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0 INTRODUCTIONCurrentprocessforethyleneproductionisnotenvi ronmentfriendly ,becausealargeamountofspentcausticisdischargedduringthescrubbingofthecrackinggas ,whichcontainshighconcentrationsulfideandorganiccompounds.Sometechniqueshavebeenappliedtotreatthespentcaustic ,includingchemicaloxidation ,neutral izationandprecipitation[1~ 3] .However ,lowremovaleffi ciencyandsecondpollutionarecommonlyinvolvedinthesetechniques .Althoughwetairoxidationprocesscanefficientlyremoveorganiccompoundsinspe… 相似文献
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纳米粒子TiO2/Ti膜的制备及其光催化活性 总被引:7,自引:2,他引:7
以钛酸四丁酯为原料,利用溶胶-凝胶方法制备了纳米粒子TiO2/Ti膜。TG-DTA、XRD、TEM和SEM的测试表明:纳米粒子经历了无定型向锐钛矿和锐钛矿向金红石相转变两个过程,而焙烧温度为600℃时,TiO2纳米粒子具有与国际商品P-25型TiO2粒子相类似的组成、结构、形貌和粒子尺寸。考虑TiO2粒子性质及与基体Ti片的结合能力,焙烧温度对基体Ti片的影响和纳米粒子TiO2/Ti膜表面形貌等因素,确定600℃是制备纳米粒子TiO2/Ti膜光催化剂的最合适的焙烧温度。另外,以光催化降解苯酚为模型反应,考察了焙烧温度对纳米粒子TiO2/Ti膜催化活性的影响,并初步地探讨了光催化降解苯酚反应的动力学。结果表明,600℃焙烧的TiO2纳米粒子膜具有最高的光催化活性,而光催化降解反应为准一级动力学反应。 相似文献
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研究了UV/H2O2,UV/O3和UV/H2O2/O3三种高级氧化体系处理乙烯装置所排放废碱液的特点。对于UV/H2O2体系,随着H2O2剂量的增加,COD的去除率以及处理液的可生化性(BOD:COD值)都随之增大,其性能也好于单独的H2O2体系,该体系在最佳条件下,COD的去除率达到68%,BOD/COD值从0.22增大到0.52;对于UV/O3体系,随着O3剂量的增加,COD的去除率及处理液的可生化性(BOD:COD值)也都随之增大,其性能也好于单独的O3体系。该体系在最佳条件下,COD的去除率达到54%,可生化性(BOD/COD值)从0.22增大到0.48;对于UV/H2O2/O3体系,其COD去除率比UV/O3体系高出22.0%。 相似文献
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采用自行合成的有机吸附膜富集净化水中微量有机污染物,依据有机吸附膜对水中有机污染物物理吸附的过程,在大量测试数据基础上建立高效有机吸附膜吸附饮用水中氯仿的数学模型,并用统计方法求取了模型中的参数.应用此模型研究了萃取时间、水样中氯仿的本底质量浓度和高效有机吸附膜厚度等对萃取效率的影响.通过有机吸附膜对模拟饮用水中氯仿的吸附实验,证明该模型能较准确地模拟高效有机吸附膜吸附氯仿的过程,模型计算数据与实验数据吻合较好. 相似文献
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A method of detection hydroxyl radical ( · OH) produced by electrochemical oxidation in organic wastewater treatment was developed. Benzoic acid with weak fluorescence may reacted with hydroxyl radical to produce 3-hydroxybenzonic acid with intense fluorescence, whose characteristic fluorescence excitation and e- mission wavelength were at 305 nm and 410 nm. The 3-hydroxybenzonic acid was separated from electroehenaical oxidation system by HPLC. Two major hydroxylated products were quantified corresponding to 3-hydroxybenzonic, 4-hydroxybenzonic acid. Therefore the quantity of hydroxyl radical in the reactive system should be primarily calculated. The optimal experimental program was obtained by studying the determination conditions, which were benzoic acid of 1.0 mmol/L, electrolysis time of 60 min, current density of 39 mA/cm^2 , supporting electrolyte (Na2SO4 ) of 0. 02 mol/L, and the low rate of sparged-air of 25 mL/s. The results show that this method is stable, sinaple and rapid and can be used as a convenient method for the determination of hydroxyl radical. 相似文献
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In order to obtain a novel polyamide having excellent heat-resistant properties which could be anticipated as a thermal modifier for aliphatic polyamide,a series of new semi-aromatic polyamides (BO6,BO8,BO10) containing benzoxazole unit were synthesized based on 5-amino-2-(p-aminophenyl) benzoxazole (ABO) and aliphatic acids (adipic,suberic and sebacic acid) by means of Yamazaki phosphorylation method.The effect of reaction temperature on the inherent viscosity of the polymers was studied,and the structures of products were characterized by FTIR,1 H-NMR,and the heat resistance of the polymers was studied by DSC and TG.The results showed that the reaction temperature gives the polymers the highest viscosity at around 90 ℃,130 ℃ and 130 ℃ for BO6,BO8 and BO10,respectively.The heat resistance of the new semi-aromatic polyamides is much higher than that of the common aliphatic polyamides.In addition,the products show good solvent resistance and crystallization properties. 相似文献
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光催化连续降解汽油气的研究 总被引:1,自引:0,他引:1
以掺铁TiO2薄膜为光催化剂,光催化连续动态降解汽油气.分别考察了汽油气的初始质量浓度、反应体系的相对湿度、氧气含量以及载气的流量对汽油气去除率的影响.结果表明,初始质量浓度、反应体系的相对湿度和载气的流量对汽油气去除有较大的影响,氧气含量高于20%时,对汽油气去除影响不大.在最佳工艺参数条件下,对于初始质量浓度低于2327.47mg/m^3的汽油气,经反应光催化降解,出口处汽油气的质量浓度均低于检出下限.对汽油气的光催化降解反应动力学进行了初步探讨. 相似文献