LiNi₁/₃Co₁/₃Mn₁/₃O₂-graphene composite as a promising cathode for lithium-ion batteries

The use of graphene as a conductive additive to enhance the discharge capacity and rate capability of LiNi(1/3)Co(1/3)Mn(1/3)O(2) electrode material has been demonstrated. LiNi(1/3)Co(1/3)Mn(1/3)O(2) and its composite with graphene (90:10 wt %) were prepared by microemulsion and ball-milling techniques, respectively. The structural and morphological features of the prepared materials were investigated with powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. Characterization techniques depict single-phase LiNi(1/3)Co(1/3)Mn(1/3)O(2) with particle sizes in the range of 220-280 nm. Electrochemical studies on LiNi(1/3)Co(1/3)Mn(1/3)O(2) and LiNi(1/3)Co(1/3)Mn(1/3)O(2)-graphene were conducted using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy methods by constructing a lithium half-cell. Cyclic voltammograms show the well-defined redox peaks corresponding to Ni(2+)/Ni(4+). Charge-discharge tests were performed at different C rates: 0.05, 1, and 5 between 2.5 and 4.4 V. The results indicate the better electrochemical performance of the LiNi(1/3)Co(1/3)Mn(1/3)O(2)-graphene composite in terms of high discharge capacity (188 mAh/g), good rate capability, and good cycling performance compared to LiNi(1/3)Mn(1/3)Co(1/3)O(2). The improved electrochemical performance of the LiNi(1/3)Co(1/3)Mn(1/3)O(2)-graphene composite is attributed to a decrease in the charge-transfer resistance.     

Involvement of sensory neurons in bone defect repair in rats

We investigated bone repair in sensory-denervated rats, compared with controls, to elucidate the involvement of sensory neurons. Nine-week-old male Wistar rats received subcutaneous injections of capsaicin to denervate sensory neurons. Rats treated with the same amount of vehicle served as controls. A standardized bone defect was created on the parietal bone. We measured the amount of repaired bone with quantitative radiographic analysis and the mRNA expressions of osteocalcin and cathepsin K with real-time polymerase chain reaction (PCR). Quantitative radiographic analysis showed that the standard deviations and coefficients of variation for the amount of repaired bone were much higher in the capsaicin-treated group than in the control group at any time point, which means that larger individual differences in the amount of repaired bone were found in capsaicin-treated rats than controls. Furthermore, radiographs showed radiolucency in pre-existing bone surrounding the standardized defect only in the capsaicin-treated group, and histological observation demonstrated some multinuclear cells corresponding to the radiolucent area. Real-time PCR indicated that there was no significant difference in the mRNA expression levels of osteocalcin and cathepsin K between the control group and the capsaicin-treated group. These results suggest that capsaicin-induced sensory denervation affects the bone defect repair.     

A novel approach to a fine particle coating using porous spherical silica as core particles

The applicability of porous spherical silica (PSS) was evaluated as core particles for pharmaceutical products by comparing it with commercial core particles such as mannitol (NP-108), sucrose and microcrystalline cellulose spheres. We investigated the physical properties of core particles, such as particle size distribution, flow properties, crushing strength, plastic limit, drying rate, hygroscopic property and aggregation degree. It was found that PSS was a core particle of small particle size, low friability, high water adsorption capacity, rapid drying rate and lower occurrence of particle aggregation, although wettability is a factor to be carefully considered. The aggregation and taste-masking ability using PSS and NP-108 as core particles were evaluated at a fluidized-bed coating process. The functional coating under the excess spray rate shows different aggregation trends and dissolution profiles between PSS and NP-108; thereby, exhibiting the formation of uniform coating under the excess spray rate in the case of PSS. This expands the range of the acceptable spray feed rates to coat fine particles, and indicates the possibility of decreasing the coating time. The results obtained in this study suggested that the core particle, which has a property like that of PSS, was useful in overcoming such disadvantages as large particle size, which feels gritty in oral cavity; particle aggregation; and the long coating time of the particle coating process. These results will enable the practical fine particle coating method by increasing the range of optimum coating conditions and decreasing the coating time in fluidized bed technology.     

A real-time inspection system using a terahertz technique to detect microleak defects in the seal of flexible plastic packages

A method to detect production faults in flexible plastic packages with the use of terahertz radiation is presented. Relying on the large difference between the absorption coefficients of plastic and water (for water-filled channel defects) and on the refraction index difference between plastic and air (for air-filled channel defects), our technique consists of focusing and scanning a terahertz beam on the sealed area of the package, followed by detection of the transmitted signal. Compared with previous methods, such as visual and ultrasound inspection, our technique can be applied to optically opaque packages and does not require immersion in a matching liquid. We tested our system on defects that we fabricated as water-filled and air-filled channels imbedded in polyethylene films, with diameters in the range of 10 to 100 microm. The detection limit (the minimum size of a detectable defect) depends on the conveying speed; this relationship was determined and analyzed. The results show that our system has the potential for application in an actual production line for real-time inspection.     

Antioxidant activity of a hydrothermal extract from watermelons

In this study, the antioxidant activity of hydrothermal extracts of different parts of watermelons (flesh, white rind, and green rind) was evaluated. Each part of the watermelons was extracted at temperatures ranging from 100 °C to 300 °C for 10, 30, or 60 min. The highest total phenol content was observed for the green rind extracted at 300 °C for 30 min with 7626.52 μg gallic acid equivalents (GAE)/g, whereas the phenol content of the untreated green rind extract was 715.15 μg GAE/g. The antioxidant activity of the watermelon parts increased with increase in treatment temperature and time. In GC–MS analysis, catechol, 4-methylcatechol, pyrogallol, and 1,2,4-benzenetriol were detected after hydrothermal extraction at 300 °C for 30 min. These results indicate that hydrothermal extraction is an efficient process for increasing the antioxidant activity of watermelon extracts.     

Toward a real-world knowledge medium: Building a guidance system for exhibition tours

We propose a notion of a real-world knowledge medium by presenting our ongoing project to build a guidance system for exhibition tours. In order to realize a knowledge medium usable in the real world, we focus on the context-awareness of users and their environments. Our system is a personal mobile assistant that provides visitors touring exhibitions with information based on their spatial/temporal locations and individual interests. We also describe an application of knowledge sharing used in the actual exhibition spaces. Yasuyuki Sumi, Ph.D.: He has been a researcher at ATR Media Integration & Communications Research Laboratories since 1995. His research interests include knowledge-based systems, creativity supporting systems, and their applications for facilitating human collaboration. He received his B. Eng. degree from Waseda University in 1990, and M. Eng. and D. Eng. degrees in information engineering from the University of Tokyo in 1992 and 1995, respectively. He is a member of Institutes of Electronics, Information and Communication Engineers (IEICE) of Japan, the Information Processing Society of Japan (IPSJ), the Japanese Society for Artificial Intelligence (JSAI), and American Association for Artificial Intelligence (AAAI). Kenji Mase, Ph.D.: He received the B.S. degree in Electrical Engineering and the M.S. and Ph.D. degrees in Information Engineering from Nagoya University in 1979, 1981 and 1992 respectively. He has been with ATR (Advanced Telecommunications Research Institute) Media Integration & Communications Research Laboratories since 1995 and is currently the head of Department 2. He joined the Nippon Telegraph and Telephone Corporation (NTT) in 1981 and had been with the NTT Human Interface Laboratories. He was a visiting researcher at the Media Laboratory, MIT in 1988–1989. His research interests include image sequence processing of human actions, computer graphics, computer vision, artificial intelligence and their applications for computer-aided communications and human-machine interfaces. He is a member of the Information Processing Society of Japan (IPSJ), Institutes of Electronics, Information and Communication Engineers (IEICE) of Japan and IEEE Computer Society.     

Improvements of numerical stability of electromagnetic transient simulation by use of phase‐domain synchronous machine models

The present paper proposes the use of a phase‐domain (abc frame) generator model in electromagnetic transient analysis instead of the conventional dq0‐domain generator model in order to improve numerical stability. The drawback of the conventional dq0‐domain machine model is that the prediction of a number of electrical variables as well as machine speed is needed in order to interface the circuit of a machine model with the rest of the power system network, and the prediction of these variables leads to numerical instability. In contrast, prediction of electrical variables is not needed in the proposed phase‐domain model. In this paper, the phase‐domain machine model is developed. The proposed model is validated by comparisons with an existing EMTP type‐59 machine model. The paper makes it clear that numerically stable solutions are obtained by using the proposed model even in cases where numerical instabilities occur when the existing type‐59 model is used. © 1999 Scripta Technica, Electr Eng Jpn, 128(3): 53–62, 1999     

Design and calibration of curved and see-through integral imaging 3D display

Virtual Reality - Heads-up displays that are ‘see-through’ and ‘curved’ and capable of displaying 3D contents are considered crucial for augmented reality-based navigation...     

Bio-Inspired Adhesive with Reset-On Demand,Reuse-Many (RORM) Modes

Development of tough, reusable adhesives is important, but remains a major challenge, especially in water. A tough reusable adhesive that resets entirely to its virgin condition when needed is reported using caffeic acid. Here, caffeic acid is employed as adhesive moiety to achieve such the functions due to its dual characteristics: an adhesive moiety from mussel-inspired catechol and a photo-reversible crosslink from cinnamic acid. Adhesion involves a two-step process. First, the caffeic acid-functionalized polymer is applied to the adherend, followed by UV irradiation (peak wavelength of light-emitting diode, λ_P: 365 nm) to form a durable pre-applied adhesive (PAA) layer through crosslinking among the caffeic acid moieties. Second, thermal activation of the PAA layer ensures repeated adhesion to a variety of adherends ( R euse- M any mode). The cyclic dimer of the caffeic acid moiety is de-crosslinked by UV irradiation at λ_P: 254 nm. This allows the complete removal of the adhesive residues from the adherends when the adhesive is no longer needed ( R eset- O n demand mode). Furthermore, using magnetic nanoparticles, the caffeic acid-functionalized polymer can be activated remotely under water by magnetic induction heating. This study paves the way for the rational design of bio-inspired adhesives that outperform nature using plant-derived raw materials.