Studies of Bainitic Steel for Rail Applications Based on Carbide-Free,Low-Alloy Steel

Metallurgical and Materials Transactions A - This paper describes the development and characterisation of bainitic steel for rail applications based on carbide-free, low-alloy steel. The results...     

Towards automated mapping and monitoring of potentially dangerous glacial lakes in Bhutan Himalaya using Sentinel-1 Synthetic Aperture Radar data

The majority of glacial lakes around the world are located in remote and hardly accessible regions. The use of remote sensing data is therefore of high importance to identify and assess their potential hazards. However, the persistence of cloud cover, particularly in high mountain areas such as the Himalayas, limits the temporal resolution of optical satellite data with which we can monitor potentially dangerous glacial lakes (PDGLs). The ability of Synthetic Aperture Radar (SAR) satellites to collect data, irrespective of weather and at day or night, facilitates monitoring of PDGLs by without compromising temporal resolution. In this study, we present a semi-automated approach, based on a radar signal intensity threshold between water and non-water feature classes followed by post-processing including elevations, slopes, vegetation and size thresholds, to delineate glacial lakes in Sentinel-1 SAR images in Bhutan Himalaya. We show the capability of our method to be used for delineating and monitoring glacial lakes in Bhutan Himalaya by comparing our results to 10 m resolution Sentinel-2 multispectral data, field survey data, meteorological data, and a time series of monthly images from January to December 2016 of two lakes. Sentinel-1 SAR data can, moreover, be used for detecting lake surface area changes and open water area variations, at temporal resolution of six days, providing substantial advantages over optical satellite data to continuously monitor PDGLs.     

Microwave-assisted synthesis of anion-exchange resins for sorption of noble metals: how to boost sorption capacity using a proper reaction environment

In the present studies a series of anion-exchange resins was synthesized in a microwave field. The 1,6-diaminohexane functionalized resins were obtained in presence of selected organic solvents, N,N-dimethyl formamide, dimethyl sulfoxide and 1-methyl-2-pyrrolidone. The resins were employed in batch and dynamic processes of Au(III), Pt(IV) and Pd(II) sorption from tricomponent systems in 0.1 M HCl. The experiment was designed in a way that allowed to determine the use of a specific solvent in the microwave field and how it impacts on properties of the anion exchangers. An influence of a reaction environment was discussed taking into account i.e., dielectric characteristics of the specific solvent, efficiency of the syntheses processes as well as the maximum sorption capacity of the resins. Ultimately the application of a specific reaction environment was set together with sorption of noble metals ability and evaluated using infrared spectroscopy. The proceeded analyzes allowed to determine which organic solvent from the selected ones is the most suitable for microwave-assisted synthesis of the anion-exchange resins.     

Analysis of wet oxidation process after initial thermohydrolysis of excess sewage sludge

The authors propose a new technique to analyse a complex process of wet oxidation of excess sewage sludge by separating thermohydrolysis that results in the separation of sewage sludge into hydrolysates: solid and liquid products, from the basic process of oxidation of the two products. Wet oxidation kinetics was studied at different temperatures of both products based on the measurement of total organic carbon during the process with the use of a PARR high-pressure reactor. Decomposition of the liquid product leads to the formation of non-degradable and gaseous final products, while degradation of the solid product-via an intermediate liquid product-also leads to the formation of final and gaseous products. Solution of the kinetic equations that describe the dependence of relative organic carbon concentration on time is well illustrated by experimental results. On the basis of fitting theoretical curves to the experimental results, the kinetic parameters of the process were determined.     

Influence of post-weld heat treatment (PWHT) on the structure and properties of welded joints of chromium–nickel stainless steel with soft martensite

This paper reviews the results of investigations on how post-weld heat treatment (PWHT) influences the hardness and microstructures of welded joints in stainless steel X3Cr-NiMo 13-4. It is known that welding leads to high segregation of components in the solidification process, which has an influence on phase transitions in PWHT. The investigated steel has a very narrow PWHT range, about 600–620°C, which provides optimum levels of hardness and toughness. Excessive annealing temperature leads to decreased toughness, which in turn causes exceeding of the A_c1 temperature in the segregation range, which then leads to increased ‘fresh’ martensite content.     

Influence of modified starches on properties of gluten-free dough and bread. Part II: Quality and staling of gluten-free bread

The aim of the study was to check the quality of gluten-free bread produced basing on the recipes, in which part of native starch was replaced with high amylose corn starch (HACS), acetylated distarch adipate (ADA), and hydroxypropyl distarch phosphate (HDP). The application 10 or 15% of chemically modified starches (HDP, ADA) caused the increase in volume of the obtained gluten-free loaves. The changes were accompanied by a decrease of average cell size, and an increase in their number. Due to the addition of modified starch crumb structure became more elastic, which was revealed in the results of stress relaxation. A slight decrease in hardness and chewiness of the crumb was also observed on the day of baking, and its extent depended on the level of modified starch, and was a little more pronounced in case of starch adipate. In comparison to the chemically modified starches, HACS deteriorated structural and mechanical properties of the crumb, which is probably related to their resistance to pasting and divergence in retrogradation pattern, where amylose component is more important than amylopectin.     

Growth and exopolysaccharide yield of Lactobacillus delbrueckii ssp. bulgaricus DSM 20081 in batch and continuous bioreactor experiments at constant pH

Some Lactobacillus delbrueckii ssp. bulgaricus strains are able to synthesize exopolysaccharides (EPS) and are therefore highly important for the dairy industry as starter cultures. The aim of this study was to investigate the nutritional requirements for growth and EPS production of Lactobacillus delbrueckii ssp. bulgaricus DSM 20081. A medium was developed from a semi-defined medium (SDM) in which glucose was replaced by lactose and different combinations of supplements (nucleobases, vitamins, salts, sodium formate and orotic acid) were added. Constant pH batch fermentation with the modified medium resulted in an EPS yield of approximately 210 mg glucose equivalents per liter medium. This was a 10-fold increase over flask cultivation of this strain in SDM. Although not affecting cell growth, the mixture of salts enhanced the EPS synthesis. Whereas EPS production was approximately 12 mg/g dry biomass without salt supplementation, a significantly higher yield (approximately 20 mg/g dry biomass) was observed after adding the salt mixture. In continuous fermentation, a maximal EPS concentration was obtained at a dilution rate of 0.31/h (80 mg EPS/L), which corresponded to a specific EPS production of 49 mg/g dry biomass.     

Antifungal activity of denture soft lining material modified by silver nanoparticles-a pilot study

Soft liner materials in oral cavity environments are easily colonized both by fungi and dental plaque. These factors are the cause of mucosal infections. The microorganism that most frequently colonizes soft liner materials is Candida albicans. Colonization occurs on the surface of materials and within materials. A solution to this problem might involve modification of soft liner materials with silver nanoparticles (AgNPs). In this article, we present results showing the antifungal efficacy of silicone soft lining materials modified with AgNPs. The modification process was conducted by dissolving both material components (base and catalyst) in a colloidal solution of AgNPs and evaporating the solvent. Composites with various AgNP concentrations (10, 20, 40, 80, 120 and 200 ppm) were examined. The in vitro antifungal efficacy (AFE) of composite samples was 16.3% to 52.5%.