Electrochemical intercalation into graphite seen as an electrocapillary process

The electrochemical intercalation of H₂SO₄ into graphite leads to the well known graphite salts C⁺_n HSO⁻₄. χH₂SO₄ (with n → 20), χ ≈ 2.5). The potential—charge relations observed during intercalation agree well with a model involving the extended graphene layer-intercalate interfacial capacitance. The components of this capacitance are studied, including the effect of Fermi level lowering. A computed electrocapillary curve is compared to the separation work of graphene layers.     

Who and what links to the Internet Archive

The Internet Archive’s (IA) Wayback Machine is the largest and oldest public Web archive and has become a significant repository of our recent history and cultural heritage. Despite its importance, there has been little research about how it is discovered and used. Based on Web access logs, we analyze what users are looking for, why they come to IA, where they come from, and how pages link to IA. We find that users request English pages the most, followed by the European languages. Most human users come to Web archives because they do not find the requested pages on the live Web. About 65 % of the requested archived pages no longer exist on the live Web. We find that more than 82 % of human sessions connect to the Wayback Machine via referrals from other Web sites, while only 15 % of robots have referrers. Most of the links (86 %) from Websites are to individual archived pages at specific points in time, and of those 83 % no longer exist on the live Web. Finally, we find that users who come from search engines browse more pages than users who come from external Web sites.     

Statistical segmentation and structural recognition for floor plan interpretation

A generic method for floor plan analysis and interpretation is presented in this article. The method, which is mainly inspired by the way engineers draw and interpret floor plans, applies two recognition steps in a bottom-up manner. First, basic building blocks, i.e., walls, doors, and windows are detected using a statistical patch-based segmentation approach. Second, a graph is generated, and structural pattern recognition techniques are applied to further locate the main entities, i.e., rooms of the building. The proposed approach is able to analyze any type of floor plan regardless of the notation used. We have evaluated our method on different publicly available datasets of real architectural floor plans with different notations. The overall detection and recognition accuracy is about 95 %, which is significantly better than any other state-of-the-art method. Our approach is generic enough such that it could be easily adopted to the recognition and interpretation of any other printed machine-generated structured documents.     

Corrosion and mechanical behavior of fusion bonded epoxy (FBE) in aqueous media

In recent years there have been many reported cases of corrosion failure in cement concrete pipelines. In the majority of cases, the failures have been attributed to rebar corrosion which is caused by the permeability of chloride from low resistivity soil and subsequent attack on a passive layer on an iron bar in the structure. As a possible alternative to cementitious materials, some organic coatings based on olefin, vinyl or epoxy-based polymers have been considered. However, due to a paucity of data on the behavior of these coatings in aqueous media— particularly product water—the possibility of their application in water transmission systems in the Kingdom has not been fully exploited. This paper deals with the studies carried out on the corrosion and mechanical behavior of fusion bonded epoxy (FBE) coating on steel in aqueous media which include product water, distilled water and saline water. The mechanical testings on coating include adhesion, bending and cathodic disbondment testings. The corrosion studies include immersion testing under static and dynamic conditions, autoclave tests and accelerated (salt-fog) tests. The analysis of results indicates chemical inertness of FBE coating in either of the aforementioned water used during testing, good adhesion and no damage to the coating during bending. Cathodic disbondment tests indicate that FBE coating sustains under cathodic protection (CP) conditions. In general, the results of mechanical and corrosion tests indicate that FBE is a promising material for internal coating on steel in water transmission systems.     

Remarks on the Surface Area and Equality Conditions in Regular Forms. Part I: Triangular Prisms

This work presents four mathematical remarks concluded from the mathematical analysis for the interrelationships between the dependent and independent variables that control the measures: perimeter, floor area, walls surface area and total surface area in the regular forms that have a given volume. Such forms include prismatic and pyramidal forms. The work consists of four parts, of which this first part presents the remarks of the isosceles triangular right prism. The first remark examines the effect of θ, the angle of the triangular base, on the total surface area. The second remark calculates the minimum total surface area in two cases, depending on whether angle θ is constant or variable. The third remark calculates the walls ratio and the critical walls ratio. The last remark studies the required conditions for the numerical equality in two cases, where the perimeter is equal to the area, and where the total surface area is equal to the volume.     

Effects of cobalt and potassium doping on thermal stability and electrical properties of radiation grafted acrylic acid onto poly(tetrafluoroethylene ethylene) copolymer films

Grafted copolymer of poly(tetrafluoroethylene ethylene) (ET) with acrylic acid (AAc) was prepared by direct radiation method. The obtained films were modified by treating with small amounts of Co²⁺ and K⁺ ions (1.0 wt %). The effects of such treatment on the thermal stability and electrical conductivity of these films were studied. Cobalt treatment did not much affect the thermal degradation of the films. The results obtained revealed that k⁺ treatment enhanced the thermal degradation of ET‐g‐PAAc, which started 273 K lower than that observed in the case of the untreated and Co²⁺‐treated films. Potassium and cobalt treatment of the investigated films increased their electrical conductivity (σ) and decreased the activation energy ΔE_σ. The increase in σ values was, however, more pronounced in the case of K⁺‐treated film. These results were discussed in terms of the effective increase in the hydrophilicity of the films, especially those treated with potassium. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 867–871, 2005     

Distributed control of nonlinear diffusion systems by input–output linearization

This paper addresses the distributed control by input–output linearization of a nonlinear diffusion equation that describes a particular but important class of distributed parameter systems. Both manipulated and controlled variables are assumed to be distributed in space. The control law is designed using the concept of characteristic index from geometric control by using directly the PDE model without any approximation or reduction. The main idea consists in the control design in assuming an equivalent linear diffusion equation obtained by use of the Cole–Hopf transformation. This framework helps to demonstrate the closed‐loop stability using some concepts from the powerful semigroup theory. The performance of the proposed controller is successfully tested, through simulation, by considering a nonlinear heat conduction problem concerning the control of the temperature of a steel plate modeled by a nonlinear heat equation with Dirichlet boundary conditions. Copyright © 2012 John Wiley & Sons, Ltd.     

Oil thermal annealed nano‐structured indium tin oxide thin films for display applications

Indium tin oxide‐coated thin films (200 nm) are deposited on glass substrates by using R.f. sputtering technique. Here, we investigate the influence of new technique of treatment, which is called as “oil thermal annealing” on the nano‐structured indium tin oxide thin films at fixed temperature (150 °C) which improves adhesion strength, electrical conductivity and optical properties (transmittance) of the films. Oil thermal annealing is used to reduce inherent defects that may be introduced during the prepared thin film and cooling processes. Proposed technique is highly suitable for liquid crystal displays, solar cells and organic light emitting diodes, and many other display‐related applications.     

Thermodynamics of ionic-association in aqueous solutions of Ca and Mg organic salts using ion-selective electrode technique—II. benzoate, o-toloate, o-chlorobenzoate and salycylate

The stoichiometric association constants, K, the thermodynamic association constant, K_A, and the other thermodynamic parameters such as ΔS°, ΔH° and ΔG° for the association between each of the Ca and Mg ions with benzoate, o-toloate, o-chlorobenzoate and salycylate have been determined at 25°C, 35°C and 45°C in aqueous media. Ion-selective electrode technique has been used in the measurements of Ca and Mg ion activitiesThe trend of association behavior of both Ca and Mg aromatic salts could not be explained on the basis of pK_a of the mother organic acids but could be explained based on the trend of Hammet function σ of these salts themselves relative to the corresponding benzoate salt.