Spinel-Coated Graphite for Carbon Containing Refractory Castables

Oxidation resistance and water wettability of graphite flakes have been improved by a thin sol–gel film of magnesium aluminate spinel (MgAl₂O₄) over its surface. The hydrosol has been synthesized by less expensive precursors and the spinel formation has been studied by scanning electron microscopy (SEM), supplemented with energy dispersive spectral analysis. After an easy-to-use mixing procedure, drying (110°C), and subsequent calcination (550°C), coated graphites were sieved to below 75 μm. The coating over the powder contained 1.5 wt% MgAl₂O₄, which enormously increased the oxidation resistance (performed at 600°, 900°, and 1200°C) and water wettability, as revealed by hydrophilic functional groups from infrared spectra. Defective, intermediate spinel structure of fine, lamellar Mg-doped γ-Al₂O₃ has been considered to be significant for this improvement. An approximate (1:2) stoichiometry of (Mg:Al) in the coating composition was confirmed by an X-ray photoelectron spectroscopy test. Castables prepared by this graphite remarkably improved their bulk density and apparent porosity compared with those prepared by the as-received graphite. Casting water was reduced along with the amount of antioxidants. This also enhanced the resistance toward the basic slag by retaining the graphite in the refractory.     

Efficient monitoring approach for reputation system-based trust-aware routing in wireless sensor networks

Trust-aware routing in wireless sensor networks (WSNs) is a crucial problem that has drawn the attention of researchers. The motivation for tackling this problem arises directly from the highly constrained nature of a WSN and its easy exposure to insecure conditions. In this regard, reputation-based solutions are used to provide trust-aware routing. However, this approach requires that a node needs to continuously monitor its environment to detect misbehaviour events. This is considered to be a costly operation for WSN nodes because of its resource scarcity. Here, the authors propose a reputation system-based solution for trust-aware routing, which implements a new monitoring strategy called an efficient monitoring procedure in a reputation system (EMPIRE). EMPIRE is a probabilistic and distributed monitoring methodology that tries to reduce the monitoring activities per node while maintaining the ability to detect attacks at a satisfactory level. The proposed procedure has been evaluated using the Monte Carlo simulation. New evaluation methodologies are introduced to test and explore the efficiency of our proposed procedure. Simulation results of the reputation system show that reducing monitoring activities with EMPIRE does not have a significant impact on system performance in terms of security.     

Gas-phase driven nano-machined TiO2 ceramics

A simple, inexpensive gas phase reaction termed as “nanocarving process” converts TiO₂ grains into arrays of single crystal nanofibers by selective and anisotropic etching. This process is conducted by exposing dense polycrystalline TiO₂ to a H₂/N₂ environment at 700 °C. The dimensions of nanofibers are around 20 nm in diameter and 1 μm in length. The preferred crystallographic orientation for the nanocarving process is the <001> direction. Nanoparticles composed of Fe and Ni were observed on the surface of TiO₂ that formed nanofiber tips. Sintering parameters before the nanocarving treatment play a critical role in the formation of nanofibers. As sintering temperature and time increased, the rate of nanofiber generation decreased. Moreover, it was observed that by varying the heat treatment conditions, it is possible to create other structures like nanowhiskers and nanofilaments. Nanowhiskers were formed by reoxidation of nanofiber-formed TiO₂ over 600 °C. Nano-filaments were generated by heat treating sintered TiO₂ in N₂-carrying water vapor at 700 °C.     

Will New Antenna Materials Enable Single Path Multiple Access (SPMA)?

The aim of this paper is to introduce a novel frequency reuse concept especially for macro cellular networks to substantially increase the mobile network capacity, and simultaneously to avoid the implementation of low efficient small cells. Single path multiple access (SPMA) utilizes the characteristics of independent propagation paths for particular geographical location in the coverage area of mobile network. The proposed concept is based on the assumption that new approach will be adopted by the antenna manufacturers for producing advanced antennas by utilizing materials like metamaterials including carbon based nanotechnology, and graphene. In SPMA concept, communication between base station and mobile station happens through only single independent propagation path, and frequency resources can be reused in 5 m  \(\times \)  5 m areas or even more often in 1 m  \(\times \)  1 m areas, but limited by a base station/mobile station antenna requirement. Thus, the capacity of the network will be increased dramatically, and it can be managed in centralized manner at certain macro site locations. In already deployed cellular networks, these macro sites are mostly easily available, and that would help to implement SPMA to enhance the network capacity. Simulation results provided in this paper show the applicability of SPMA technique, by limiting the radiation of signal as single path propagation between base station and mobile station.     

Stability Analysis of Laminated Soft Core Sandwich Plates Using Higher Order Zig-Zag Plate Theory

C₀ finite element model based on higher order zig-zag plate theory is used to study the stability analysis of laminated sandwich plates. The in-plane displacement field is obtained by superposing a global cubically varying displacement field on a zig-zag linearly varying displacement field with different slope in each layer. The transverse displacement assumes to have a quadratic variation within the core and constant in the faces. The conditions regarding transverse shear stress at layer interfaces and top and bottom are satisfied. Numerical examples covering different features of laminated sandwich plates are presented to illustrate the accuracy of the model.     

Jitter‐minimized reliability‐maximized management of networks

We propose a joint optimization network management framework for quality‐of‐service (QoS) routing with resource allocation. Our joint optimization framework provides a convenient way of maximizing the reliability or minimizing the jitter delay of paths. Data traffic is sensitive to droppage at buffers, while it can tolerate jitter delay. On the other hand, multimedia traffic can tolerate loss but it is very sensitive to jitter delay. Depending on the type of data, our scheme provides a convenient way of selecting the parameters which result in either reliability maximization or jitter minimization. We solve the optimization problem for a GPS network and provide the optimal solutions. We find the values of control parameters which control the type of optimization performed. We use our analytical results in a multi‐objective QoS routing algorithm. Finally, we provide insights into our optimization framework using simulations. Copyright © 2011 John Wiley & Sons, Ltd.