The impact of uncertain emission trading markets on interactive resource planning processes and international emission trading experiments

Interactive resource planning is an increasingly important aspect of emission trading markets. The conferences of Rio de Janeiro, 1992, and Kyoto, 1997, originally focusing on environmental protection at both macro- and micro-economic levels, called for new economic instruments of this kind. An important economic tool in this area is Joint Implementation (JI), defined in Article 6 of the Kyoto Protocol. Sustainable development can be guaranteed only if JI is embedded in optimal energy management. In this contribution we describe and evaluate one international procedure within uncertain markets which helps to establish optimal energy management and interactive resource planning processes within uncertain emission trading markets.     

Sediment transport,biotic modifications and selection of grain size in a surface deposit-feeder

Deposit-feeders often select for particles on the basis of grain size. The available pool of particles at the sediment surface may be modified both by deposit-feeder activity and by sediment transport, but the effects of these alterations on deposit-feeder diet composition have received little attention. In laboratory experiments the spionid polychaeteParaprionospio pinnata altered the grain-size composition in its foraging area, and these alterations were reflected in grain-size changes in the diet. After simulated transport of fine-grain sediments,P. pinnata diets also changed in grain-size composition. Field data were collected from 9 m depth in the lower Chesapeake Bay. A video camera, deployed near the bottom, identified times of sediment transport over a 6-h Period;P. pinnata were collected concurrently for gut analysis. Consistent with predictions from the laboratory experiments,P. pinnata ingested primarily small-grain sizes. During periods of no sediment transport this feeding pattern reduced the relative availability of small particles; larger sediments were incorporated into the diet. Sediment transport may resupply the foraging area with fine-grain particles which are then incorporated into the diet. On these small spatial and time scales, deposit-feeder activity may affect the availability of food resources.     

Desertification in Africa — A critique and an alternative approach

This article critically reviews the international debate on desertification, its status and rate as well as causes and consequences. The article rejects the commonly used concept of a degrading environment, but tries to explain the environmental problems as symptoms of a wider economic and political crisis. An alternative approach applying systems analysis of the entire socio-economic-system to the study of desertification and land degradation is discussed, with examples from the Western Sudan.     

Cretaceous to Eocene sea-level fluctuations on the New Jersey margin

The New Jersey margin contains an extensive record of Cretaceous to Eocene sea-level fluctuations. These events have been documented on the basis of sedimentology, benthic foraminiferal paleobathymetry (paleoslope), biostratigraphic recognition of unconformities and their associated hiatuses, and on seismic reflection records. The record of sea-level change for the New Jersey margin shows a long-term (second-order) rise beginning in the upper Albian that is punctuated by numerous third-order cycles of change in the Upper Cretaceous, Paleocene, and Eocene. The sequences deposited during these cycles that are most readily recognizable, are separated by type 1 unconformities. Sequences bracketed by one or two type 2 unconformities are more difficult to resolve, although many have been identified. Sequences shown on the cycle chart of Haq et al. (1987) of less than 1 Ma duration are the most difficult to recognize and many have not been identified in the New Jersey section.

Benthic foraminiferal paleoslope studies indicate that relative sea-level rise on the New Jersey margin varied on the order of 10–120 m above present sea level. Much of the preserved record in the coastal plain consists of sediments deposited during rising sea level. This has led to a stacked record of sea-level rise events separated by unconformities.     

Solution chemistry studies and flotation behaviour of apatite,calcite and fluorite minerals with sodium oleate collector

The maximum flotation response for three naturally occurring calcium minerals, apatite, calcite and fluorite with sodium oleate collector correlated directly with the minimum interfacial tension of the air/solution interface. For fluorite and apatite the minimum surface tension occurred about the mid-pH region and was attributed to the formation of pre-micellar associated species in solution. In the case of calcite the minimum was observed at high pH since the presence of high concentrations of calcium ions in solution appeared to reduce the concentration of amphililic species in the low and mid-pH regions.Microelectrophoresis data demonstrated that the three minerals acquired a negative charge in sodium oleate solution, resulting from adsorption of oleate species on the mineral surfaces.The flotation behaviour of the systems were shown to be related to the species distribution diagrams suggesting that the role of the acid soap dimer, soap dimer, molecular and lattice species could make a significant contribution to the character and composition of the interfacial films.High flotation response was explained by strong adhesion between the hydrophobic particle and bubble. It was suggested that the reduction in surface tension may not be the major factor contributing to the flotation efficiency but indicated the presence of associated surfactant species in solution which could also synergistically adsorb at the solid/liquid interface, increasing the hydrophobic character of the mineral surface. This would maximize the magnitude of the contact angle and hence the strength of the adhesion between particle and bubble. This adsorption behaviour is not in general agreement with conventionally non-hydrolyzable collector theory which is usually based on electrostatic models.     

Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants,effective surface area,and the hydrolysis of feldspar

Analysis of experimental data reported by Lagache (1965, 1976), Evans (1965), Busenberg (1975), Busenberg and Clemency (1976), Holdren and Berner (1979), Siegel and Pfannkuch (1984), and Chou and Wollast (1984) with the aid of irreversible thermodynamics and transition state theory (Aagaard and Helgeson, 1977, 1982) suggests that at temperatures at least up to 650°C, the rate of both congruent and incongruent feldspar hydrolysis in aqueous solutions far from equilibrium at pH ? 10.6 ? (2300/T), where T stands for temperature in kelvins, is a function solely of effective surface area and pH at constant pressure and temperature. At higher pH, the rate is apparently pH-independent up to ~pH 8 at 25°C, where it again becomes pH-dependent at higher pH. Observations of scanning electron micrographs indicate that the cross-sectional area of etch pits on hydrolyzed feldspar grains is of the order of 10^?9 to 10^?8 cm² and that the ratio of the effective to total surface area (which may or may not change with reaction progress) ranges from <0.01 to 1, depending on the grain size, dislocation density, and the extent of comminution damage on the surfaces of the grains. Apparent rate constants retrieved from experimental data reported in the literature for feldspar hydrolysis in the lower pH-dependent range extend from ~10^?13 to ~10^?7 moles cm^?2 sec^?1 at temperatures from 25° to 200°C, which is consistent with activation enthalpies for albite and adularia of the order of 20 kcal mole^?1. In contrast, the apparent rate constants for the pH-independent rate law range from ~10^?16 to ~10^?11 moles cm^?2 sec^?1 at temperatures from 25° to 650°C, which requires an activation enthalpy for adularia of ~ 9 kcal mole^?1. These observations are consistent with surface control of reaction rates among minerals and aqueous solutions. The rate-limiting step in the pH-dependent case apparently corresponds at the lower end of the pH scale to breakdown of a protonated configuration of atoms on the surface of the reactant feldspar, but at higher pH the rate is limited by decomposition of an activated surface complex corresponding in stoichiometry to hydrous feldspar. In highly alkaline solutions, an activated complex containing hydroxyl ions apparently controls the rate of feldspar hydrolysis. Nevertheless, near equilibrium, regardless of pH the rate is proportional to the chemical affinity of the overall hydrolysis reaction.     

A review of mathematical models of river planform changes

Different mathematical models of river planform changes exist or are being developed. They are reviewed here by discussing a two-dimensional depth-averaged model, various meander models and a model for the braided Brahmaputra-Jamuna River in Bangladesh. Much emphasis is placed on topics where further research is needed. It is concluded that the models help in understanding the underlying processes, but cannot yet be considered generally valid and easy-to-use software packages. In the hands of experienced geomorphologists or river engineers, however, some of the models do already form valuable tools which allow better predictions of future river planforms.     

Rock bursting phenomena in a superficial rock mass in southern central Sweden

SummaryRock Bursting Phenomena in a Superficial Rock Mass in Southern Central Sweden Rock bursting phenomena have been observed in connection with excavation of two shallow sited rock tunnels in the Forsmark area in southern, central Sweden. The tunnels are excavated in gneiss granite and the rock cover varies between 5–15 m. The stress release occurred locally in the tunnels which indicates significant variations in rock stresses.In situ measurements of the triaxial stress situation carried out in the area show values of the principal stresses in the horizontal plane of a magnitude in excess of 20 MPa in the superficial rock mass. The rock stress measurements indicate a clear correspondence of the directions of the highest compressive stress and the rock foliation. There is also a clear correspondence between the directions of a vertical and a horizontal joint set and the highest compressive stress. The three-dimensional stress tensor indicates that the horizontal fractures are exposed to the smallest closure pressure, i. e. the vertical stress, which set should therefore be most open. The horizontal joint set in the superficial rock mass has a significantly higher value of aperture than the vertical sets which may be a consequence of the stress situation in the rock mass. The rock bursting is not attributed to a breakage of the rock matrix, but merely to a propagation of already existing small fractures and potential fractures. The stress situation in the Forsmark area may be regarded as an uniaxial stress field in the horizontal plane.With 12 Figures