Characterization of stabilized porous magnetite core–shell nanogel composites based on crosslinked acrylamide/sodium acrylate copolymers

Stabilized and dispersed superparamagnetic porous nanogels based on sodium acrylate (AA‐Na) and acrylamide (AM) in a surfactant‐free aqueous system were synthesized via solution polymerization at room temperature. The formation of magnetite nanoparticles was confirmed and their properties characterized using Fourier transform infrared spectroscopy. Extensive characterization of the magnetic polymer particles using transmission electron microscopy (TEM), dynamic light scattering and zeta potential measurements revealed that Fe₃O₄ nanoparticles were incorporated into the shells of poly(AM/AA‐Na). The average particle size was 5–8 nm as determined from TEM. AM/AA‐Na nanoparticles with a diameter of about 11 nm were effectively assembled onto the negatively charged surface of the as‐synthesized Fe₃O₄ nanoparticles via electrostatic interaction. Crosslinked magnetite nanocomposites were prepared by in situ development of surface‐modified magnetite nanoparticles in an AM/AA‐Na hydrogel. Scanning electron microscopy was used to study the surface morphology of the prepared composites. The morphology, phase composition and crystallinity of the prepared nanocomposites were characterized. Atomic force microscopy and argon adsorption–desorption measurements of Fe₃O₄.AM/AA indicated that the architecture of the polymer network can be a hollow porous sphere or a solid phase, depending on the AA‐Na content. © 2013 Society of Chemical Industry     

Large‐scale fading behavior for a cellular network with uniform spatial distribution

Large‐scale fading (LSF) between interacting nodes is a fundamental element in radio communications, responsible for weakening the propagation, and thus worsening the service quality. Given the importance of channel‐losses in general, and the inevitability of random spatial geometry in real‐life wireless networks, it was then natural to merge these two paradigms together in order to obtain an improved stochastical model for the LSF indicator. Therefore, in exact closed‐form notation, we generically derived the LSF distribution between a prepositioned reference base‐station and an arbitrary node for a multi‐cellular random network model. In fact, we provided an explicit and definitive formulation that considered at once: the lattice profile, the users' random geometry, the effect of the far‐field phenomenon, the path‐loss behavior, and the stochastic impact of channel scatters. The veracity and accuracy of the theoretical analysis were also confirmed through Monte Carlo simulations.     

Low end‐to‐end delay fuzzy networking protocol for mobile wireless sensing

Because of the practical limitations of the energy and processing capabilities, the deployment of many Wireless Sensor Networks (WSN) is facing two main challenges of increasing network lifetime and reducing End to End Delay (EED) which become critical when the nodes are mobile and use non‐rechargeable energy sources. One way to help to extend network lifetime is using fuzzy logic in a form of artificial intelligence. To this end we propose a new routing protocol for using mobile WSNs, which holds the nodes in an equal level of energy and decreases energy dissipation of the network. An optimum path is selected based on the cost of each node to increase network lifetime. In order to lessen EED, we also attempt to design a novel zoning‐scheme for the network area. In this scheme, zonation is dynamic and works based on the Data Link (DL) position. The simulation result shows a significant improvement in lifetime and EED by proposed protocol compared with existing protocols. Copyright © 2016 John Wiley & Sons, Ltd.     

Supertough (Polyamide 6)/(acrylonitrile butadiene rubber) nano alloy through in situ polymerization of caprolactam in the presence of acrylonitrile butadiene rubber nanophase

In this work, polymerization of caprolactam (CL) was carried out in the presence of acrylonitrile butadiene rubber (NBR) during the reactive melt‐mixing process. During shear mixing, NBR particles swelled and dissolved in the molten CL, which led to separation and distribution of rubber particles to nanoscale in the dissolution stage. Then, in an internal mixer, supertough Polyamide 6 was prepared via melt polymerization of CL/NBR mixture, sodium caprolactam as a catalyst, and hexamethylene diisocyanate as an activator. The effects of various concentrations of catalyst and activator on the initiation time of the reaction were determined. Physical and mechanical properties of different formulations prepared via reactive melt blending were determined by tensile and impact measurements, differential scanning calorimetry, Fourier‐transform infrared spectroscopy, X‐ray scattering techniques, transmission electron microscopy, and dynamic mechanical thermal analysis. Experimental results showed that a recipe with 3% nitrile rubber in a CL/NBR mixture enhances the physical and mechanical properties the best, compared with other formulations. This condition led to the formation of NBR nanospheres during melt polymerization of Polyamide 6 as well. J. VINYL ADDIT. TECHNOL., 21:116–121, 2015. © 2014 Society of Plastics Engineers     

Nodular structure of isotactic polypropylene crystallizes from the melt

This article highlights the melt crystallization behavior of different grades of isotactic polypropylene (iPP) using a hot‐stage polarizing optical microscopy. iPP samples were heated up at a heating rate of 10°C/min passing the melting temperature and then kept for 3 min at a temperature range of 175–200°C before they cooled rapidly at 40°C/min to crystallize isothermally at a range of 130–145°C. It has been found that the temperature at which the samples were kept has a strong effect on the crystallization mode; for samples heated up and kept at temperatures below 190°C, the crystallization started with thin and long rods or nodules, which grew in the circumferential direction only while their lengths remain unchanged as the time passed. The shape of the nodules can be straight, circular, branched, or entangled, and they can grow parallel to each other or they can be crossed or in a random way. This phenomenon disappeared completely for samples melted and kept at temperatures above 195°C. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Operations research/management science in the Arab world: historical development

This study aims to review the related literature on operations research (OR)/management science (MS) in the Arab world published during the last three decades. Owing to the nature of this study, an extensive survey of the related literature was conducted and inferences were drawn. The inferences drawn from the literature survey on OR/MS in the Arab world were first, there is a paucity of published real‐world applications of OR/MS. Second, there is a lack of published survey‐type studies in most Arab countries, except in Jordan, Lebanon, Palestine, Syria, and the United Arab Emirates. Third, the majority of published works on OR/MS were of a conceptual nature. A few papers concerned with OR/MS in the Arab world were published during the 1980s, with a special emphasis on conceptual issues rather than on applied or survey‐type studies. The 1990s witnessed an increased number of publications on both survey‐type and conceptual studies. Since 2000, the number of publications has increased substantially, mainly through conceptual studies. This study has a number of implications for both practitioners and researchers. Practitioners will be made aware of the applications of OR/MS in the Arab world and the type of problems that have been addressed. This, in turn, might motivate the decision makers and the managers to adopt OR/MS approaches in solving their organizations' problems. As a result, this might increase the usage of OR/MS in this part of the world. Researchers will be able to identify the OR/MS research areas that need more attention in the Arab world. The study mainly covers the studies that are written in English and indexed in non‐Arabic databases. Although the Arabic works were not surveyed exhaustively, the author reviewed and included some available OR/MS works written in Arabic. This study is considered as the first work of its type in surveying the scholarly publications pertaining to OR/MS in the Arab world since the 1980s.     

Application of ozone for enhancing the microbiological safety and quality of foods: a review.

Ozone (O3) is a strong antimicrobial agent with numerous potential applications in the food industry. High reactivity, penetrability, and spontaneous decomposition to a nontoxic product (i.e., O2) make ozone a viable disinfectant for ensuring the microbiological safety of food products. Ozone has been used for decades in many countries and recently, the generally recognized as safe (GRAS) status of this gas has been reaffirmed in the United States. Ozone, in the gaseous or aqueous phases, is effective against the majority of microorganisms tested by numerous research groups. Relatively low concentrations of ozone and short contact time are sufficient to inactivate bacteria, molds, yeasts, parasites, and viruses. However, rates of inactivation are greater in ozone demand-free systems than when the medium contains oxidizable organic substances. Susceptibility of microorganisms to ozone also varies with the physiological state of the culture, pH of the medium, temperature, humidity, and presence of additives (e.g., acids, surfactants, and sugars). Ozone applications in the food industry are mostly related to decontamination of product surface and water treatment. Ozone has been used with mixed success to inactivate contaminant microflora on meat, poultry, eggs, fish, fruits, vegetables, and dry foods. The gas also is useful in detoxification and elimination of mycotoxins and pesticide residues from some agricultural products. Excessive use of ozone, however, may cause oxidation of some ingredients on food surface. This usually results in discoloration and deterioration of food flavor. Additional research is needed to elucidate the kinetics and mechanisms of microbial inactivation by ozone and to optimize its use in food applications.     

Cyanoethylation of Hydroxyethyl Cellulose: Preparation and Characterization

Commercial hydroxyethyl cellulose (HEC) was cyanoethylated with acrylonitrile in nonaqueous medium in the presence of sodium hydroxide under a variety of conditions. Variables studied included the amount of acrylonitrile and the reaction temperature. The reaction was proved by NMR and its extent was measured by determining the nitrogen content. The physical properties of the obtained derivatives—i.e., the electric properties and the apparent viscosity at various rates of shear—were investigated. It was found that the extent of reaction was increased by increasing the amount of acrylonitrile as well as the reaction temperature. The products were water soluble and their apparent viscosity increased with increasing nitrogen content. The same holds true for the dielectric constant and dielectric loss.     

Ability of adaptive filters to track carrier offsets and channelnonstationarities

This paper studies the tracking performance of adaptive filters operating in the presence of two sources of nonstationarities: carrier frequency offsets and random channel variations. Both impairments are common in digital communications due to mismatches between transmitter and receiver carrier generators and channel fading. The paper derives expressions for the mean-square error and shows how filter performance is degraded under such nonstationary conditions. Selections of step sizes for optimal tracking performance are derived, different adaptive algorithms are compared, and supporting simulation results are provided