受污染湖泊沉积物中氮素转化对有机污染物降解的促进效应与机制

目前有关硝化反应动力学及其共代谢降解有机污染物的研究多为实验室微生物纯培养体系,来源于野外环境样品的很少.以受污染湖泊严家湖1号塘沉积物为研究对象,野外钻探采样,并选取不同深度沉积物进行室内外加氮源的硝化实验.结果表明:表层土和钻井一处50～100 cm沉积物发生明显的硝化反应,同时有机污染物中六氯苯含量降低最多,分别...     

桥梁与隧道GPS网的设计与应用

计算了江阴公路长江大桥GPS网所能达到的精度,阐述了隧道GPS网布设的一般规律,对长梁山13km隧道实测GPS网进行了计算。从比较分析可以看出:1)GPS网能够满足桥梁和隧道工程的精度要求;2)在GPS网中适当加入一些高精度的边长有利于提高GPS网的精度和可靠性,并使得最后GPS网的尺度与施工测量时保持一致;3)GPS用于隧道与桥梁工程测量具有精度高、工期短、效益高等特点。     

旋转风螺旋度及其在暴雨演变过程中的作用

利用中尺度有限区域模式ＭＭ４对１９９１年７月５－６日的江淮梅雨锋暴雨过程进行了数值模拟,在模拟结果可靠的基础上,用模式输出的细多格动力协调资料,根据螺旋度理论分析了这次过程中的暴雨演变以及对流层低层的中尺度低涡及地面气旋发生发展的原因。结果表明,正在旋转风螺旋度大值中心及其演变较好地应和反映了暴雨中心及造成暴雨的中尺度涡旋的发生益及演变,较大的螺旋度值是暴雨及低层中尺度低涡和地面气旋系统发生发展的     

大兴安岭北部森林覆盖区植物化探找矿方法的新思路

大兴安岭北部森林覆盖区内白桦、落叶松分布广泛。以白桦、落叶松作为植物化探的主要研究对象具有可操作性和可推广性.植物的外皮、落叶是植物化探研究的首选.落叶松、白桦树叶的采集时间应在9月份叶落后不久,采样间距可在100~600m之间.松树、白桦树皮的采样时间集中在6月和9月两个阶段,采样间距在10~200m之间,采集的树皮距地约0.2m.建议采用干灰化法,最佳的灰化温度在450℃左右     

夹皮沟金矿深部成矿预测研究

系统研究了夹皮沟地区二道沟、庙岭、大猪圈、下戏台和东坨腰子等矿床矿体和近矿围岩微量元素、矿石矿物组合和黄铁矿热电系数等的垂直变化特征,认为三者具有相互一致的变化规律,即：与热液金矿床通常的分带性相比,具有逆向分带的现象,这种特征被认为是多层次正常分带上下叠加的产物,反映夹皮沟地区金矿床在垂向上普遍存在着多个富集地段.据此预测二道沟、庙岭、大猪圈、下戏台和东坨腰子等矿床在目前的开采深度下部仍有发现深部矿体的可能.     

浅析张集矿立井地面预注浆堵水效果

介绍了张集矿立井基岩段水文地质和基岩地面预注浆的有关情况。根据井简实测资料,分析基岩裂隙的发育规律、裂隙层界面的浆波充填情况、实际浆液有效扩散半径及堵水效果。认为：立井基岩地面预注浆,不仅能成功地起到堵水的自的．从而缩短工期、降低造价、提高质量,而且还有利于井筒安全揭穿突出谋层,达到安全施工。     

宁芜云台山黄铁矿矿床中黄铁矿矿物的初步研究

宁芜云台山黄铁矿矿床中黄铁矿矿物以自形晶为主 ,次为他形粒状 ;黄铁矿晶胞参数为 5 .415 2 3～ 5 .41843× 10 -10 m ,晶体化学式为 (Fe0 .9968Co0 .0 0 0 6Ni0 .0 0 2 6) 1.0 0 0 0 S2 .0 597;黄铁矿红外吸收光谱主吸收峰值为 34 8cm-1,最小透过率为 30 .0 0 %～ 48.80 % ,透过率极差为 31.13～ 47.5 1;黄铁矿中Fe平均含量为 45 .44 % ,S平均含量 5 3.91% ,具有富S特征 ;Co/Ni平均值为 0 .2 1;稀土元素总量平均为2 1.84× 10 -6,具有明显负铈异常 (δCe :0 .76～ 0 .93)和负铕异常 (δEu :0 .72～ 0 .90 ) ;硫同位素组成δ3 4S为 7.0 0‰～ 2 3.0 0‰ ,黄铁矿是含矿热液以堆积、充填和交代方式形成 ,黄铁矿床为火山热水沉积矿床。     

河南地磁短周期变化特征

为了研究河南地区地磁短周期变化的特征,１９９６年１０月至１１月在该地区布设了近似南北向的两条临时测线,东测线由河南信阳至汤阴,西测线由河南西峡至山西曲沃,在测线上进行了地磁短周期变化三分量的同步观测,在３ｍｉｎ至２ｈ周期范围内统计计算了各测点各周期成分的地磁垂直转换函数及水平转换函数,通过地磁转换函数的分析,给出了该地区地磁短周期变化空间,周期分布概况。西峡至曲沃测线,除曲沃外垂直分量没有出现反向     

Mössbauer effect study of anapaite, Ca2Fe2+(PO4)2 · 4H2O, and of its oxidation products

Mössbauer spectra (MS) of anapaite (Ca₂ Fe²⁺(PO₄)₂?·?4H₂O) and of a sample after being immersed in a 4% H₂O₂ solution at room temperature (RT) over 12 days (hereafter an4ox) were collected at temperatures in the range 4.2 to 420?K and 11 to 300?K respectively. All MS consist of symmetrical doublets, hence magnetic ordering was not observed. The temperature dependencies of the Fe²⁺ centre shifts of anapaite and an4ox were analysed with the Debye model for the lattice vibrations. The characteristic Mössbauer temperatures were found as 370?K?±?25?K and 340?K?±?25?K, and the intrinsic isomer shifts as 1.427?±?0.005?mm/s and 1.418?±?0.005?mm/s respectively. From the external-field (60?kOe) MS recorded at 4.2 and 189?K for the non-treated sample, the principal component V _zz of the electric field gradient (EFG) is determined to be positive and the asymmetry parameter η?≈?0.2 and 0.4 respectively. The temperature variations of the quadrupole splittings, ΔE _Q(T), cannot be interpreted on the basis of the thermal population of the ⁵ D electronic levels resulting from the tetragonal compression of the O₆ co-ordination. The low-temperature linear behaviour of ΔE _Q(T) is attributed to a strong orbit-lattice coupling. A field of 60 kOe applied to anapaite at 4.2?K produces magnetic hyperfine splitting with effective hyperfine fields of ?136, ?254 and ?171?kOe along the principal axes Ox, Oy and Oz of the EFG tensor respectively. Additional oxidation treatments in solutions with various H₂O₂ concentrations up to 20% and subsequent Mössbauer experiments at room temperature, have revealed that the anapaite structure is not sensitive to oxidation since eventually only a small amount of Fe²⁺ (～6.5%) is converted into Fe³⁺.     

Urbanization and sustainable metropolitan development in China: Patterns, problems and prospects*

The path of urbanization in the People's Republic of China is largely shaped by the nation's industrial development strategies. In the first three decades of socialist construction, and especially after the Sino-Soviet rift at the end of the 1950s, the adoption of strategies of self-reliance had led to urban biased patterns of development. The introduction of economic reforms and the open door policy in 1978 paved the way for and facilitated national economic development. Two issues, which feature significantly in the processes of development in China, are assessed. The first is the relationship between economic development and the protection of arable land. The second is the quest for a coordinated hyper-development in both urban and rural areas. This paper concludes by proposing a sustainable metropolitan development strategy that suits the case of China. This revised version was published online in July 2006 with corrections to the Cover Date.