Fabrication and characterization of MnO2 based composite sheets for development of flexible energy storage electrodes

Development of cost efficient, flexible and light weight paper electrodes for high-tech applications is high in demand in era of modern disposable technology. In this study α-MnO₂ nanorods were fabricated through hydrothermal method by varying growth time and further combined with lignocelluloses fibers extracted from self growing plant, Monochoria Vaginalis. Crystal structure, morphology and thermal properties of MnO₂ nanorods were characterized by X. Ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM) and Thermogravimetric Analysis (TGA), respectively. FESEM image analysis revealed the highest aspect ratio of 48.016 for 4?h treated MnO₂ sample and high purity level was confirmed by XRD. MnO₂ sample with high aspect ratio, relatively pure and larger yield was selected for incorporation of lignocelluloses fibers to fabricate flexible, light-weight and environmentally safe LC/MnO₂ composite paper sheet. Furthermore, LC/MnO₂ composite sheet was employed as working electrode in 2?M sodium sulfate electrolyte for cyclic voltammetry measurements. Presented LC/MnO₂ composite sheet revealed specific capacitances 117, 59, 39, 25 and 23?F/g at scan rates of 5, 10, 20, 50 and 100?mV/s, respectively. Incorporation of LC fibers within MnO₂ nanorods as binders will open the possibilities to fabricate the flexible paper electrode for application in supercapacitors and batteries due to facile synthesis, light-weight and environmentally friendly aspects.     

Modular Wavelet–Extreme Learning Machine: a New Approach for Forecasting Daily Rainfall

Water Resources Management - A rainfall forecasting method based on coupling wavelet analysis and a novel artificial neural network technique called extreme learning machine (ELM) is proposed. In...     

Simultaneously achievement of high recoverable energy density and efficiency in sodium niobate-based ceramics

Journal of Materials Science: Materials in Electronics - Single lead-free Na0.73Bi0.09(Nb1???xTax)O3 (x?=?0, 0.10, 0.20, 0.30, and 0.40) ceramic phases were processed...     

Corrosion-resistant polypyrrole-banana carbon (PPy-BC) nanocomposites for protection against electromagnetic interference: a green approach

Journal of Materials Science: Materials in Electronics - The article focuses on the suitability of electrically characterized polypyrrole-banana carbon (PPy-BC) nanocomposites for broadband...     

Intelligent Transmission Control for Efficient Operations in SDN

Although the Software-Defined Network (SDN) is a well-controlled and efficient network but the complexity of open flow switches in SDN causes multiple issues. Many solutions have been proposed so far for the prevention of errors and mistakes in it but yet, there is still no smooth transmission of pockets from source to destination specifically when irregular movements follow the destination host in SDN, the errors include packet loss, data compromise etc. The accuracy of packets received at their desired destination is possible if networks for pockets and hosts are monitored instead of analysis of network snapshot statistically for the state, as these approaches with open flow switches, discover bugs after their occurrence. This article proposes a design to achieve the said objective by defining the Intelligent Transmission Control Layer (ITCL) layer. It monitors all the connections of end hosts at their specific locations and performs necessary settlements when the connection state changes for one or multiple hosts. The layer informs the controller regarding any state change at one period and controller collects information of end nodes reported via ITCL. Then, updates flow tables accordingly to accommodate a location-change scenario with a route-change policy. ICTL is organized on prototype-based implementation using the popular POX platform. In this paper, it has been discovered that ITCL produces efficient performance in the trafficking of packets and controlling different states of SDN for errors and packet loss.     

An online resource allocation algorithm to minimize system interference for inband underlay D2D communications

This paper addresses the research question of total system interference minimization while maintaining a target system sum rate gain in an inband underlay device‐to‐device (D2D) communication. To the best of our knowledge, most of the state of the art research works exploit offline resource allocation algorithms to address the research problem. However, in Long‐Term Evolution (LTE) and beyond systems (4G, 5G, or 5G+), offline resource allocation algorithms do not comply with the fast scheduling requirements because of the high data rate demand. In this paper, we propose a bi‐phase online resource allocation algorithm to minimize the total system interference for inband underlay D2D communication. Our proposed algorithm assumes D2D pairs as a set of variable elements whereas takes the cellular user equipment (UEs) as a set of constant elements. The novelty of our proposed online resource allocation algorithm is that it incurs a minimum number of changes in radio resource assignment between two successive allocations among the cellular UEs and the D2D pairs. Graphical representation of the simulation results suggests that our proposed algorithm outperforms the existing offline algorithm considering number of changes in successive allocation for a certain percentage of sum rate gain maintaining the total system interference and total system sum rate very similar.     

Infrastructure‐based vehicular congestion detection scheme for V2I

With the increasing number of vehicles, traffic jam becomes one of the major problems of the fast‐growing world. Intelligent transportation system (ITS) communicates perilous warnings and information on forthcoming traffic jams to all vehicles within its coverage region. Real‐time traffic information is the prerequisite for ITS applications development. In this paper, on the basis of the vehicle‐to‐infrastructure (V2I) communication, a novel infrastructure‐based vehicular congestion detection (IVCD) scheme is proposed to support vehicular congestion detection and speed estimation. The proposed IVCD derives the safety time (time headway) between vehicles by using iterative content‐oriented communication (COC) contents. Meanwhile, the roadside sensor (RSS) provides an infrastructure framework to integrate macroscopic traffic properties into the estimation of both the traffic congestion and vehicle safety speed. The main responsibilities of RSS in IVCD are to preserve privacy, aggregate data, store information, broadcast routing table, estimate safety speed, detect traffic jam, and generate session ID (S‐ID) for vehicles. Monte Carlo simulations in four typical Chinese highway settings are presented to show the advantage of the proposed IVCD scheme over the existing Greenshield's and Greenberg's macroscopic congestion detection schemes in terms of the realized congestion detection performance. Real road traces generated by Simulation of Urban Mobility (SUMO) over NS‐3.29 are utilized to demonstrate that the proposed IVCD scheme is capable of effectively controlling congestion in both single and multilane roads in terms of density and speed health with previous schemes in this field.     

Zr‐Doped Indium Oxide (IZRO) Transparent Electrodes for Perovskite‐Based Tandem Solar Cells

Parasitic absorption in transparent electrodes is one of the main roadblocks to enabling power conversion efficiencies (PCEs) for perovskite‐based tandem solar cells beyond 30%. To reduce such losses and maximize light coupling, the broadband transparency of such electrodes should be improved, especially at the front of the device. Here, the excellent properties of Zr‐doped indium oxide (IZRO) transparent electrodes for such applications, with improved near‐infrared (NIR) response, compared to conventional tin‐doped indium oxide (ITO) electrodes, are shown. Optimized IZRO films feature a very high electron mobility (up to ≈77 cm² V^?1 s^?1), enabling highly infrared transparent films with a very low sheet resistance (≈18 Ω □^?1 for annealed 100 nm films). For devices, this translates in a parasitic absorption of only ≈5% for IZRO within the solar spectrum (250–2500 nm range), to be compared with ≈10% for commercial ITO. Fundamentally, it is found that the high conductivity of annealed IZRO films is directly linked to promoted crystallinity of the indium oxide (In₂O₃) films due to Zr‐doping. Overall, on a four‐terminal perovskite/silicon tandem device level, an absolute 3.5 mA cm^?2 short‐circuit current improvement in silicon bottom cells is obtained by replacing commercial ITO electrodes with IZRO, resulting in improving the PCE from 23.3% to 26.2%.