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81.
An improved allelopathic correlation between phytotoxicity measured in root growth bioassay upon annual ryegrass (Lolium rigidum Gaud.) and the concentrations of a selection of dynamically produced allelochemicals quantified in the root exudates of cv. Khapli wheat (Triticum turgidum ssp. durum (Desf.) Husn.) monitored during the first 15 days of wheat seedling growth in a sterile, agar–water medium, has been established. Changes over the 15-day growth period in the quantities of five exuded benzoxazinones and seven phenolic acids were measured simultaneously using GC/MS/MS. Substantiating pure compound dose–response measurements were conducted over a range of concentrations for the putative allelochemicals within the wheat exudates. One synergism-based proposal using the monitored compounds to explain the observed low-exudate-concentration phytotoxicity was explored, but was found to be experimentally inadequate. 相似文献
82.
Solid state magnetic resonance spectra of Illinois No. 6 coal and some reductive alkylation products
Illinois No. 6 coal and its reductive methylation and butylation products have been studied by magnetic resonance techniques. Conventional CP-MAS13Cn.m.r. spectroscopy indicates that 62% of the carbon atoms in the coal are aromatic and that about 6% of the carbon atoms are carbonyl. Esters are more abundant than carboxylic acids. The resonances of methoxy groups and other novel etheric carbon atoms are apparent in the high field region. Dipolar dephasing experiments suggest that methyl carbon atoms constitute no more than 16% of the carbon, methylene and methine carbon atoms about 14% and quaternary aliphatic carbon atoms about 2%. The dipolar dephasing experiments in conjunction with previous work also permit estimates of the hydrogen atom distribution. The THF-insoluble products obtained in the reductive alkylation reactions with13C-enriched alkylating agents contain paramagnetic and ferromagnetic substances that adversely influence the solid state n.m.r. spectra. However, good 13C n.m.r. spectra were obtained after these substances were extracted with aqueous hydrochloric acid. The O:C alkylation ratios are 1.2 and 1.0 for methylation and butylation, respectively. Dipolar dephasing experiments establish that the decay constants of functional groups in the whole coal and of C- and O-methyl-13C and C- and O-butyl-1 -13C nuclei in the labelled coal molecules are very similar to those of reference compounds. These findings suggest that the decay constants measured for the 13C nuclei in coals and coal-derived solids provide reliable information about their degree of substitution. 相似文献
83.
Minimum spouting velocities in conical spouted beds have been obtained from pressure drops versus the superficial gas velocity curves, based on both increasing and decreasing the superficial gas velocity. It has been shown that the minimum spouting velocity from decreasing the superficial gas velocity is lower than from increasing the superficial gas velocity in most cases. This phenomenon is similar to that in conventional spouted beds and different from the early works. The experimental results also showed that there isn't significant difference in the pressure drop and Ums under identical operating conditions between semi‐circular and circular conical spouted beds, and the same Ums can be obtained from absolute pressure drops at any position above the gas inlet. The Ums is found to increase with increasing the cone angle and static bed height, as well as the gas inlet diameter to a less extent. 相似文献
84.
Peter A. Edwards Grant Striemer Dean C. Webster 《Journal of Coatings Technology and Research》2005,2(7):517-527
Glycidyl carbamate chemistry combines the excellent properties of polyurethanes with the crosslinking chemistry of epoxy resins.
Glycidyl carbamate functional oligomers were synthesized by the reaction of polyfunctional isocyanate oligomers and glycidol.
The oligomers were formulated into coatings with several amine functional crosslinkers at varying stoichiometric ratios and
cured at different temperatures. Properties such as solvent resistance, hardness, and impact resistance were dependent on
the composition and cure conditions. Most coatings had an excellent combination of properties. Studies were carried out to
determine the kinetics of the curing reaction of the glycidyl carbamate functional oligomers with multifunctional and model
amines. Detailed kinetic analysis of the curing reactions was also undertaken. The results indicated that the glycidyl carbamate
functional group is more reactive than a glycidyl ether group.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, on October 27–29, 2004, in Chicago,
IL. 相似文献
85.
Antonio G. González Ignacio A. Jiménez Mercedes P. Núñez Angel G. Ravelo Isabel L. Bazzocchi Orlando M. Muñoz Marcelino A. Aguilar 《Journal of chemical ecology》1994,20(4):823-830
Three new dihydro--agarofuran sesquiterpenes from two species ofMaytenus were isolated and their structures were elucidated by means of1H and13C NMR studies. The differences and similarities noted in the chemical content of the dihydro--agarofuran sesquiterpenes from the fourMaytenus species from Chile are in line with the taxonomic characterization of these species; their geographical distribution is also given. 相似文献
86.
Jim D. Earls Jerry E. White Marvin L. Dettloff Marty J. Null 《Journal of Coatings Technology and Research》2004,1(3):243-245
Epoxidized 10-undecenoic acid triglyceride, an experimental seed oil derivative that has a terminal epoxy group on each of
the three acyl glyceride segments, has been found to have good reactivity with amine curatives and allows room temperature
cures to be obtained. Coatings based on epoxidized 10-undercenoic acid triglyceride have also shown excellent UV stability.
As an example, coatings samples placed in a QUVA chamber exhibit no loss in gloss after 3000 hr of a cycled exposure to high
intensity UV lamps and moisture at temperatures of 50–60°C. In comparison, coatings based on standard liquid epoxy resins
(LERs) and commercially available hydrogenated LERs lose gloss due to chalking/decomposition within 200–800 hr.
Presented at the 81 st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献
87.
Quintanar-Reséndiz Ana L. Rodríguez-Santos Francisco Pichardo-Méndez Josué L. Delgado-Gutiérrez Guillermo Ramírez Omar Jiménez Vázquez-Medina Rubén 《Multimedia Tools and Applications》2021,80(13):19513-19538
Multimedia Tools and Applications - It is proposed a forensic method for the capture device identification from digital images, which requires two elements: i) a digital image subject to... 相似文献
88.
T.A. Owoseni A. Rincon Romero Z. Pala F. Venturi E.H. Lester D.M. Grant T. Hussain 《Ceramics International》2021,47(17):23803-23813
Yttrium aluminium garnet (YAG) is a promising topcoat material for thermal barrier coatings due to its high temperature stability and better CMAS (calcium-magnesium-alumino-silicate) resistance. YAG topcoats were deposited by suspension and solution precursor high-velocity oxy-fuel (HVOF) thermal spray. The relationships between processing, microstructure and final properties were studied through a range of characterization techniques and thermal cycling tests. The microstructure of the as-sprayed YAG topcoat from stoichiometric solution precursor (SP-YAG) had distributed pores and inter-splat boundaries, while the as-sprayed topcoat produced from suspension (S-YAG) had vertical and branched micro cracks, pores, and inter-splat boundaries. Both as-sprayed coatings were composed of amorphous phase, hexagonal yttrium aluminium perovskite (YAP) and cubic YAG. In thermal cycling tests, 20% of SP-YAG failure was reached after the 10th cycle; whereas, S-YAG reached the failure criteria between the 60th and 70th cycle. The failure of both the SP-YAG and the S-YAG topcoats occurred due to thermal stresses during the thermal cycling. 相似文献
89.
Gordon D. Gemmell Nicholas J. Grant 《JOM Journal of the Minerals, Metals and Materials Society》1957,9(4):417-423
The effects of solid solution alloying on the creep-rupture properties, deformation characteristics, ductility, and fracture of pure aluminum were studied by means of creep-rupture tests on polished specimens of three alloys each of Al-Cu (0.24, 0.79, and 2.05 pct Cu), Al-Zn (4.93, 9.89, and 19.78 pct Zn), and Al-Mg (0.94, 1.92, and 5.10 pct Mg) at 500°, 700°, and 900°F. 相似文献
90.
Nicholas J. Grant Earl C. Roberts John Chipman 《JOM Journal of the Minerals, Metals and Materials Society》1954,6(2):145-149
An equilibrium study was made of the distribution of chromium and oxygen between liquid iron, containing less than 1 pct Cr, and simple slags of the CaO(MgO)-SiO2-FeO-Cr2O3 type in the temperature range 1526° to 1734°C The effects of slag oxidation, temperature, and basicity were observed. 相似文献