低碳结构钢的氢脆行为研究

采用宏观、微观、纳米等手段,开展低碳钢在酸性环境中氢诱导作用对其力学性能影响进行研究。从研究结果可以看出,氢浓度和腐蚀扩展速率存在一定关系,低碳钢暴露于富氢酸性环境28天后,体积弹性模量显著降低。通过微观结构分析,发现氢渗透引起的大晶粒的变形、裂纹和氢鼓包是性能下降的主要原因。此外,通过在不同时间对试样的不同区域进行纳米压痕,确定了氢对晶粒纳米弹性和纳米硬度性能的影响。在宏观、微观和纳米层面上对受到氢损伤钢的力学性能的进一步研究,将对低碳结构钢的维护和使用寿命预测提供一种新途径。     

利用介质超材料控制太赫兹波的振幅和相位

设计了基于介质高阻硅的超材料用于对太赫兹波的透射振幅和相位进行控制。这里组成超材料的基本结构单元为亚波长柱状硅,相比于基于金属的超材料,其损耗小,效率也更高。太赫兹入射到不同尺寸和旋向的柱状硅时,所透射的太赫兹波的振幅和相位也不同。通过设计不同空间位置处的柱状硅尺寸和旋向,就可以实现任意的振幅和相位分布,从而对透射波波前进行完全的控制。实验中,利用这种硅质微结构设计了三种不同的奇异光栅,其衍射级次和数目可任意控制。这种基于介质超材料的方法,设计简单,加工方便,在制作太赫兹波段低损耗的功能器件方面有着广泛的应用前景。     

钻井液用页岩防塌剂中磺化度测定方法的改进

磺化沥青中磺酸钠基含量为衡量其质量好坏的重要指标,其含量越高,性能越好。采用离子色谱与元素分析仪相结合,建立了1种快捷地测定磺化沥青中磺酸钠基含量的方法。此方法测定每个样品结果的相对标准偏差（RSD）均小于1%（n=5）,表明该方法具有良好重复性。经实验表明,此方法简单快速可靠,可便捷地应用于磺化沥青中磺酸钠基含量的测定。      

Sn含量对轧制Mg-6Bi-Sn合金组织演变和腐蚀性能的影响

研究了轧制态Mg-6Bi-xSn (x=0,1,2,3,%,质量分数) 4种合金的组织演变和腐蚀性能。结果表明：研究合金均表现出等轴晶组织和少量的孪晶组织,随着Sn含量的增加,平均晶粒尺寸分别为 (15.63±1.37),(13.71±1.15),(10.86±1.39) 和 (12.29±1.15) μm;第二相体积分数分别为 (3.56±0.06)%,(3.67±0.09)%,(3.76±0.36)%和 (9.58±0.69)%。另外,随着Sn含量的增加,腐蚀速率先减小再增大,这是因为晶粒细化和第二相颗粒增加竞争机制的结果,Mg-6Bi-2Sn合金由于其均匀的微观组织而表现出最佳的耐腐蚀性能。     

GaAs双光束耦合中的普克尔效应

本文报道在GaAs晶体中用1.15μm红外He—Ne激光进行相对传播的双光束耦合的实验研究,测量了透射光束偏振面的旋转角(?)与两束光强比β_0的关系,这些现象可归结于光感空间电荷电场引起的线性电光效应(普克尔效应)所造成。     

基于交互式图割算法的结肠组织提取

针对腹部CT医学图像中结肠组织自身局部特征的问题,研究了一种基于交互式Graph Cuts结肠组织的分割方法。首先人工标定一部分体素标记为＂目标＂和＂背景＂种子点。然后将图像映射成网络图,通过相邻像素间的灰度特征分配边的权重值,采用26邻域系统实现三维图像的分割。最后使用最大流/最小割方法最小化能量函数,得到结肠区域。实验结果表明,交互式的图割算法能够准确地从三维腹部CT医学图像中提取出结肠组织,体现了结肠数据的局部特征。算法能自动将所有腹部CT切片的结肠组织分割出来,实验获得的结果有利于结肠病变的发现和精确定位。     

多业务网络性能测试方法研究

由于多业务网络对各种业务进行了细分,并分别提供不同质量的服务,网络的复杂性大大提高。这不仅给网络配置增加了困难,也给网络性能测试带来了新的挑战。针对多业务网络的特点,本文详细分析了过载测试、多业务源负载生成、多业务相互作用测试和性能指标测量四个多业务网络性能测试的关键问题,从而给出了多业务网络性能测试的基本方法。     

Aqueous in-situ electrosynthesis and electrochromic performance of PEDOT:PSS/Reline film

Poly(3,4-ethylene dioxythiophene) (PEDOT) is a promising electrochromic material in many practical application, such as smart windows and displays. However, there are still difficulties in currently realizing green manufacturing, high coloration efficiency, and rapid response. Herein, in-situ electrochemical polymerization of PEDOT:PSS/Reline films was suggested in aqueous solution. Deep eutectic solvents (DES) composed of choline chloride and urea (Reline) were employed as green solvents in reaction system and used as dopants for the PEDOT:PSS. The as-prepared PEDOT:PSS/Reline films exhibited remarkable electrochromic properties, including great ion diffusion coefficient, fast reaction time (coloration response time was 1.4 s), prominent transmittance modulation (38%), high coloration efficiency (223 cm²/C) and excellent cyclic stability. Impressively, doping of Reline cannot only provide a green polymerization environment, but also significantly boost the electrochromic properties.     

Direct stamping and capillary flow patterning of solution processable piezoelectric polyvinylidene fluoride films

It is well known that the potential applications of polyvinylidene fluoride (PVDF) mainly come from the piezoelectricity and ferroelectricity of its polar β phase. Thus, we have investigated the effect of different preparation conditions namely evaporation temperature, type of solvent and additive to enhance the β crystal structures of PVDF thin film. Subsequently, facile and direct soft lithography technique; direct stamping and capillary flow were employed to demonstrate good pattern transfer of PVDF thin films. The piezoelectricity of the microstructure was characterized using piezoresponse force microscopy (PFM) where fairly good piezoresponse was obtained without further processing procedures i.e., annealing or applied pressure/electric field. As such, our solution processable and direct patterning of PVDF techniques offer facile and promising route to produce arrays of isolated microstructures with improved piezoelectric functionality.     

Preparation and properties of three novel poly(phosphazene‐aryl amide)s containing cyclotriphosphazene structures

1,1,3,5‐tetraphenoxy‐3,5‐bis(4‐aminoanilino)cyclotriphosphazene, 1,1,3,5‐tetraphenoxy‐3,5‐bis[4‐(4‐aminophenysulfone)anilino)]cyclotriphosphazene, and 1,1,3,5‐tetraphenoxy‐3,5‐bis(N,N′‐ethanediamine)cyclotriphosphazene were synthesized in two steps from the p‐Phenylenediamine, 4,4′‐diaminodiphenylsulfone, and ethylenediamine via nucleophilic substitution and catalytic reduction with hexachlorocyclotriphosphazene. Three novel aromatic polyamides such as poly(cyclotriphosphazene‐p‐phenylene amide), poly(cyclotriphosphazene‐p‐sulfuryl amide), and poly(cyclotriphosphazene‐ethyl amide) were synthesized from these diamines by direct polycondensation reaction with terephthaloyl chloride and pyridine in N‐methyl pyrrolidone, respectively. The chemical structures of the diamine monomers and three novel poly(cyclotriphosphazene‐aryl amide)s were characterized by Fourier Transform Infrared, (¹H and ³¹P) Nuclear Magnetic Resonance, and Elemental Analysis. The thermal properties of the polyamides were determined by Differential Scanning Calorimetry and Thermogravimetric Analysis (TGA). The crystallization behaviors of the polyamides were studied by Wide‐ray X‐ray diffraction, and the morphology of the pyrolysis residues were observed by Scanning Electron Microscope. The three poly(cyclotriphosphazene‐aryl amide)s with amorphous structure would exhibit an enhanced solubility in polar aprotic solvents and a superior thermal stability with initial decomposition temperature being at about 198–259°C. TGA curves of the poly(cyclotriphosphazene‐aryl amide)s exhibit mainly three thermal decomposition steps, and the poly(cyclotriphosphazene‐p‐phenylene amide) presents the highest solid residue rate 62.6% heated to 600°C. In the morphology analysis of the poly(cyclotriphosphazene‐aryl amide) solid residues, organophosphorus gelatum forms in the surface layer were observed. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013