The main goal of the present study is to prepare a titania membrane with high permeability and photocatalytic activity for environmental applications. In this investigation a mesoporous titania multilayer membrane on alumina substrate is successfully fabricated via the sol–gel processing method. The prepared titania polymeric sol for the membrane top layer has an average particle size of 11.7 nm with a narrow distribution. The resulting TiO2 multilayer membrane exhibits homogeneity with no cracks or pinholes, small pore size (4 nm), large specific surface area (83 m2/g), and small crystallite size (10.3 nm).The permeability and photocatalytic properties of the titania membrane were measured. The photoactivity of the titania membrane was examined to be 41.9% after 9 h UV irradiation based on methyl orange degradation. This measurement indicates high photocatalytic activity per unit mass of the catalyst. Through multilayer coating procedure, the photocatalytic activity of the membrane improved by 60% without sacrificing the membrane permeation. The prepared TiO2 photocatalytic membrane has a great potential in developing high efficient water treatment and reuse systems due to its multifunctional capability such as decomposition of organic pollutants and physical separation of contaminants. 相似文献
Following on from Part I of this review article that focuses on the suitability of Er3+-doped tellurium oxide glass for optical amplification in fiber, this Part II article describes how the fiber gain data were then employed to engineer amplification in waveguides, which can be integrated with semiconductor pump sources. The gain characteristics and bandwidth of a phosphate modified tellurite waveguide formed on a GaAs substrate are discussed. The limiting structural compatibility of Er3+-doped tellurite glass with polydimethylsiloxane polymer for active–passive integration is overcome by adopting a nanoscale super-lattice approach for waveguide engineering. 相似文献
Conductive nanofibers have been considered as one of the most interesting and promising candidate scaffolds for cardiac patch applications with capability to improve cell–cell communication. Here, we successfully fabricated electroconductive nanofibrous patches by simultaneous electrospray of multiwalled carbon nanotubes (MWCNTs) on polyurethane nanofibers. A series of CNT/PU nanocomposites with different weight ratios (2:10, 3:10, and 6:10wt%) were obtained. Scanning electron microscopy, conductivity analysis, water contact angle measurements, and tensile tests were used to characterize the scaffolds. FESEM showed that CNTs were adhered on PU nanofibers and created an interconnected web‐like structures. The SEM images also revealed that the diameters of nanofibers were decreased by increasing CNTs. The electrical conductivity, tensile strength, Young's modulus, and hydrophilicity of CNT/PU nanocomposites also enhanced after adding CNTs. The scaffolds revealed suitable cytocompatibility for H9c2 cells and human umbilical vein endothelial cells (HUVECs). This study indicated that simultaneous electrospinning and electrospray can be used to fabricate conductive CNT/PUnanofibers, resulting in better cytocompatibility and improved interactions between the scaffold and cardiomyoblasts. 相似文献
The separation of water from diesel fuel is very important for safety, ecological, and economic reasons, as otherwise it can lead to lower combustion efficiency and engine problems. In addition, the free water from ultra‐low‐sulfur diesel (ULSD) can only be insufficiently separated with the classic separation systems. To solve this problem, a membrane process with different organic/inorganic membranes for the selective separation of water droplets from ULSD and an innovative water‐in‐oil online sensor were developed. 相似文献
Non-biodegradability and disposal problems are the major challenges associated with synthetic plastic packaging. This review article discusses a new generation of biodegradable active and smart packaging based on porous nanomaterials (PNMs), which maintains the quality and freshness of food products while meeting biodegradability requirements. PNMs have recently gained significant attention in the field of food packaging due to their large surface area, peculiar structures, functional flexibility, and thermal stability. We present for the first time the recently published literature on the incorporation of various PNMs into renewable materials to develop advanced, environmentally friendly, and high-quality packaging technology. Various emerging packaging technologies are discussed in this review, along with their advantages and disadvantages. Moreover, it provides general information about PNMs, their characterization, and fabrication methods. It also briefly describes the effects of different PNMs on the functionality of biopolymeric films. Furthermore, we examined how smart packaging loaded with PNMs can improve food shelf life and reduce food waste. The results indicate that PNMs play a critical role in improving the antimicrobial, thermal, physicochemical, and mechanical properties of natural packaging materials. These tailor-made materials can simultaneously extend the shelf life of food while reducing plastic usage and food waste. 相似文献
In the present study, green tea extract was encapsulated in liposomes based on the Mozafari method (with no organic solvents) and characterized for its physicochemical properties (encapsulation efficiency, particle size, and Z-potential). Encapsulation efficiency, particles size, and Z-potential were determined to be 51.34, 419 nm, and -57 mV, respectively. Total polyphenol content of the green tea by Folin-Ciocalteu's phenol reagent was measured as 164.2 mg gallic acid/g extract. Free radical scavenging activities of free and liposomal extracts were 90.6 and 93.4%, respectively, using the DPPH method. Antioxidant activity of the ethanolic extract of green tea in free and liposomal forms with concentrations of 200, 600, and 1000 mg L−1 were assessed on oxidative stability of the canola oil at 60 °C for 0, 4, 8, 12, 16, 20, 24, 28, and 32 days. Results were compared to results of synthetic antioxidant butylated hydroxytoluene at 200 mg L−1. To assess antioxidant activity on canola oil stability, peroxide, thiobarbitoric acid, and anisidine values were assessed as well as the total oxidation value and rancimat test. Results showed that the liposomal green tea extract was more effective than the free extract. Furthermore, a 600 mg L−1 concentration of the green tea extract showed a significant antioxidant activity, compared to other extract concentrations. Increasing storage time and various concentrations of the ethanolic green tea extracts included significant effects on canola oil stability (P ≤ 0.05). Results demonstrated that the green tea extract could be used as an effective antioxidant. Free and liposomal extract (at 600 mg L−1) resulted in stronger functionality than the synthetic antioxidant butylated hydroxytoluene. 相似文献
Material behavior beyond the elastic limit can be rate-dependent, and this rate sensitivity can be captured by the viscoplastic material models. To describe the viscoplastic material behavior in structural analysis, an efficient numerical framework is necessary. In this paper an algorithm is proposed for metals for which von Mises yield surface along with Peri?’s viscoplastic model is employed. The efficiency and accuracy of the technique is examined by comparison with different numerical studies. The convergence rate of the proposed algorithm is investigated. Characteristics of the viscoplastic behavior such as relaxation are illustrated in the selected case studies. Finally, application of the algorithm in practice is demonstrated by a boundary value problem.