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71.
Patricia Amouzegh Annie Finiels Patrick Geneste Erick Ginestar Patrice Moreau 《Catalysis Letters》1995,34(3-4):389-394
The acylation reaction of 2-butylbenzofuran withp-anisoyl chloride andp-anisic acid in the presence of faujasite type zeolites, in the liquid phase, is reported. A good initial selectivity to the 3-acylated derivative is obtained, but the selectivity decreases with time. This result is explained by the involvement of a deacylation-reacylation process. 相似文献
72.
Digital curve acquisition with a vision system introduces a large amount of degradation. At the same time ‘corners’ convey important visual information. Unfortunately they are found in the same spectral domain as the quantization noise. Low-pass filtering of the curvature function is compared with more sophisticated methods that keep the angles ‘sharp’. An automated inspection is successfully performed, demonstrating the efficiency of a new method. 相似文献
73.
74.
The tightness of retail packagings and of their closures is of primary importance both for domestic and industrial products. For this reason, a research programme designed to establish proper testing methods for a wide range of ‘packaging + product’ combinations, in order to check their tightness or permeability, was set up. All the available testing methods were reviewed, the most reliable ones selected and their sensitivity determined. More than 200 combinations of ‘packaging + product’ belonging to five families of consumer products were examined and their tightness/permeability problems noted. Finally, specific testing methods were assigned to each combination of ‘packaging + product’. All these examples are currently in use in the packaging laboratory as a guideline for the testing of every kind of packaging. 相似文献
75.
76.
The effects of growth temperature and salinity on the cellular fatty acids were investigated on Aeromonas caviae, Aeromonas hydrophila and Aeromonas sobria. Under optimal growth conditions, fatty acids patterns were dominated by even-numbered chains C(16:0), C(16:1cis9), C(18:1cis11), C(12:0) and C(14:0). Growth temperature modifications induced, in the three Aeromonas species, important changes in fatty acid (i) unsaturation, (ii) branching and (iii) chain length. An important decrease in the C(18:1cis11) fatty acid content was observed for the three species below 15 degrees C and above 25 degrees C. The evolution of C(18:1cis11) and C(16:0) showed a mirror image for the three Aeromonas species. Low NaCl concentrations did not elicit significant changes in the fatty acids content of the three Aeromonas species. However, for high NaCl concentration in the medium, the growth ability was related to an important decrease of the unsaturated to saturated fatty acids ratio indicating a membrane rigidification. Thermal and salinity adaptations were branched fatty acid-dependent for A. caviae, whereas this phenomenon was less significant for A. hydrophila and A. sobria. 相似文献
77.
The following paper presents the results of a comparative reliability study conducted on three tpes of high density circular connectors, conforming to NAS 1599, MIL. C. 38 999, and MIL. C. 81 511. After runing numerous relability tests, Souriau has been able to develop a highly successful high density connector. 相似文献
78.
Alain De Savignac Patrice Dupin Hubert Matondo Serge Bories Armand Lattes 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1980,30(1):117-128
Evidence is given for the involvement of hydrophobic interactions in the retention of hydrocarbons in oil fields. A prerequisite is that the surface of the reservoir rock has to be hydrophobic. This was obtained through adsorption of lipophilic polar compounds. The isotherms for the adsorption of dodecylamine hydrochloride and N-hexadecylpyridine hydrochloride were plotted. The treated quartz could take up large amounts of toluene. The relationships between some features of the isotherms and the retention phenomenon have been analysed. The effect of water-structuring additives (e.g. LiF, CaCl2, NaF and guanidine hydrochloride) on the recovery of hydrocarbons was investigated by means of static and dynamic methods. 相似文献
79.
Karine Blondeau Hlne Boze G. Jung G. Moulin P. Galzy 《Yeast (Chichester, England)》1994,10(10):1297-1303
Production of recombinant human serum albumin (rHSA) controlled by the constitutive promoter phosphoglycerate kinase was studied in Kluyveromyces lactis. It was governed by both cell concentration and glycolytic flow. The triggering of the fermentation metabolism by unfavourable culture conditions (pH, pO2, D) caused a decrease in the synthesis of the heterologous protein. The highest productivity (75 mg 1?1 per h) and rHSA concentration (62 mg 1?1) were obtained in chemostat culture with a dilution rate of 0·12 h?1 and with 38 g 1?1 dry weight. 相似文献
80.
Poly(acrylonitrile‐co‐methyl acrylate)/clay nanocomposites were prepared by free radical polymerization in emulsion using 2‐acrylamido‐2‐methyl‐1‐propanesulphonic acid (AMPS) as a compatibilizer. The resultant nanocomposites were of partially exfoliated morphology despite the variations in clay content among the nanocomposites, as confirmed by transmission electron microscopy and small‐angle X‐ray scattering analysis. Rheological studies of these materials were carried out using parallel plate geometry. The storage modulus increased monotonically with increasing clay content throughout the frequency range studied. However, the neat copolymer, poly(acrylonitrile‐co‐methyl acrylate) and its nanocomposites, exhibited long relaxation behavior as the storage modulus (G′) was greater than the loss modulus (G″) throughout the angular frequency range studied. The complex viscosity of the nanocomposites increased with increasing clay content and they exhibited shear‐thinning behavior. Despite the enhanced rheological properties observed, the copolymer and its nanocomposites underwent structural changes during oscillatory measurements due to cyclization reactions. POLYM. COMPOS., 32:59–66, 2011. © 2010 Society of Plastics Engineers 相似文献