High Capacity Li2S–Li2O–LiI Positive Electrodes with Nanoscale Ion-Conduction Pathways for All-Solid-State Li/S Batteries

All-solid-state lithium–sulfur (Li/S) batteries are promising next-generation energy-storage devices owing to their high capacities and long cycle lives. The Li₂S active material used in the positive electrode has a high theoretical capacity; consequently, nanocomposites composed of Li₂S, solid electrolytes, and conductive carbon can be used to fabricate high-energy-density batteries. Moreover, the active material should be constructed with both micro- and nanoscale ion-conduction pathways to ensure high power. Herein, a Li₂S–Li₂O–LiI positive electrode is developed in which the active material is dispersed in an amorphous matrix. Li₂S–Li₂O–LiI exhibits high charge–discharge capacities and a high specific capacity of 998 mAh g⁻¹ at a 2 C rate and 25 °C. X-ray photoelectron spectroscopy, X-ray diffractometry, and transmission electron microscopy observation suggest that Li₂O–LiI provides nanoscale ion-conduction pathways during cycling that activate Li₂S and deliver large capacities; it also exhibits an appropriate onset oxidation voltage for high capacity. Furthermore, a cell with a high areal capacity of 10.6 mAh cm^–2 is demonstrated to successfully operate at 25 °C using a Li₂S–Li₂O–LiI positive electrode. This study represents a major step toward the commercialization of all-solid-state Li/S batteries.     

Fabrication and Training of 3D Conductive Polymer Networks for Neuromorphic Wetware

The human brain possesses an exceptional information processing capability owing to the 3D and dense network architecture of numerous neurons and synapses. Brain-inspired neuromorphic hardware can also benefit from 3D architectures, such as high integration of circuits and acquisition of highly complex dynamical systems. In this study, for future 3D neuromorphic engineering, 3D conductive polymer networks consisting of poly(3,4-ethylenedioxy-thiophene) doped with poly(styrene sulfonate) anions (PEDOT:PSS) are successfully and stably fabricated between multiple electrodes from scratch in precursor solution by electropolymerization. The networks efficiently emulate the 3D local connections between neighboring neurons observed in the cortex. This novel technology, which allows 3D conductive wiring only between desired electrodes, is unprecedented and has potential as an underlying technology for 3D integration. Furthermore, the experimental results also conclusively prove that conductance modification can be performed by manipulating the physical and chemical properties of 3D branch-wired conductive polymer wires, thus demonstrating for the first time the feasibility of neuromorphic wetware with enhanced biological plausibility in the subsequent post-Moore era.     

Development of Magnetocaloric Microstructures from Equiatomic Iron–Rhodium Nanoparticles through Laser Sintering

Pronounced magnetocaloric effects are typically observed in materials that often contain expensive and rare elements and are therefore costly to mass produce. However, they can rather be exploited on a small scale for miniaturized devices such as magnetic micro coolers, thermal sensors, and magnetic micropumps. Herein, a method is developed to generate magnetocaloric microstructures from an equiatomic iron–rhodium (FeRh) bulk target through a stepwise process. First, paramagnetic near-to-equiatomic solid-solution FeRh nanoparticles (NPs) are generated through picosecond (ps)-pulsed laser ablation in ethanol, which are then transformed into a printable ink and patterned using a continuous wave laser. Laser patterning not only leads to sintering of the NP ink but also triggers the phase transformation of the initial γ- to B2-FeRh. At a laser fluence of 246 J cm⁻², a partial (52%) phase transformation from γ- to B2-FeRh is obtained, resulting in a magnetization increase of 35 Am² kg⁻¹ across the antiferromagnetic to ferromagnetic phase transition. This represents a ca. sixfold enhancement compared to previous furnace-annealed FeRh ink. Finally, herein, the ability is demonstrated to create FeRh 2D structures with different geometries using laser sintering of magnetocaloric inks, which offers advantages such as micrometric spatial resolution, in situ annealing, and structure design flexibility.