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41.
Cellulase cross‐linked enzyme aggregates (CLEA) activities can be modulated and enhanced by precipitant selection 下载免费PDF全文
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Nabarun Roy Tuli Dey Subhas C. Kundu Anil K. Bhowmick 《Journal of Materials Science》2013,48(15):5132-5139
Silicone elastomers have the potential to be a valuable biomaterial due to their mechanical and chemical properties, easy processing, and high gas permeability. Some inherent properties of the pure silicone implant such as high hydrophobicity and low load bearing capacity can be problematic for biomedical applications. The issues were addressed by fabricating hydroxyapatite nanofiber/polydimethylsiloxane nanocomposites. The morphology of nanocomposite structures was visualized by high resolution transmission electron microscopy and field emission scanning electron microscopy. Improved mechanical strength and compliance of the prepared nanocomposite structures were obtained by frequency sweep and creep measurements. Surface hydrophilicity of polydimethylsiloxane was enhanced by hydroxyapatite nanofiber incorporation into the polymer matrix. The cytotoxicity and biocompatibility of the structures were analyzed using breast epithelial cells (MDA MB 231 cell line). These studies showed that the nanocomposite scaffold did not leach any cytotoxic material and showed better cell adhesion and cell proliferation compared to the unfilled elastomer. 相似文献
44.
Perforation resistance of five different high-strength steel plates subjected to small-arms projectiles 总被引:1,自引:0,他引:1
Thin plates of high-strength steel are frequently being used both in civil and military ballistic protection systems. The choice of alloy is then a function of application, ballistic performance, weight and price. In this study the perforation resistance of five different high-strength steels has been determined and compared against each other. The considered alloys are Weldox 500E, Weldox 700E, Hardox 400, Domex Protect 500 and Armox 560T. The yield stress for Armox 560T is about three times the yield stress for Weldox 500E, while the opposite yields for the ductility. To certify the perforation resistance of the various targets, two different ballistic protection classes according to the European norm EN1063 have been considered. These are BR6 (7.62 mm Ball ammunition) and BR7 (7.62 mm AP ammunition), where the impact velocity of the bullet is about 830 m/s in both. Perforation tests have been carried out using adjusted ammunition to determine the ballistic limit of the various steels. In the tests, a target thickness of 6 mm and 6 + 6 = 12 mm was used for protection class BR6 and BR7, respectively. A material test programme was conducted for all steels to calibrate a modified Johnson–Cook constitutive relation and the Cockcroft–Latham fracture criterion, while material data for the bullets mainly were taken from the literature. Finally, results from 2D non-linear FE simulations with detailed models of the bullets are presented and the different findings are compared against each other. As will be shown, good agreement between the FE simulations and experimental data for the AP bullets is in general obtained, while it was difficult to get reliable FE results using the Lagrangian formulation of LS-DYNA for the soft core Ball bullet. 相似文献
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Manjima Bhattacharya Riya Chakraborty Arjun Dey Ashok Kumar Mandal Anoop Kumar Mukhopadhyay 《Ceramics International》2013,39(2):999-1009
The present experiments were focused on nanoindentation behaviour and the attendant “micro-pop-in” in a dense (~95% of theoretical) coarse-grain (~20 μm) alumina ceramic as a function of loading rate variations at three constant peak loads in the range of 105–106 μN. Based on the experimental results here we report for the first time, to the best of our knowledge, an increase in intrinsic nano scale contact resistance as well as the nanohardness with the loading rate. These observations were explained in terms of the correlation between the nanoscale plasticity and shear stress active just underneath the nanoindenter. 相似文献
47.
Anal Tarafder Atiar Rahaman Molla Chirantan Dey Basudeb Karmakar 《Journal of the American Ceramic Society》2013,96(8):2424-2431
The precursor glass in the ZnO–Al2O3–B2O3–SiO2 (ZABS) system doped with Eu2O3 was prepared by the melt‐quench technique. The transparent willemite, Zn2SiO4 (ZS) glass–ceramic nanocomposites were derived from this precursor glass by a controlled crystallization process. The formation of willemite crystal phase, size, and morphology with increase in heat‐treatment time was examined by X‐ray diffraction (XRD) and field‐emission scanning electron microscopy (FESEM) techniques. The average calculated crystallite size obtained from XRD is found to be in the range 18–70 nm whereas the grain size observed in FESEM is 50–250 nm. The refractive index value is decreased with increase in heat‐treatment time which is caused by the partial replacement of ZnO4 units of ZS nanocrystals by AlO4 units due to generation of vacancies. Fourier transform infrared (FTIR) reflection spectroscopy was used to evaluate its structural evolution. Vickers hardness study indicates marked improvement of hardness in the resultant glass‐ceramics compared with its precursor glass. The photoluminescence spectra of Eu3+ ions exhibit emission transitions of 5D0→7Fj (j = 0, 1, 2, 3, and 4) and its excitation spectra show an intense absorption band at 395 nm. These spectra reveal that the luminescence performance of the glass–ceramic nanocomposites is enhanced up to 17‐fold with the process of heat treatment. This enhancement is caused by partitioning of Eu3+ ions into glassy phase instead of into the willemite crystals with progress of heat treatment. Such luminescent glass–ceramic nanocomposites are expected to find potential applications in solid‐state red lasers, phosphors, and optical display systems. 相似文献
48.
We have recently reported upon the development of crosslinked urethane-doped polyester (CUPE) network elastomers, which was motivated by the desire to overcome the drawbacks presented by crosslinked network polyesters and biodegradable polyurethanes for soft tissue engineering applications. Although the effect of the isocyanate content and post-polymerization conditions on the material structure-property relationship was examined in detail, the ability of the diol component to modulate the material properties was only studied briefly. Herein, we present a detailed report on the development of CUPE polymers synthesized using diols 4, 6, 8, 10, or 12 methylene units in length in order to investigate what role the diol component plays on the resulting material's physical properties, and assess their long-term biological performance in vivo. An increase in the diol length was shown to affect the physical properties of the CUPE polymers primarily through lowered polymeric crosslinking densities and elevated material hydrophobicity. The use of longer chain diols resulted in CUPE polymers with increased molecular weights resulting in higher tensile strength and elasticity, while also increasing the material hydrophobicity to lower bulk swelling and prolong the polymer degradation rates. Although the number of methylene units largely affected the physical properties of CUPE, the choice of diol did not affect the overall polymer cell/tissue-compatibility both in vitro and in vivo. In conclusion, we have established the diol component as an important parameter in controlling the structure-property relationship of the polymer in addition to diisocyanate concentration and post-polymerization conditions. Expanding the family of CUPE polymers increases the choices of biodegradable elastomers for tissue engineering applications. 相似文献
49.
Riya Chakraborty Arjun Dey Anoop Kumar Mukhopadhyay 《Metallurgical and Materials Transactions A》2010,41(5):1301-1312
To understand how hardness, the key design parameter for applications of brittle solids such as glass concerning contact deformation,
is affected by loading rate variation, nanoindentation with a Berkovich tip was used to measure the nanohardness of a 330-μm-thick soda-lime-silica glass as a function of loading rate (1 to 1000 mN·s−1). The results showed for the very first time that, with variations in the loading rate, there was a 6 to 9 pct increase in
the nanohardness of glass up to a threshold loading rate (TLR), whereafter it did not appreciably increase with further increase
in loading rate. Further, the nanohardness data showed an indentation size effect (ISE) that obeyed the Meyer’s law. These
observations were explained in terms of a strong shear stress component developed just beneath the nanoindenter and the related
shear-induced deformation processes at local microstructural scale weak links. The significant or insignificant presence of
shear-induced serrations in load depth plots and corresponding scanning electron microscopic evidence of a strong or mild
presence of shear deformation bands in and around the nanoindentation cavity supported such a rationalization. Finally, a
qualitative picture was developed for different deformation processes induced at various loading rates in glass. 相似文献
50.
Tailoring the local flow field around a fin can substantially enhance the forced convection heat transfer from a conventional heat sink. A fin is set into oscillation leading to rupture of the thermal boundary layer developed on either side of the fin. This enhancement in heat transfer is demonstrated through an increase in the time-averaged Nusselt Number (Nu) on the fin surfaces. Nu has been found to be strongly dependent on the flow Reynolds Number (Re), the frequency and amplitude of the fin oscillations. A threshold amplitude and frequency is identified beyond which Nu improvements are observed for fixed Re. 相似文献