanism that does not involve growth inhibition.     

Heuristics for the N-product,M-stage,economic lot sizing and scheduling problem with dynamic demand

This paper presents a new composite heuristics approach for solving the N-product, M-stage lot sizing and scheduling problem with dynamic demands and limited production capacity. The first phase of these composite heuristics aims at finding a feasible solution. This solution is such that for each period and for each product, the lot size equals the net demand of the considered period plus the demand of a number of upcoming periods. If capacity does not satisfy all demands of a given period, we try to find earlier periods where we can produce the missing units. The second phase is an improvement procedure which recursively attempts to move back each lot, provided that it is both more economical to do so and capacity feasible. We also provide two variants of this heuristic to handle the case where production capacity can be increased by using overtime. Overtime is a usual practice in real life which, in many cases, allows a reduction of the overall cost. The first variant constructs the initial solution without recourse to overtime and introduces overtime only during the solution improvement phase. The second one considers overtime during both the first and second phases. The performance of the proposed heuristics is numerically assessed and the most efficient ones are identified.     

Multiphase coatings from complex radiation curable polyurethane dispersions

The waterborne nature of radiation curable polyurethane dispersions largely respond to the current environmental concerns and do not require any additional coalescent since the film formation (drying) and hardening (photo-curing) take place in distinct steps. It is possible to design aqueous dispersions with distinct polymer particle populations resulting in micro-structured coatings with optimized properties over a wide range of curing conditions. Mixed dispersions based on hard and soft acrylated polyurethane particles were used as model systems for the present study. The minimum film formation temperature has been investigated as a function of the hard:soft polymer ratio. The elastic modulus of the dry coatings shows a reinforcing effect consistent with the inclusion of hard domains in a soft continuous matrix. However, the level of reinforcement is not properly predicted by the usual mechanical models and it is qualitatively accounted for by assuming a composition gradient (interphase) between the hard domains and the matrix. The multiple-phase structure was clearly established by Atomic Force Microscopy in agreement with thermal analysis data. Furthermore the local nanoscale mechanical properties were mapped using a new imaging mode based on real-time force–distance curve analysis. Finally, the coatings prepared using this multiple-phase pattern present a clear benefit over conventional homogeneous coatings by offering an improved balance of chemical and mechanical resistance in pigmented systems applied on melamine-coated MDF panels.