Thermal–economic–environmental analysis and multi-objective optimization of an internal-reforming solid oxide fuel cell–gas turbine hybrid system

In this article, an internal-reforming solid oxide fuel cell–gas turbine (IRSOFC–GT) hybrid system is modeled and analyzed from thermal (energy and exergy), economic, and environmental points of view. The model is validated using available data in the literature. Utilizing the genetic algorithm optimization technique, multi-objective optimization of modeled system is carried out and the optimal values of system design parameters are obtained. In the multi-objective optimization procedure, the exergy efficiency and the total cost rate of the system (including the capital and maintenance costs, operational cost (fuel cost), and social cost of air pollution for CO, NO_x, and CO₂) are considered as objective functions. A sensitivity analysis is also performed in order to study the effect of variations of the fuel unit cost on the Pareto optimal solutions and their corresponding design parameters. The optimization results indicate that the final optimum design chosen from the Pareto front results in exergy efficiency of 65.60% while it leads to total cost of 3.28 million US$ year⁻¹. It is also demonstrated that the payback time of the chosen design is 6.14 years.     

Stability analysis of shallow tunnels subjected to eccentric loads by a boundary element method

In this paper, stress behavior of shallow tunnels under simultaneous non-uniform surface traction and symmetric gravity loading was studied using a direct boundary element method(BEM). The existing fullplane elastostatic fundamental solutions to displacement and stress fields were used and implemented in a developed algorithm. The cross-section of the tunnel was considered in circular, square, and horseshoe shapes and the lateral coefficient of the domain was assumed as unit quantity. Double-node procedure of the BEM was applied at the corners to improve the model including sudden traction changes. The results showed that the method used was a powerful tool for modeling underground openings under various external as well as internal loads. Eccentric loads significantly influenced the stress pattern of the surrounding tunnel. The achievements can be practically used in completing and modifying regulations for stability investigation of shallow tunnels.     

Effect of Various On-Farm Water Management Scenarios on Equity and Productivity in Irrigation Networks

This research investigated the optimum on-farm water management methods for a summer crop (Maize). Water equity and productivity were optimized simultaneously by using genetic algorithms in Doroodzan Irrigation Network. Increase in water reduction fraction (WRF) (0.0 to 0.8) has the incremental effect on water equity (on average 19.4 %), however by increasing WRF, water productivity initially increased (on average 25.3 % at WRF?=?0.4) and then decreased. With increasing irrigation application efficiency (E_a) (40 to 90 %), the values of water equity and productivity increased by on average 52.8 and 91.5 %, respectively. Increment of conveyance efficiency of channels (E_c) (70 to 90 %) resulted in minimum incremental effect on water equity and productivity (on average 18.5 and 11.9 %, respectively). Furthermore, the values of performance measure decreased from wet water year to drought water year. Tape irrigation system was considered as the best choice at low quantities of WRF (<=0.4), however for higher values of WRF (>?=?0.6), sprinkler irrigation system was considered as the best choice for achieving higher values of water equity and productivity. Meanwhile, when equity and productivity were considered together for a specific method of deficit irrigation scheduling, under specified quantity of irrigation water, with increasing equity the water productivity reduction was negligible.     

Fabrication and characterization of microencapsulated PA with SiO<Subscript>2</Subscript> shell through sol–gel synthesis via sodium silicate precursor

In the present study, the microencapsulated phase change material with palmitic acid as core and inorganic SiO₂ shell was successfully fabricated by a sol–gel method in alkaline medium via sodium silicate precursor. The chemical compositions, crystalloid phase, microstructure and morphology of PA@SiO₂ microcapsule were studied by Fourier transform infrared spectroscopy, X-ray diffractometer, scanning electron microscopy and transmission electron microscopy. Differential scanning calorimetry and thermogravimetric analysis were used to determine the thermal properties and thermal stability of microcapsules, respectively. According to the XRD and FT-IR results, all the characteristic peaks of PA and SiO₂ were observed and there is no chemical reaction between them. Scanning electron microscopy images indicated that the microcapsule synthesized in pH 11 had a perfect spherical shape with smooth surfaces compared with other samples, and transmission electron microscopy images confirm that the PA have been well encapsulated by SiO₂. Differential scanning calorimetry analysis showed that the microcapsules indicated similar phase change behaviors as those of pristine PA, which melt at 67.2?°C with a latent heat of 111.2 J/g and freezing at 56.5?°C with a latent heat of 103.2 J/g. TGA analysis indicated that the thermal stability of the PA was also improved due to the protection of SiO₂ shell toward the encapsulated PA.     

Physical and Morphological Properties of Combined Treated Wood Polymer Composites by Maleic Anhydride and Methyl Methacrylate

Wood polymer composites were prepared by consecutive impregnation with maleic anhydride (MAN) and methyl methacrylate (MMA). Samples impregnated with MAN alone, were heated at 120°C and 150°C for 4 and 8 h. Based on the Fourier transform infrared (FT-IR) analysis and soaking-drying test results, treatment with MAN at 150°C for 4 h resulted in formation of stable crosslinks. In the second stage, MMA was used for in situ polymerization within MAN-treated wood. Field emission scanning electron microscopy observation and FT-IR analysis indicated that MMA copolymerized with MAN, and the resultant polymer filled up the lumen and is also grafted on to the cell wall. Improvement of water repellency and dimensional stability were observed in the treated samples, particularly in combined treated samples. The MAN/MMA treatment improved interaction between polymer and wood.     

Median line location problem with positive and negative weights and Euclidean norm

Let n existing facilities be given in the plane. The classical version of the median line location problem asks to find a line L in the plane, so that the sum of the weighted distances from L to all existing facilities is minimized. We consider the semi-obnoxious case, where every point has either a positive or a negative weight. In this paper, we discuss some properties of semi-obnoxious median line location problem with Euclidean norm and propose a particle swarm optimization algorithm for this problem.     

Synthesis and characterization of multiwall carbon nanotube/waterborne polyurethane nanocomposites

The preparation of thermoplastic nanocomposites of waterborne polyurethane (WBPU) and multiwall carbon nanotubes (MWCNTs) via an in situ polymerization approach is presented. The effects of the presence and content of MWCNTs on the morphology and thermal, mechanical and electrical properties of the nanocomposites were investigated. Carbon nanotubes were modified with amide groups in order to enhance their chemical affinity towards WBPU. Thermogravimetric studies show enhanced thermal stability of the nanocomposites. Scanning and transmission electronic microscopy images prove that functionalized carbon nanotubes can be effectively dispersed in WBPU matrix. Mechanical properties reveal that Young's modulus and tensile strength tend to increase when appropriate amounts of MWCNTs are loaded due to the reinforcing effect of the functionalized carbon nanotubes. Thermal properties show an increase in the glass transition temperature and storage modulus with an increase in MWCNT content. X‐ray diffraction reveals better crystallization of the WBPU in the presence of MWCNTs. The WBPU/MWCNT nanocomposite film containing 1 wt% of MWCNTs exhibits a conductivity nearly five orders of magnitude higher than that of WBPU film. © 2017 Society of Chemical Industry     

A modified particle swarm optimization for disaster relief logistics under uncertain environment

Relief logistics is one of the most important elements of a relief operation. This paper investigates a relief chain design problem where not only demands but also supplies and the cost of procurement and transportation are considered as the uncertain parameters. Furthermore, the model considers uncertainty for the locations where those demands can arise and the possibility that a number of the facility could be partially destroyed by the disaster. The proposed model for this study is formulated as a mixed-integer nonlinear programming to minimize the sum of the expected total cost (which includes costs of location, procurement, transportation, holding, and shortage) and the variance of the total cost. The model simultaneously determines the location of relief distribution centers and the allocation of affected area to relief distribution centers. Furthermore, an efficient solution approach based on particle swarm optimization is developed in order to solve the proposed mathematical model. At last, computational results for several instances of the problem are presented to demonstrate the feasibility and effectiveness of the proposed model and algorithm.     

Intelligent energy management of a fuel cell vehicle based on traffic condition recognition

Clean Technologies and Environmental Policy - This paper presents a methodological approach for intelligent control of fuel cell vehicles based on traffic condition recognition. For this purpose,...     

Production of hyaluronic‐acid‐based cell‐enclosing microparticles and microcapsules via enzymatic reaction using a microfluidic system

This article describes the preparation of cell‐enclosing hyaluronic acid (HA) microparticles with solid core and microcapsules with liquid core through cell‐friendly horseradish peroxidase (HRP)‐catalyzed hydrogelation. The spherical vehicles were made from HA derivative possessing phenolic hydroxyl moieties (HA‐Ph) cross‐linkable through the enzymatic reaction by extruding cell‐suspending HA‐Ph aqueous solution containing HRP from a needle of 180 μm in inner diameter into the ambient coaxial flow of liquid paraffin containing H₂O₂ in a microtubule of 600 μm in diameter. By altering the flow rate of liquid paraffin, the diameters of gelatin and HA‐Ph microparticles were varied in the range of 120–220 μm and 100–300 μm, respectively. The viability of the enclosed human hepatoma HepG2 cells in the HA‐Ph microparticles of 180 μm in diameter was 94.2 ± 2.3%. The growth of the enclosed HepG2 cells was enhanced by decreasing the HRP concentration. The microcapsules of 200 μm in diameter were obtained by extruding HA‐Ph aqueous solution containing thermally liquefiable cell‐enclosing gelatin microparticles of 150 μm in diameter using the same microfluidic system. The enclosed cells grew and filled the cavity within 10 days. Spherical tissues covered with a heterogeneous cell layer were obtained by degrading the microcapsule membrane using hyaluronidase after covering the surface with a heterogeneous cell layer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43107.