首页 | 官方网站   微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   173046篇
  免费   18223篇
  国内免费   10840篇
工业技术   202109篇
  2024年   926篇
  2023年   2962篇
  2022年   5951篇
  2021年   8113篇
  2020年   6052篇
  2019年   4672篇
  2018年   5201篇
  2017年   6161篇
  2016年   5329篇
  2015年   7913篇
  2014年   9911篇
  2013年   11633篇
  2012年   13548篇
  2011年   14038篇
  2010年   12991篇
  2009年   12171篇
  2008年   12004篇
  2007年   11320篇
  2006年   10251篇
  2005年   7995篇
  2004年   5583篇
  2003年   4707篇
  2002年   4526篇
  2001年   3991篇
  2000年   3177篇
  1999年   2523篇
  1998年   1603篇
  1997年   1310篇
  1996年   1216篇
  1995年   1044篇
  1994年   850篇
  1993年   525篇
  1992年   425篇
  1991年   309篇
  1990年   248篇
  1989年   211篇
  1988年   147篇
  1987年   98篇
  1986年   92篇
  1985年   39篇
  1984年   37篇
  1983年   24篇
  1982年   33篇
  1981年   41篇
  1980年   46篇
  1979年   26篇
  1977年   9篇
  1976年   10篇
  1959年   11篇
  1951年   16篇
排序方式: 共有10000条查询结果,搜索用时 17 毫秒
71.
韦永德 《金属学报》1979,15(4):559-562
<正> 本文试图从化学键理论出发,探讨石墨球化的规律。鉴于用键参数图法总结与化学键有关的规律性往往见效,故本文从球化剂元素和反球化元素在键参数图中的分布规律入手进行研究。 球化剂元素(或反球化元素)对石墨球化的影响应与该元素和C_(石墨)间的相互作用有关,其键参数函数写成如下形式:  相似文献   
72.
热压变形对灰口铸铁石墨形态的影响   总被引:2,自引:0,他引:2  
研究了灰口铸铁(HTl50)在900℃大压下量塑性变形后石墨的分布形态,结果表明:随着压下量的增加,石墨片逐渐趋于平行分布;变形过程中发生了碳的回溶,同时伴随着石墨片的断裂;石墨片体积分数及片间距随压下量的增加而逐渐减少。  相似文献   
73.
有限元方法在离心机转鼓强度分析中的应用   总被引:14,自引:2,他引:14  
谭蔚  王泽军  朱企新 《化工机械》2002,29(2):103-107
在回顾以往转鼓强度分析的基础上 ,指出了目前转鼓有限元应力分析所存在的问题 ,给出了提高计算精度和保证模拟有效性的注意事项 ,并探讨了转鼓强度评定准则  相似文献   
74.
A mathematical model for flowthrough (perfusion) chromatography, namely packed-microtubes (PMT) model, has been proposed for a column packed with biporous (BiP) anion exchanger in which the mesopores and flowthrough pores are created with liquid and solid porogens, respectively. The model is established based on the assumption that the BiP particle is made up of packed microtubes. Bovine serum albumin (BSA) is used as a model protein and three kinds of anion exchangers (i.e., mesoporous, macroporous and BiP resins) are used as adsorbents to determine the model parameters and to evaluate the model. Adsorption equilibrium and finite bath experiments are performed to determine the adsorption isotherms and kinetics parameters. Both the bound amounts of the protein on the surface of the mesopores and macropores are experimentally determined and taken into account in the mathematical model. With all the model parameters determined by independent experiments or calculated from available correlations, model simulations are performed and compared with the experimentally determined breakthrough profiles of the BiP column. It is found that the model predictions agree reasonably well with the experimental data obtained under various conditions and the PMT model fit experimental data better than the modified double linear driving force (LLDF) model proposed by Leitão and Rodriogues (1999. Biochemical Engineering Journal 3, 131) in which the adsorbent particle is considered to be made up of packed microparticles. The results indicate that the PMT model is more reasonable for this kind of BiP adsorbent.  相似文献   
75.
王雪  李伟  刘天鹤 《轮胎工业》2004,24(3):152-155
在中试装置上合成相对分子质量分布较宽的充油S-SBR,考察不同环烷油和芳烃油填充量的充油S-SBR的流变性能和混炼行为。结果表明,增大油的填充量能提高充油S-SBR的流动性能,充芳烃油S-SBR相对于充环烷油的S-SBR对温度更敏感,宽相对分子质量分布的充环烷油S-SBR的混炼性能优于S-SBR1204及E-SBRl778,竟相对分子质量分布的充芳烃油S-SBR的混炼性能优于S-SBR1204,Solprene380和E-SBR1712。  相似文献   
76.
The secure operation of autonomous vehicle networks in the presence of adversarial observation is examined, in the context of a canonical double-integrator-network (DIN) model. Specifically, we study the ability of a sentient adversary to estimate the full network’s state, from noisy local measurements of vehicle motions. Algebraic, spectral, and graphical characterizations are provided, which indicate the critical role of the inter-vehicle communication topology and control scheme in achieving security.  相似文献   
77.
加成型高强度硅橡胶   总被引:4,自引:0,他引:4  
  相似文献   
78.
An isothermal model for hydrodemetallation (HDM) of crude oils in catalytic fixed-bed reactors is proposed. This model involves a consecutive reaction mechanism, which is capable of accounting for particle deposit profiles with interior maxima. Consistent with the fact that HDM catalysts are conglomerates formed by precipitation, the porous catalyst itself is modeled as randomly overlapping spheres of equal size. The metal is deposited as growing metal sulfide crystallites on the inner surface of the catalyst. These crystallites originate from a certain number of randomly scattered nuclei and increase in size as the deposition proceeds. The random sphere model for the catalyst and the deposit provides the changes in the catalyst pore structure—local porosity and surface area.

The mass transport within the domain of the particle is due to restricted liquid diffusion, since the diameter of the metal bearing compound (porphyrin) and the intermediate are comparable to the pore size. The diffusion restrictions taken into account are the enhanced drag imposed on a molecule by adjacent pore walls and steric partitioning.

Since the deposition process is much slower than diffusion and reaction, the pseudo-steady-state assumption can be justified. The equations of conservation for mass are solved by orthogonal collocation on finite elements. Based on this solution technique a computer simulation program of HDM is designed that allows two modes of operation: constant temperature and constant conversion. The simulation program “SIMULA” is highly flexible with regard to reaction kinetics, catalyst structure, reactor design, and operating conditions. In comparison to a base case with uniform activity, the effect of intraparticle (radial) and bed (axial) activity profiles on the conversion rate is discussed. For the case investigated, a radial distribution of activity higher at the center of the particle than at the edge can increase catalyst life by 25%, but axial distribution was less successful.  相似文献   
79.
荧光染料用于涤纶织物染色的荧光性能研究   总被引:4,自引:0,他引:4  
杨文芳  周微 《染料与染色》2004,41(4):206-208
在实验条件下,染色织物的荧光反射率随荧光染料的浓度增加而增加,超过一定浓度后,有下降趋势;在pH=5左右,荧光反射率最高;荧光增白剂会提高染色织物的荧光反射率,在荧光黄2GFL中,当荧光增白剂的浓度由0.1%增加到5%时,荧光反射率由8.43增加至18.59,而对非荧光染料只有增艳的作用,不产生荧光。荧光染料染色织物的荧光反射率随着加入非荧光染料量的增加而减弱。  相似文献   
80.
Gas phase propylene epoxidation on gold catalysts has attracted wide attention from industry and academia due to its high selectivity. However, it suffers from low propylene conversion and rapid catalyst deactivation. Experiments showed that propylene conversion could be increased by raising H2, O2, or C3H6 concentration in the feed, but the feed compositions were within the explosion limit. It was also shown that the activity of the used catalyst could be fully recovered, but the regeneration temperature was 280 °C, much higher than that for reaction. Therefore a microchannel reactor was devised to suppress explosion and was constructed with Fecralloy, to raise the temperature rapidly for catalyst regeneration by electric heating. In two minutes the temperature of the reactor could be raised from 50 to 300 °C. Catalysts were coated on the alloy belt by dip coating, and the performance of the reactor was evaluated under different operating conditions. Results showed that in the microreactor the overall reaction rate was controlled mainly by the intrinsic reaction rate, and also influenced by film diffusion to a certain extent. The deactivated catalyst was regenerated in the microchannel reactor and the activity was fully recovered.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司    京ICP备09084417号-23

京公网安备 11010802026262号