莫来石纤维多孔陶瓷的制备与性能

对纤维多孔陶瓷的制备及性能进行了研究。在制备纤维多孔陶瓷时,采用酸性磷酸铝A23(P/Al原子比为2 3)作粘结剂,所制备的多孔陶瓷在各方面都具有优良的性能。如导热系数λ(22℃)为0.0529W/m.℃、热膨胀系数α为4.75×10-6/℃、孔隙率为96.22%、容重为0.1142 g/cm3等。在环保、节能领域具有广泛的应用前景和重要的社会及经济意义。     

基于匹配策略融合的低误差快速图像拼接算法

针对目前多数拼接算法正确匹配率低、耗时及误差大的问题,提出了基于匹配策略融合的改进图像拼接算法。该算法首先仅在图像的重合区域提取SIFT特征点,并计算SURF特征描述符;其次,融合改进的最近邻比次近邻、双向交叉检查及匹配差值的阈值化3种匹配策略,结合坐标约束及RANSAC算法完成特征匹配;最后,提出利用配准参数计算任意图像到参考图像坐标空间的投影变换模型的方法,并利用多线程技术将所有图像投影至参考坐标系,经过亮度校正、加权融合后合成全景图。实验结果表明,提出的拼接算法正确匹配率提高了10~20%,拼接总耗时约为传统逐帧扩大式拼接算法的1/3,且累计误差大大降低,拼接图像畸变小。     

处理硝基苯类废水的Fenton催化氧化技术研究现状

硝基苯类化合物是高毒性物质,难以生物降解且对生化反应有抑制和毒害作用.因此,硝基苯对环境的污染问题越来越受到科学研究者的关注.目前,采用Fenton氧化技术降解硝基苯类化合物的机理和工艺研究越来越活跃.作者就近几年来国内外Fenton催化氧化技术降解硝基苯类废水的研究现状进行了综述.     

基于资源分配网络的小数据集并行集成学习方法

机器学习领域中,如何在小规模的训练数据集上获得一个具有稳定的高计算精度的算法模型,一直以来都是一个棘手而富有挑战的问题。从算法模型出发,提出了一种基于扩展卡尔曼滤波器的资源分配网络并行集成学习方法。该集成系统由多个带有扩展卡尔曼滤波器的资源分配网络（RANEKF）组成,并且每个RANEKF子网的输入由原始数据集中的输入经过随机权值的修正得到。通过和其他神经网络构成的集成学习算法的实验对比,发现提出的方法在小训练集上拥有更高的计算精度和稳定性。     

3,5-二氯苯甲酸的合成

考察了在以邻氨基苯甲酸为原料，三氯化铁为催化剂，X为溶剂，直接通氯氯化，再经重氮化合物3，5－二氯苯甲酸的工艺过程中，物料配比，反应湿度等反应条件对收率的影响，确定了合成的适宜条件，通过此合成工艺，产品的收率可达85％以上。     

Optimal control of molecular motion: design, implementation, and inversion

This paper reviews recent theoretical and experimental developments aimed at controlling molecular motion using tailored laser fields. Emphasis is given to seeking optimal designs for the laser controls and optimal implementation of the controls in the laboratory. Optimization on both counts provides a rigorous, flexible, and physically attractive means for obtaining the best possible control over molecular motion under any specified conditions. The theoretical design and laboratory implementation of control are best effected by a closed-loop process that draws on observations of the evolving molecular sample to steer it toward the desired target. Going beyond control, similar closed-loop laboratory learning concepts may lead to automated molecular monitors for inversion to systematically identify details of molecular Hamiltonians.     

硫化胶制样技术对红外光谱分析的影响

样品粒径对硫化胶网络主链α－亚甲基浓度影响较大，但对侧甲基浓度影响甚微。样品粒径减小会导致样品严重氧化，因此压片法红外光谱分析要严格控制样品粒径。样品浓度对分析结果也有较大影响。在样品粒径小于２μｍ、样品与溴化钾质量比为（１～５）：１０００时，可获得较为理想的红外光谱图。     

Catalytic cracking of 1-butene to propene and ethene on MCM-22 zeolite

Catalytic cracking of butene to propene and ethene was investigated over HMCM-22 zeolite. The performance of HMCM-22 zeolite was markedly influenced by time-on-stream (TOS) and reaction conditions. A rapid deactivation during the first 1 h reaction, followed by a quasi-plateau in activity, was observed in the process along with significant changes in product distributions, which can be attributed to the fast coking process occurring in the large supercages of MCM-22.

Properly selected reaction conditions can suppress the secondary reactions and enhance the production of propene and ethene. According to the product distribution under different butene conversion, we propose a simple reaction pathway for forming the propene, ethene and by-products from butene cracking.

HMCM-22 exhibited similar product distribution with the mostly used high silica ZSM-5 zeolite under the same conversion levels. High selectivities of propene and ethene were obtained, indicating that the 10-member ring of MCM-22 zeolite played the dominant role after 1 h of TOS. However, MCM-22 exhibited lower activity and stability than that on high silica ZSM-5 zeolite with longer time-on-stream.     

林可霉素生产废水处理站的改造

对某林可霉素生产废水处理站进行了改造.为提高废水的可生化性,增设了水解调节池,好氧生化工艺改为AB法;对于废水中难于生物降解的有机物,采用Fenton氧化法处理,药剂投加量以出水水质达标为目标.处理站改造的工程投资为96.0万元,改造后的运行成本为3.36元/m3.     

Consolidation of Nano-Sized TiN Powders by Spark Plasma Sintering

Nano-sized TiN powders with an average particle size of 19 nm were synthesized via a new method, reduction–nitridation reaction in liquid ammonia. A consolidation procedure using spark plasma sintering (SPS) was used, and a dense TiN ceramic (>98% of theoretical) with mean grain size of 100–150 nm was obtained at 1380°C. The influence of sintering temperature on grain growth and microstructural evolution was also discussed.