Rapid exploration of unknown areas through dynamic deployment of mobile and stationary sensor nodes

When an emergency occurs within a building, it may be initially safer to send autonomous mobile nodes, instead of human responders, to explore the area and identify hazards and victims. Exploring all the area in the minimum amount of time and reporting back interesting findings to the human personnel outside the building is an essential part of rescue operations. Our assumptions are that the area map is unknown, there is no existing network infrastructure, long-range wireless communication is unreliable and nodes are not location-aware. We take into account these limitations, and propose an architecture consisting of both mobile nodes (robots, called agents) and stationary nodes (inexpensive smart devices, called tags). As agents enter the emergency area, they sprinkle tags within the space to label the environment with states. By reading and updating the state of the local tags, agents are able to coordinate indirectly with each other, without relying on direct agent-to-agent communication. In addition, tags wirelessly exchange local information with nearby tags to further assist agents in their exploration task. Our simulation results show that the proposed algorithm, which exploits both tag-to-tag and agent-to-tag communication, outperforms previous algorithms that rely only on agent-to-tag communication.     

Spatio-Temporal Modeling in Video and Multimedia Geographic Information Systems

The geographic application domain includes important information such as design plans, record drawings, photographs, and video data records. The corresponding geographic information systems (GISs) should maintain a specific model for each geographic data modality such as geographic video model for video records. Real-time 3-D geographic information systems provide comprehensive interface to complex and dynamic databases and truly immersive capability for visualizing geographic data. In cases, where information about location of geographic objects is needed at different moments of time, a GIS should process video data that is directly manipulated and retrieved through representation of its spatio-temporal characteristics. In this context, the most advanced multimedia form—digital video, finds an efficient application in GIS for versatile specification of geographic data. In this paper, a model for spatial data evolving with time is introduced in the context of video data manipulation. We designed a model that represents the spatio-temporal continuum among geographic objects in geographic video sequences, or digital video. The model developed here was motivated by the requirements for manipulating, managing, and analyzing geographic data for the necessities of infrastructure management, urban and regional planning, hazard prevention and management, transportation networks, vehicles routing, etc. This model allows the important issues for GIS such as conditions of adjacency (what is next to what), containment (what is enclosed by what), and proximity (how close one geographic object is to another) to be determined. Our model describes the spatial relationships among objects for each key frame in a given video scene, and the temporal relationships of the temporal intervals measuring the validity duration of the spatial relationships spanning over the given key frame. One of the main GIS issues—distance estimation, is solved as quantitative metrics of geographic objects in digital video are easily and precisely specified. This model is a basis for annotation of raw video for subsequent use in geographic video databases and digital libraries that provide access to and efficient storage of large volume of geographic data.     

Growth and electrical properties of ZnO thin films deposited by novel ion plating method

The URT(Uramoto-gun with Tanaka magnetic field)-IP(ion plating) method is a technique for depositing a thin film on a substrate. This method offers the advantage of low-ion damage, low deposition temperatures, large area deposition and high growth rates. Ga-doped ZnO thin films were grown using the URT-IP method, and the material properties were evaluated. The quality of ZnO thin films grown by the URT-IP method was found to be sensitive to oxygen supply during growth. It was observed that the saturation point of the growth rate corresponding to the optimum oxygen supply leads to the best electrical properties. The profiles of the dependence of film properties on oxygen supply revealed a part of growth mechanism of the URT-IP method.     

Acrolein is a product of lipid peroxidation reaction. Formation of free acrolein and its conjugate with lysine residues in oxidized low density lipoproteins

Lipoprotein peroxidation, especially the modification of apolipoprotein B-100, has been implicated to play an important role in the pathogenesis of atherosclerosis. However, there have been few detailed insights into the chemical mechanism of derivatization of apolipoproteins during oxidation. In the present study, we provide evidence that the formation of the toxic pollutant acrolein (CH2=CH-CHO) and its conjugate with lysine residues is involved in the oxidative modification of human low density lipoprotein (LDL). Upon incubation with LDL, acrolein preferentially reacted with lysine residues. To determine the structure of acrolein-lysine adduct in protein, the reaction of acrolein with a lysine derivative was carried out. Employing Nalpha-acetyllysine, we detected a single product, which was identified to be a novel acrolein-lysine adduct, Nalpha-acetyl-Nepsilon-(3-formyl-3,4-dehydropiperidino )lysine. The acid hydrolysis of the adduct led to the derivative that was detectable with amino acid analysis. It was revealed that, upon in vitro incubation of LDL with acrolein, the lysine residues that had disappeared were partially recovered by Nepsilon-(3-formyl-3, 4-dehydropiperidino)lysine. In addition, we found that the same derivative was detected in the oxidatively modified LDL with Cu2+ and that the adduct formation was correlated with LDL peroxidation assessed by the consumption of alpha-tocopherol and cholesteryl ester and the concomitant formation of cholesteryl ester hydroperoxide. Enzyme-linked immunosorbent assay that measures free acrolein revealed that a considerable amount of acrolein was released from the Cu2+-oxidized LDL. Furthermore, metal-catalyzed oxidation of arachidonate was associated with the formation of acrolein, indicating that polyunsaturated fatty acids including arachidonate represent potential sources of acrolein generated during the peroxidation of LDL. These results indicate that acrolein is not just a pollutant but also a lipid peroxidation product that could be ubiquitously generated in biological systems.     

Oxidative degradation of polymers. II. Thermal oxidative degradation of atactic polypropylene in solution under pressure

Atactic polypropylene was oxidized in solution in the presence and absence of radical initiator over the temperature range of 140° to 200°C under oxygen pressure of 3.3 to 12.4 kg/cm², and the effects of metal catalyst and additives on the rate, products, and change in molecular weight distribution were measured. The synergistic effect was observed with cobalt and managanese salts. The deactivation of the metal catalyst was suppressed by the addition of acetic acid and acetic anhydride as solvent. The rate of oxidation increased with increasing temperature, but the decrease in molecular weight was nevertheless not so significant as to give many low-boiling products. However, the production of mixtures of acid, ketone, alcohol, and ester with molecular weights of several hundreds was promising. The refractive index of polypropylene decreased markedly as the oxidation proceeded, and the complications involved in the determination of the change in molecular weight distribution measured by gel permeation chromatography are discussed.     

Using Logical Rings to Solve the Distributed Mutual Exclusion Problem with Fault Tolerance Issues

In this paper, we investigate distributed mutual exclusion algorithms and delineate the features of a new distributed mutual exclusion algorithm. The basis of the algorithm is the logical ring structure employed in token-based mutual exclusion algorithms. Specifically, there exists dynamic properties of the logical ring that, given certain restrictions regarding message traffic flow, passively give useful information about the location of the token. Effectively, the algorithm demonstrates a type of intelligent routing that identifies useful shortcuts in the routing of the token. The result is a reduction in the total number of messages exchanged prior to the execution of the critical section as compared to the algorithm proposed by Fu and Tzeng [3]. Furthermore, the algorithm allows for an increased degree of fairness in a lightly loaded system than that allowed by Fu and Tzeng's algorithm. The paper also addresses failure recovery issues.     

Long life sealed nickel-zinc cell using a new separator

Because of internal shorting due to zinc (Zn) dendrite formation at the Zn electrode, nickel-zinc (NiZn) secondary cell cycle life is somewhat less than the NiCd cell cycle life. To solve this problem, a new kind of separator was developed which consisted of nylon non-woven cloth coated with poly(vinyl alcohol) (PVA) containing boric acid. This separator has a high ionic conductivity, but is resistant to zincate ion penetration. A large number of additives, effective for Zn dendrite suppression, was also tested. From them, bismuth oxide (Bi₂O₃) was selected and added, together with calcium hydroxide (Ca(OH)₂), to the Zn electrode. A charging method, applying an intermittent anodic pulse, was found to be effective to reduce the Zn electrode shape change and prolong the cycle life of this cell. By using these materials and investigating a cell construction containing an electrolytic solution and hydrogen gas absorber, sizes AA, C, and D sealed NiZn cells were developed whose charging and discharging cycle life achieved over 500 cycles, for a size C cell.     

Electrical and magnetic properties of rare-earth sulfides, (Sm1−xGdx)3S4

Electrical and magnetic properties of mixed-valence rare-earth sulfides, (Sm_1?xGd_x)₃S₄, were investigated. The valence transition from trivalent to divalent samarium ions takes place gradually with increasing gadolinium concentration. In the range between x=0.80 and x=0.85, a drastic change from semiconducting to metallic conduction was observed. This phenomenon is explained by the valence change of the samarium ion in the solid solution. A mechanism of the conduction in the semiconducting sulfide is an electron hopping between Sm²⁺ and Sm³⁺ sites, and that in the metallic sulfide is a band conduction through conduction electrons. A maximum in the resistivity vs temperature curve for a metallic sample appeared near its Curie temperature. This behavior was found to result from the formation of magnetic polarons.     

Social value creation through digital activism in an online health community

The study explores how online health communities produce social value by uniting individuals under a common purpose, to advance healthcare in post‐conflict states. We selected MedicineAfrica – a digital platform known for creating social value by providing medical education in regions with under‐resourced healthcare systems – and drew on multiple data collection methods. We found that it is through a unique form of digital health activism that social value is created in this context. Drawing on a sociological understanding of digital health activism, we make the following contributions: First, we identify three types of non‐economic, social value: cognitive, professional and epistemic. Second, we indicate that social value creation is enabled by three emergent forms of digital health activism (ie, philanthropic, moral and reciprocal activity). Third, we elicit three enabling mechanisms explaining how these forms of activism are technically and socially afforded through the platform's connective capacity and emerging collective practices in tandem with its members' growing commitment. Our article contributes to the growing IS literature on digital activism by offering a framework that elucidates how digital health activism relates to social value creation. The article provides practical implications as to how platforms can enable sustainable online (health) communities.     

Mobile learning object authoring tool and management system for mobile ad hoc wireless networks

Mobile learning can augment formal education and bridge the gap between formal and informal education by creating extended learning communities using any digital technology in connected or infrastructure‐less environments. With the use of ad hoc networks and mobile authoring tools, we can now create an ‘on‐the‐fly’ learning scenario, where learners can create, share, and view content from their mobile devices without the need for server–client or infrastructure‐based liaisons. Mobile learning, however, is not just about sharing content or learning using mobile, wireless, and portable devices. Rather, it is learning across spatiotemporal contexts that enables learners to form knowledge and understanding in different scenarios. When facing limited resources stemming from the characteristics of mobility and wireless technologies, determining the best practices for content creation and delivery becomes a challenge. This paper describes the architecture of a mobile‐focused learning network designed so that learning tools, activities, contexts, and interactions are created as necessary over time and space while adhering to traditional learning object standards. Copyright © 2015 John Wiley & Sons, Ltd.