Structural,SEM and dielectric properties of PLZT

Powder of lanthanum-modified lead zirconate titanate (PLZT) with the composition La/Zr/Ti=8/65/35, was synthesized from aqueous nitrate solutions. A single-phase PLZT was obtained at ∼550 °C. The reactivity of the powder during low-temperature heating was determined using X-ray diffraction and various thermal analysis techniques. The dielectric properties of the compound were also studied at 1 and 10 kHz frequency from room temperature to 200 °C. Diffuse phase transition (DPT) in the material was observed around 136 °C at 1 kHz. An increase in peak-permittivity temperature (i.e. the transition temperature) with increasing frequency (a characteristic of relaxor ferroelectrics) was also observed.     

Freestanding 3D Graphene–Nickel Encapsulated Nitrogen‐Rich Aligned Bamboo Like Carbon Nanotubes for High‐Performance Supercapacitors with Robust Cycle Stability

3D hierarchical structures are reported based on graphene–nickel encapsulated nitrogen‐rich aligned bamboo like carbon nanotubes, which show not only high‐performance supercapacitance behavior but also a great robust cyclic stability. A facile synthesis route is developed of 2D nickel oxide decorated functionalized graphene nanosheets (2D‐NiO‐f:GNSs) hybrids and 3D nitrogen doped bamboo‐shaped carbon nanotubes (NCNTs) vertically standing on the functionalized graphene nanosheets (3D‐NCNT@f:GNSs) by using a thermal decomposition method. The chemical reduction and morphology‐dependent electrochemical response are investigated. The enhanced specific capacitance of 3D‐NCNT@f:GNSs as compared to that of 2D‐NiO‐f:GNSs suggests the synergistic effects and indicates the importance of energy storage and superior long‐term cycling performance that are achieved. This 3D‐NCNT@f:GNSs hybrid shows a remarkable cycling stability with a maximum power density of 12.32 kW kg⁻¹ and maximum energy density of 109.13 Wh kg⁻¹ due to the good connection of NCNT and f:GNSs. This unique 3D nano network architecture enables the availability of large surface areas of NCNT, thus endowing the nanohybrids with high specific capacitance and excellent reusability.     

Earthworm coelomocytes as nanoscavenger of ZnO NPs

Earthworms can ‘biotransform’ or ‘biodegrade’ chemical contaminants, rendering them harmless in their bodies, and can bioaccumulate them in their tissues. They ‘absorb’ the dissolved chemicals through their moist ‘body wall’ due to the interstitial water and also ingest by ‘mouth’ while soil passes through the gut. Since the advent of the nanotechnology era, the environmental sink has been continuously receiving engineered nanomaterials as well as their derivatives. Our current understanding of the potential impact of nanomaterials and their natural scavenger is limited. In the present investigation, we studied the cellular uptake of ZnO nanoparticles (NPs) by coelomocytes especially by chloragocytes of Eisenia fetida and their role as nanoscavenger. Results from exposure to 100- and 50-nm ZnO NPs indicate that coelomocytes of the earthworm E. fetida show no significant DNA damage at a dose lower than 3 mg/l and have the potential ability to uptake ZnO NPs from the soil ecosystem and transform them into microparticles.     

Dielectric behavior of perovskite glass ceramics

The recent developments of energy storage devices are concerned with larger energy storage ability, low loss and good temperature stability. It has a great technological importance in engineering science. The dielectric materials like ceramics and glass ceramics have great interest in electronic ceramic industry due to above concern. The ceramic dielectrics are used as a capacitive element in electronic circuits. The perovskite glass ceramics have very high dielectric constant and low dielectric loss. The high dielectric constant in glass ceramics is attributed to space charge polarization. In order to produce glass ceramics of high dielectric constant, barium titanate glass ceramics is the first discovered ferroelectric perovskite. In this review article, we are summarizing the dielectric behavior of perovskite glass ceramics such as BaTiO₃, SrTiO₃, PbTiO₃, (Ba,Sr)TiO₃ and (Pb,Sr)TiO₃.     

Photoelectrochemical studies on spray deposited copper selenide thin films

Thin films of copper selenide have been deposited by spraying a mixture of aqueous solutions (0.50 M) of copper chloride hydrate (CuCl₂·2H₂O) and selenourea [H₂NC(Se)NH₂] on preheated fluorine doped tin oxide coated glass substrates at various substrate temperatures. The cell configurations copper selenide/0.5 M K₂SO₄/C are used for studying the capacitance–voltage (C–V) characteristics in the dark, current–voltage (I–V) characteristics in dark and under illumination, photovoltaic power output and spectral response characteristics of the as deposited films. Photoelectrochemical study records that as deposited copper selenide thin films are of p-type. The spectral response characteristics of the films at room temperature show a prominent, sharp peak at 550 nm. The measured values of efficiency (η) and fill factor (FF) are found to be 0.99 % and 0.51 respectively for film deposited at 350 °C.     

A Precision Ultrasonic Phase Velocity Measurement Technique for Liquids

Present paper reports the design and developmental aspects of a new technique for ultrasonic phase velocity measurement in liquids, which is based on the studies carried out on frequency dependence of ultrasonic velocity in pure, binary and ternary liquids/mixtures. The design and developmental aspects of the experimental set up are reported along with optimisation of data acquisition software developed in LabVIEW. Finally, the developed technique is used to measure phase velocity in water (W), aqueous solution of mannitol (M), binary mixture of tertiary butyl alcohol (TBA) in water and a tertiary mixture of TBA + W + M. The results are reported within frequency bandwidth from 3 to 7 MHz. The main reason for selecting these liquids was to identify some of the liquids which can be used as reference liquids for metrological applications. Although, reporting the systematic studies to find out the reference liquid is beyond the scope of the present paper due to obvious reasons, and will be dealt separately, but the studies certainly demonstrate that the technique can successfully be used for phase velocity measurement as a function of frequency and temperature.     

India's fast growing power sector - from regional development to the growth of a national grid

This paper describes the efforts of the Indian government to upgrade its power system to account for the increasing interconnections due to rapid regional development. These include the unibus act (EA2003), which addresses the issue of public sector monopoly and opens up the field for competition, private participation and reforms, and the implementation of the ABT to the intrastate level. The reforms and restructuring policies of the government have assured an adequate rate of return to investors. The national electricity policy implementation is expected to fulfill the aim of meeting more demand at a higher security level.     

Economic analysis of a G.I. sheet multiwick solar distillation plant

On account of the energy crisis, several types of solar energy devices have been developed and marketed in various parts of the world with varying degrees of thermal performance. The economic aspect of these solar energy devices becomes more significant when they replace those devices which use conventional fuels. In this paper, an economic analysis of one of the solar energy devices, namely a G.I. sheet multiwick solar distillation plant, has been presented taking into account the various factors, viz. the lifetime of the system, salvage values of the system, interest rate and maintenance cost.     

Non-linear response statistics of composite laminates with random material properties under random loading

Laminated composite plates find extensive use in many engineering applications. Some of these incorporate large deflections that may not be in the linear range. The external loading may be random in nature. The laminate material properties show an inherent dispersion around a mean value. In this paper the static response of laminated composite flat plates to transverse random loading has been studied. The material properties have been taken as random variables for accurate prediction of the system behaviour. The basic formulation of the problem has been developed based on the classical laminate theory and the Von-Karman non-linear strain–displacement relationship. A first order perturbation technique has been used to obtain the second order response statistics. Typical results have been presented for a plate with all edges simply supported. A comparison has been drawn with Monte Carlo simulation results for validation of the proposed approach. The effects of side-to-thickness ratio, aspect ratio and change in standard deviation of input random variables have been investigated for cross-ply symmetric and anti-symmetric laminates.