Isolation and identification of two major acylated anthocyanins from purple sweet potato (Ipomoea batatas L. cultivar Eshu No. 8) by UPLC‐QTOF‐MS/MS and NMR

In recent years, researches on the isolation and preparation of monomeric anthocyanins have intensified because of the requirements of quantitative and structure–bioactivity relationship analyses. However, simple and effective methods about the scale of monomeric anthocyanins from the natural purple sweet potato powder are rarely reported. In this study, high molecular weight acylated monomeric anthocyanins were isolated from purple sweet potato (Ipomoea batatas L. cultivar Eshu No. 8) via the combination of column chromatography and semi‐preparative HPLC technology and identified mainly by ultra‐high‐performance liquid chromatography quadrupole time‐of‐flight tandem mass spectrometry/mass spectrometry (UPLC‐QTOF‐MS/MS) and ¹H and ¹³C nuclear magnetic resonance (NMR). Two major acylated anthocyanins were unambiguously determined as peonidin 3‐O‐(6‐O‐(E)‐caffeoyl‐(2‐O‐(6‐O‐p‐hydroxybenzoyl)‐β‐D‐glucopyranosyl)‐β‐D‐glucopyranoside)‐5‐O‐(β‐D‐glucopyranoside) and peonidin 3‐O‐(6‐O‐(E)‐caffeoyl‐(2‐O‐(6‐O‐(E)‐feruloyl)‐β‐D‐ glucopyranosyl)‐β‐D‐glucopyranoside)‐5‐O‐(β‐D‐glucopyranoside). The results of this study may help promote the purification of high molecular weight acylated anthocyanins from purple sweet potato as well as from other plant materials in nature.     

How hydrogen-storage material affects the decomposition of nitramine explosive: CPMD investigations of LAB-doped CL20

As the most popular high-energy explosives, 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo [5.5.0.0.0] dodecane (Simplified as HNIW or CL20) attracts many attentions for improving its detonation appearance in the application. Here we introduce hydrogen-storage compounds into explosives to estimate the possible improved detonation performances by Car-Parrinello molecular dynamics (CPMD) simulation, where we construct lithium amidoborane (LAB) doped CL20 as the initial structure. Almost all the interactions between hydrogen and CL20 appear exothermic properties, which indicate LAB increases the enthalpies of detonation. The results suggest explosive mixed with hydrogen-storage material is possibly a new field of energetic compound.     

敦煌艺术风格数码提花织物的设计实践

通过对中国传统敦煌艺术的风格和表现形式的研究,设计敦煌艺术风格图案,并用于数码提花织物设计。深入分析了影响分层组合模式下数码提花织物结构设计的基本因素,通过改变全息组织加强点个数和加强点位置来制定设计实验方案,选择加强点个数为6和7进行设计实践,通过结果分析和比较得出结构设计的优化方法,并采用Lab色彩模式实现组织与灰度的精确替换。该研究的设计实验和设计实例为传统艺术与数码提花技术结合,并应用于纺织品的创新设计提供技术借鉴和设计参考。     

催化裂化装置外取热器运行异常分析

中国石油化工股份有限公司洛阳分公司Ⅱ套催化裂化装置外取热系统自2011年改造后,出现难流化,难建立循环的现象,无法灵活调整外取热器产汽量,给生产造成很大影响.针对进料复杂多变、外取热器难以流化的现状,采取了外取热器单器流化的操作模式,以保证装置具备灵活的取热手段.分析认为外取热器简体内流化风管的流化状态对外取热器流化有重要影响.装置检修期间,对外取热器进行了改造,主要改造内容是简体内的流化风环.改造后,外取热器循环流化和产汽较之前有大幅度改善,为生产优化提供了保障.     

飞秒激光加工单晶金刚石制备正前角磨削工具

目的制造一种磨粒有序排布、具有正前角的无结合剂端面金刚石磨削工具。方法采用波长为1030 nm、脉宽为250 fs的钛蓝宝石飞秒激光对单晶金刚石(SCD)进行烧蚀加工,首先研究加工工艺参数(特别是烧蚀轨迹间距)对金刚石加工效率及表面质量的影响。采用预先设计的激光扫描路径,基于优化后的工艺参数在SCD表面加工出微磨粒阵列结构,各磨粒呈方锥台形结构,其顶部倾斜角约为100°。在此基础上,对微磨粒阵列进行烧蚀加工,将所有微磨粒顶部的倾斜角减小至小于90°。结果当激光烧蚀轨迹间距为10.0μm时,烧蚀加工表面RMS粗糙度最小。确定了一种微磨粒边缘倾斜角小于90°且磨粒有序排布的新型无结合剂金刚石端面磨削工具的激光制备方法和工艺,采用该工艺加工的磨削工具表面质量好,轮廓精度高,磨粒平均正前角约为9.80°。结论采用飞秒激光可以高质量、高效率地制备出磨粒有序排布的新型正前角无结合剂金刚石端面磨削工具,该工具有望在硬脆材料磨削中减小磨削力,提高材料表面完整性。     

河南WR-1地热井降压试验水位校正的应用研究

一般的单井稳定流抽水试验,可直接利用从孔口测得的水位降深与对应的流量关系,求取含水层的水文地质参数。但对地热井而言,由于在抽水过程中,井筒内水温的变化可对井中水位产生较大影响,故不宜直接利用降压试验前测得的静水位埋深和孔口所测的水位降深值,而应该进行静水位和动水位的校正(刘永贵,2016),才能与观测的水位埋深、水量、水温相匹配进行参数计算(高新智,2015)。文章以尉氏县WR-1地热井馆陶组降压试验静水位、动水位校正实例,阐述地热井降压试验水位校正的有效性和必要性。     

悬浮态磁化焙烧菱铁矿及冷却条件对产品的影响

针对传统的堆积态菱铁矿焙烧工艺具有气固接触面积小、能耗大、矿石质量不均匀、容易产生"过烧"和"欠烧"的缺点,开展了悬浮态磁化焙烧细粒菱铁矿的试验,研究了不同冷却条件对焙烧产品的影响.研究结果表明,冷却速度是影响焙烧矿质量的重要因素,将焙烧矿在空气中快速冷却可跳过500～400℃相变激烈区,减小氧化程度,获得良好指标.