菲酐-纳米金修饰电极同时检测抗坏血酸、多巴胺和尿酸的研究

多孔结构的3,4,9,10-茈四甲酸二酐（PTCDA）作为骨架,用抗坏血酸做还原剂制备纳米金（GNPs）,制备了高催化活性的PrC—GNPs复合纳米材料。将该材料用于玻碳电极的修饰（GCE）,制得PTC—GNPs复合材料修饰的电极（PTC—GNPs／GCE）。该修饰电极能够同时对尿酸（UA）、多巴胺（DA）和抗坏血酸（AA）进行检测。分别使用循环伏安法（CV）和差分脉冲伏安法（DPV）对UA、DA和AA和在修饰电极上的电化学行为进行研究。实验结果表明,在pH=5．0的PBS缓冲体系中,该修饰电极对UA、DA和AA的线性响应范围分别为0．002～0．462mol／L、0．002～0．352mol／L和0．04～1．54mol／L。该传感在临床医学检测领域具有一定的应用前景。     

基于项目式高校单片机课程改革与实践

针对传统单片机课程教学中存在的弊端,提出了项目式教学方法。探讨了在项目设计过程中项目的选择、项目的情境设计、项目在教学过程中的实施等问题。以燃气控制器为项目案例,介绍了如何将项目教学方法融入到单片机的硬件和软件教学中。以项目为主线,逐层完成整个项目的开发,直观地展示项目式教学方法在单片机教学中的优越性。该教学方法能充分调动学生学习的积极性,激发其创新意识,帮助学生毕业之后更快地适应相关工作。     

基于NoSQL数据库的大数据存储技术的研究与应用

实际工程中采集和处理的数据量特别大,这对传统数据库技术提出巨大挑战。针对传统关系型数据库存储速度慢、对硬件要求高的缺点,提出一种以NoSQL数据库为基础的大数据处理方法,打破了传统数据库的关系模型,数据以一种自由的方式存储,而不依赖固定的表结构。该方法主要是将经验模态分解并与NoSQL数据库技术相结合,应用于大型结构件的变形监测中,构建出一个基于NoSQL数据库系统的大型结构件变形监测系统。仿真结果表明,该方法可以实现大型结构件变形监测数据的实时处理,在计算收敛性、算法稳定性和处理速度上都优于传统数据库技术。     

Corrosion and inhibition of aged 347 grade stainless steel boiler tubes

General and pitting corrosion of both service and laboratory aged 347 grade stainless steel superheater tubes have been investigated. SEM analysis showed the precipitate phases to have a double structure consisting of phase and carbide. EDA analysis of the precipitates indicated the [Cr]/[Fe] ratio to increase with exposure time. For both set of specimens, the general corrosion rate in 1m H₂SO₄ increased with aging whilst the pitting studies (in 3.5% NaCl) also indicated increased pitting susceptibility with aging. These trends are consistent with corrosion from the chromium depleted areas adjacent to the precipitates. Methoxypropylamine is effective as an inhibitor for pitting corrosion and the concentration required to prevent this form of attack increases with exposure time for both types of specimens.     

The role of Al in C-S-H: NMR, XRD, and compositional results for precipitated samples

X-ray diffraction, compositional analysis, and ²⁹Si and ²⁷Al MAS NMR spectroscopy of Al-substituted tobermorite-type C-S-H made by precipitation from solution provide significant new insight into the structural mechanisms of Al-substitution in this important and complicated phase. Al occurs in 4-, 5-, and 6-coordination (Al[4], Al[5], and Al[6]) and plays multiple structural roles. Al[4] occurs on the bridging tetrahedra of the drierkette Al-silicate chains, and Al[5] and Al[6] occur in the interlayer and perhaps on particle surfaces. Al does not enter either the central Ca-O sheet or the pairing tetrahedra of the tobermorite-type layers. Al[4] occurs on three types of bridging sites, Q³ sites that bridge across the interlayer; Q² sites that are charge balanced by interlayer Ca⁺², Na⁺, or H⁺; and Q² sites that are most likely charge balanced by interlayer or surface Al[5] and Al[6] through Al[4]-O-Al[5,6] linkages. Although the data presented here are for relatively well-crystallized tobermorite-type C-S-H with C/S ratios ≤ 1.2, comparable spectral features for hydrated white cement pastes in previously published papers[30], [31] and [32] [M.D. Andersen, H.J. Jakobsen, J. Skibsted, Incorporation of aluminum in the calcium silicate hydrate (C-S-H) of hydrated Portland cements: a high-field ²⁷Al and ²⁹Si MAS NMR investigation Inorg. Chem. 42 (2003) 2280-2287; M.D. Andersen, H.J. Jakobsen, J. Skibsted, Characterization of white Portland cement hydration and the C-S-H structure in the presence of sodium aliminate by ²⁷Al and ²⁹Si MAS NMR spectroscopy, Cem. Concr. Res. 43 (2004) 857-868; M.D. Andersen, H. J. Jakobsen, J. Skibsted, A new aluminum-hydrate phase in hydrated Portland cements characterized by ²⁷Al and ²⁹Si MAS NMR spectroscopy, Cem. Concr. Res., submitted for publication.] indicate the presence of similar structural environments in the C-S-H of such pastes, and by implication OPC pastes.     

Multi-party quantum private comparison protocol with n-level entangled states

In this paper, two multi-party quantum private comparison (MQPC) protocols are proposed in distributed mode and traveling mode, respectively. Compared with the first MQPC protocol, which pays attention to compare between arbitrary two participants, our protocols focus on the comparison of equality for \(n\) participants with a more reasonable assumption of the third party. Through executing our protocols once, it is easy to get if \(n\) participants’ secrets are same or not. In addition, our protocols are proved to be secure against the attacks from both outside attackers and dishonest participants.     

Graft polymerization of acrylic acid onto polyphenylene sulfide nonwoven initiated by low temperature plasma

Graft copolymerization of acrylic acid (AA) onto polyphenylene sulfide (PPS) nonwoven initiated by low temperature plasma was studied. The effects of various conditions on graft reaction and the grafting rate were investigated. SEM images showed that PPS nonwoven was grafted, and the graft copolymerization only occurred on the surface of PPS. It may be due to the chain transference going with the graft copolymerization. It was found that with the increasing of plasma power, treatment time, space between electrodes, monomer concentration, and temperature of graft polymerization, the grafting rate increased at first, went to the top, and then decreased. The PPS nonwoven surface graft reaction could be optimized by the following processing conditions: 120 s of plasma treatment time, 50 W of plasma power, 1.5 cm of space between electrodes, 30% (w/w) of monomer concentration, and 50°C of temperature of graft polymerization. Measurement of XPS showed that the peak of C1s of graft polyacrylic acid was existed, and the peak area increased with the increase of the grafting rate. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5884–5889, 2006     

α—呋喃丙酸酯香料的合成研究

以糠醛为原料 ,通过三步反应合成了α-呋喃丙酸甲酯、乙酯、正丙酯、异丙酯、正丁酯、正戊酯等六种呋喃丙酸酯香料。此外 ,通过正交实验对呋喃丙酸甲酯的合成条件进行了优化。     

An alternate quantum adiabatic evolution for the Deutsch–Jozsa problem

Deutsch–Jozsa algorithm has been implemented via quantum adiabatic evolutions by Das et al. (Phys Rev A 65:062310, 2002) and Wei et al. (Phys Lett A 354:271, 2006). In the latter literature, the authors have shown a modified version of the adiabatic evolution which can improve the performance of the algorithm of S. Das et al’s to constant time. In this paper, we also improve the algorithm of S. Das et al’s in a constant time but by using a different construction of adiabatic evolution, i.e., adding ancillary qubits. The algorithm in this paper provides an alternative option to potential users.     

Optimality of partial adiabatic search and its circuit model

In this paper, we first uncover a fact that a partial adiabatic quantum search with \(O(\sqrt{N/M})\) time complexity is in fact optimal, in which \(N\) is the total number of elements in an unstructured database, and \(M\) ( \(M\ge 1\) ) of them are the marked ones(one) \((N\gg M)\) . We then discuss how to implement a partial adiabatic search algorithm on the quantum circuit model. From the implementing procedure on the circuit model, we can find out that the approximating steps needed are always in the same order of the time complexity of the adiabatic algorithm.