Numerical Investigation of Magnetic Field Effect on Heat Transfer and Entropy Generation in Channel; New Approach for Fluid and Length Scale Selections

In the present study, heat transfer and entropy generation of developing KOH-water solution is numerically examined by implementing a finite difference code to solve the governing equations. Effects of important parameters of heat transfer in both of the developing and fully developed regions are examined. The study reveals that alteration of the existing parameters could have considerable effects on the contribution of the heat transfer, friction, and magnetic field on the total entropy generation. Novelty of the present study lies on the proper fluid and length scale selection procedure which is adopted before the solution, being a guideline for the future fluid flow and heat transfer studies in the magneto-hydrodynamics (MHD). The investigations show that performing a study in the MHD flow of water base nanofluids in the length scales smaller than 0.1 m is not physically feasible, because the required magnetic field intensity is higher than the maximum generated by continuous fields.     

Comparison of conventional and spherical reactor for the industrial auto-thermal reforming of methane to maximize synthesis gas and minimize CO2

Auto-thermal reforming (ATR), a combination of exothermic partial oxidation and endothermic steam reforming of methane, is an important process to produce syngas for petrochemical industries. In a commercial ATR unit, tubular fixed bed reactors are typically used. Pressure drop across the tube, high manufacturing costs, and low production capacity are some disadvantages of these reactors. The main propose of this study is to offer an optimized radial flow, spherical packed bed reactor as a promising alternative for overcoming the drawbacks of conventional tubular reactors. In the current research, a one dimensional pseudo-homogeneous model based on mass, energy, and momentum balances is applied to simulate the performance of packed-bed reactors for the production of syngas in both tubular and spherical reactors. In the optimization section, the proposed work explores optimal values of various decision variables that simultaneously maximize outlet molar flow rate of H₂, CO and minimize molar flow rate of CO₂ from novel spherical reactor. The multi-objective model is transformed to a single objective optimization problem by weighted sum method and the single optimum point is found by using genetic algorithm. The optimization results show that the pressure drop in the spherical reactor is negligible in comparison to that of the conventional tubular reactor. Therefore, it is inferred that the spherical reactor can operate with much higher feed flow rate, more catalyst loading, and smaller catalyst particles.     

A comprehensive review of renewable energy resources for electricity generation in Australia

Recently, renewable energy resources and their impacts have sparked a heated debate to resolve the Australian energy crisis. There are many projects launched throughout the country to improve network security and reliability. This paper aims to review the current status of different renewable energy resources along with their impacts on society and the environment. Besides, it provides for the first time the statistics of the documents published in the field of renewable energy in Australia. The statistics include information such as the rate of papers published, possible journals for finding relative paper, types of documents published, top authors, and the most prevalent keywords in the field of renewable energy in Australia. It will focus on solar, wind, biomass, geothermal and hydropower technologies and will investigate the social and environmental impacts of these technologies.     

Titanium dioxide (P25) produces reactive oxygen species in immortalized brain microglia (BV2): implications for nanoparticle neurotoxicity

Concerns with the environmental and health risk of widely distributed, commonly used nanoparticles are increasing. Nanosize titanium dioxide (TiO2) is used in air and water remediation and in numerous products designed for direct human use and consumption. Its effectiveness in deactivating pollutants and killing microorganisms relates to photoactivation and the resulting free radical activity. This property, coupled with its multiple potential exposure routes, indicates that nanosize TiO2 could pose a risk to biological targets that are sensitive to oxidative stress damage (e.g., brain). In this study, brain microglia (BV2) were exposed to a physicochemically characterized (i.e., dispersion stability, particle size distribution, and zeta potential) nanomaterial, Degussa P25, and cellular expressions of reactive oxygen species were measured with fluorescent probes. P25's zeta potentials, measured in cell culture media and physiological buffer were -11.6 +/- 1.2 mV and -9.25 +/- 0.73 mV, respectively. P25 aggregation was rapid in both media and buffer with the hydrodynamic diameter of stable P25 aggregates ranging from 826 nm to 2368 nm depending on the concentration. The biological response of BV2 microglia to noncytotoxic (2.5-120 ppm) concentrations of P25 was a rapid (<5 min) and sustained (120 min) release of reactive oxygen species. The time course of this release suggested that P25 not only stimulated the immediate "oxidative burst" response in microglia but also interfered with mitochondrial energy production. Transmission electron microscopy indicated that small groups of nanosized particles and micron-sized aggregates were engulfed bythe microglia and sequestered as intracytoplasmic aggregates after 6 and 18 h exposure to P25 (2.5 ppm). Cell viability was maintained at all test concentrations (2.5-120 ppm) over the 18 h exposure period. These data indicate that mouse microglia respond to Degussa P25 with cellular and morphological expressions of free radical formation.     

Preparation and characterization of stable aqueous higher-order fullerenes

Stable aqueous suspensions of nC?? and individual higher fullerenes, i.e. C??, C?? and C??, are prepared by a calorimetric modification of a commonly used liquid-liquid extraction technique. The energy requirement for synthesis of higher fullerenes has been guided by molecular-scale interaction energy calculations. Solubilized fullerenes show crystalline behavior by exhibiting lattice fringes in high resolution transmission electron microscopy images. The fullerene colloidal suspensions thus prepared are stable with a narrow distribution of cluster radii (42.7 ± 0.8 nm, 46.0 ± 14.0 nm, 60 ± 3.2 nm and 56.3 ± 1.1 nm for nC??, nC??, nC?? and nC??, respectively) as measured by time-resolved dynamic light scattering. The ζ-potential values for all fullerene samples showed negative surface potentials with similar magnitude ( - 38.6 ± 5.8 mV, - 39.1 ± 4.2 mV, - 38.9 ± 5.8 mV and - 41.7 ± 5.1 mV for nC??, nC??, nC?? and nC??, respectively), which provide electrostatic stability to the colloidal clusters. This energy-based modified solubilization technique to produce stable aqueous fullerenes will likely aid in future studies focusing on better applicability, determination of colloidal properties, and understanding of environmental fate, transport and toxicity of higher-order fullerenes.     

Out-of-Plane Flexural Performance of GFRP-Reinforced Masonry Walls

The objective of this paper is to assess the out-of-plane flexural performance of masonry walls that are reinforced with glass fiber-reinforced polymers (GFRPs) rods, as an alternative for steel rebars. Eight 1?m×3?m full-scale walls were constructed using hollow concrete masonry units and tested in four-point bending with an effective span of 2.4 m between the supports. The walls were tested when subjected to increasing monotonic loads up to failure. The applied loads would represent out-of-plane loads arising from wind, soil pressure, or inertia force during earthquakes. One wall is unreinforced; another wall is reinforced with customary steel rebars; and the other six walls are reinforced with different amounts of GFRP reinforcement. Two of the GFRP-reinforced walls were grouted only in the cells where the rods were placed to investigate the effect of grouting the empty cells. The force-deformation relationship of the walls and the associated strains in the reinforcement were monitored throughout the tests. The relative performance of different walls is assessed to quantify the effect of different design variables. The range of GFRP reinforcement ratios covered in the experiments was used to propose a capacity diagram for the design of FRP-reinforced masonry walls similar to that of reinforced concrete elements.     

Evaluation of stress during and after sputter deposition of Cu and Ta films

The stress evolution of magnetron sputtered copper and tantalum films is presented for samples prepared at various sputtering pressures and powers. In-situ stress values were calculated using measurements from a Multi-beam Optical Stress Sensor (MOSS) system, while ex-situ stress values were calculated using measurements from a stylus profilometer. Extensive microstructural and surface analysis were performed by several techniques and related to the stress state of the film. The results demonstrate that during deposition, independent of the adatom mobility, the stress curves are initially compressive at low sputtering pressures, while at the highest sputtering pressure (1.4 Pa) the stress trend is always tensile. Meanwhile, the stress curves after deposition show a tensile trend for both materials at all sputtering pressures.     

Probabilistic safety assessment of self-centering steel braced frame

The main drawback of conventional braced frames is implicitly accepting structural damage under the design earthquake load, which leads to considerable economic losses. Controlled rocking self-centering system as a modern low-damage system is capable of minimizing the drawbacks of conventional braced frames. This paper quantifies main limit states and investigates the seismic performance of self-centering braced frame using a Probabilistic Safety Assessment procedure. Margin of safety, confidence level, and mean annual frequency of the self-centering archetypes for their main limit states, including PT yield, fuse fracture, and global collapse, are established and are compared with their acceptance criteria. Considering incorporating aleatory and epistemic uncertainties, the efficiency of the system is examined. Results of the investigation indicate that the design of low- and mid-rise self-centering archetypes could provide the adequate margin of safety against exceeding the undesirable limit-states.     

Comparative simulation of a fluidised bed reformer using industrial process simulators

A simulation model is developed by commercial simulators in order to predict the performance of a fluidised bed reformer. As many physical and chemical phenomena take place in the reformer, two sub-models (hydrodynamic and reaction sub-models) are needed. The hydrodynamic sub-model is based on the dynamic two-phase model and the reaction sub-model is derived from the literature. In the overall model, the bed is divided into several sections. In each section, the flow of the gas is considered as plug flow through the bubble phase and perfectly mixed through the emulsion phase. Experimental data from the literature were used to validate the model. Close agreement was found between the model of both ASPEN Plus (ASPEN PLUS 2004 ©) and HYSYS (ASPEN HYSYS 2004 ©) and the experimental data using various sectioning of the reactor ranged from one to four. The experimental conversion lies between one and four sections as expected. The model proposed in this work can be used as a framework in developing the complicated models for non-ideal reactors inside of the process simulators.     

Development of a simulation-based optimisation for controlling operation allocation and material handling equipment selection in FMS

Flexible manufacturing system (FMS) is described as a set of computerised numerical controlled machines, input–output buffers interconnected by automated material handling devices. This paper develops a bi-objective operation allocation and material handling equipment selection problem in FMS with the aim of minimising the machine operation, material handling and machine setup costs and maximising the machine utilisation. The proposed model is solved by a modified chaotic ant swarm simulation based optimisation (CAS²O) while applying pre-selection and discrete recombination operators is surveyed a capable method to simulate different experiments of FMS problems. A test problem is selected from the literature to evaluate the performance of the proposed approach. The results validate the effectiveness of the proposed method to solve the FMS scheduling problem.