Study of the anticorrosive properties of polypyrrole/polyaniline bilayer via electrochemical techniques

In this work, using electrochemical techniques the authors investigated the protective properties of a polypyrrole/polyaniline bilayer as a conductive polymer. A polypyrrole/polyaniline bilayer was deposited on carbon steel substrate by potentiostatic method. The electric capacitance and resistance of the films were monitored with the immersion time in a corrosive solution to investigate the water permeability of the films. Polypyrrole/polyaniline bilayer has a relatively low permeability and good catalytic behavior in passivation of carbon steel in longer periods. The results show that the bilayer has a better anticorrosive behavior compared to homopolymers (polypyrrole and polyaniline).     

Energy inputs and crop yield relationship in potato production in Hamadan province of Iran

The aim of this study was to determine energy consumption and the relationship between energy input and yield for potato production in Kaboud Rahang region of Hamadan state. The data used in this study are collected by questionnaire. The results revealed that nitrogen fertilizer (39%), diesel (21%), seed (14.9%), water (7.5%) and manure (6.4%) consumed the bulk of energy. In the surveyed farms, average yield and energy consumption were calculated as around 28613.7 kg/ha, 92296.3 MJ/ha, respectively. The results also showed that energy ratio, specific energy and energy productivity were 1.1, 3.2 MJ/kg and 0.3 kg/MJ, respectively. An econometric model was developed to estimate the impact of energy inputs on yield by using parametric methods. For this purpose, potato yield, an endogenous variable was assumed to be a function of energy inputs: fertilizer manure, chemical, machinery, human, water for irrigation, diesel and seed. The empirical results indicated that variables: fertilizer, chemical, seed and human were found statistically significant and contributed to yield. Among statistically significant exogenous variables, seed, water for irrigation, chemical, human and fertilizer were ranked in terms of elasticities.     

A Flat Polymeric Membrane Sensor for Carbon Dioxide/Nitrogen Gas Mixture

A gas sensor was developed to measure the concentration of binary gas mixtures. This sensor works based on the permeability change of different gas mixtures across the polymeric membranes. Although high values of permeability and selectivity are needed for an ideal separation, the performance of this sensor mainly depends on the permeability factor. Polysulfone and silicone rubber were applied as the membrane base and coat, respectively. Moreover, in contrast to existing polymeric sensors that use hollow fibers, the present sensor is made of flat membranes. This new design is cheaper, smaller, and easier to use in comparison to the hollow fiber polymeric sensors. In order to test the sensor applicability, nitrogen and carbon dioxide were used as model gases. The effect of pressure on the response time and sensor accuracy was studied for the aforementioned gases. The response time (T_95%) of this low price sensor was 50?s, and the tolerance of measuring concentration was approximately 1.4% at 2?bar feed pressure. Also, increasing the feed pressure can improve the response time or accuracy of the sensor.     

Prediction of wear properties in A356 matrix composite reinforced with B4C particulates

In the present study, wear properties of A356 unreinforced alloy and composites with different vol.% of boron carbide particles were investigated. It is noted that composites exhibit better wear resistance compared to unreinforced alloy. According to the differences in wear rates of the composites, two separate wear rate were identified as low and high wear rate regimes. A combination of artificial neural network (ANN) and finite element technique (FEM) was implemented in order to predict the composites wear behavior. The FEM method is used for discretization and to calculate the transient temperature field of quenching. It is observed that predictions of ANN are consistent with experimental measurements for A356 composite and considerable savings in terms of cost and time could be obtained by using neural network model.     

Origin of Surface Irregularities on Ti–10V–2Fe–3Al Beta Titanium Alloy

We studied the origin of different characteristics and properties of a Ti–10V–2Fe–3Al beta (β) titanium alloy with surface height irregularities that occurred during machining. The height differences were observed in two different regions, labeled as “soft region” and “hard region.” The present study showed a higher Fe and a lower Al content in the hard region, which resulted in higher β-phase stability to resist primary alpha (α_p) phase precipitation caused by a failure of the solution treatment process. In contrast, the soft region contained a higher volume fraction of α_p phase and a lower volume fraction of the matrix, which consisted of a combination of β and secondary alpha (α_s) phase. A high number of α_s/β interface in the matrix with a predicted hardness of 520 HV generated an improvement of hardness in the hard region. Therefore, the hard and the soft regions had different abilities to resist wear during machining process, resulting in surface height irregularities.     

Electromagnetic MEMS microspeaker for portable electronic devices

This work presents the conception, the microfabrication, and the electroacoustic characterization of a new electromagnetic microspeaker based on silicon. The objectives are to get improved sound quality compared to that of conventional microspeakers, while keeping the electroacoustic efficiency as high as possible. An optimized stiffening silicon microstructure let the sound radiator be extremely light and rigid. The mobile part is suspended to the fixed part by silicon suspension springs, which enable large out-of-plane displacement. The acoustic radiator is actuated by an electromagnetic motor, composed of a fixed permanent magnet and a planar coil located on top of the silicon radiator. The piston-like motion of the radiator favored by this structure is very beneficial for the sound quality. Electro–mechano–acoustic characterization of the microfabricated microspeaker showed that the radiator surface could run out-of-plane with displacements higher than ±400 μm, with no mechanical and electrical failure. For an electrical power of 0.5 W, the microspeaker was capable to generate a sound pressure level of 80 dB at 10 cm, from 330 Hz up to 20 kHz frequency. The efficiency reaches 3 × 10^?5, that is to say three times more than typical efficiency of conventional microspeakers. Moreover, as characterization results showed, the existence of very few structural modes and the low electroacoustic distortions evidence the high sound quality of the microspeaker.     

Classroom furniture and anthropometric characteristics of Iranian high school students: Proposed dimensions based on anthropometric data

The study evaluated the potential mismatch between classroom furniture dimensions and anthropometric characteristics of 978 Iranian high school students (498 girls, 480 boys), aged 15-18 years. Nine anthropometric measurements (stature, sitting height, sitting shoulder height, popliteal height, hip breadth, elbow-seat height, buttock-popliteal length, buttock-knee length and thigh clearance) and five dimensions from the existing classroom furniture were measured and then compared together (using match criterion equations) to identify any potential mismatch between them. The results indicated a considerable mismatch between body dimensions of the students and the existing classroom furniture, with seat height (60.9%), seat width (54.7%) and desktop height (51.7%) being the furniture dimensions with a higher level of mismatch. The levels of mismatch varied between the high-school grade levels and between genders, indicating their special requirements and possible problems. The proposed dimensions of the classroom furniture more appropriate for the students were given. This additional information on students' anthropometry can be used by local furniture industries as a starting point for designing more appropriate furniture for school children, or used by schools to aid in furniture selection.     

Methodology for in-line rheology by ultrasound Doppler velocity profiling and pressure difference techniques

This paper describes a methodology for measuring rheological flow properties in-line, in real-time, based on simultaneous measurements of velocity profiles using an ultrasound velocity profiling (UVP) technique with pressure difference (PD) technology. The methodology allows measurements that are rapid, non-destructive and non-invasive and has several advantages over methods presented previously. The set-up used here allows direct access to demodulated echo amplitude data, thus providing an option to switch between time domain algorithms and algorithms based on FFT for estimating velocities, depending on the signal-to-noise ratio (SNR) and time resolution required. Software based on the MATLAB^® graphical user interface (GUI) has been developed and provides a powerful and rapid tool for visualizing and processing the data acquired, giving rheological information in real-time and in excellent agreement with conventional methods. This paper further focuses on crucial aspects of the methodology: implementation of low-pass filter and singular value decomposition (SVD) methods, non-invasive measurements and determination of the wall positions using channel correlation and methods based on SVD. Measurements of sound velocity and attenuation of ultrasound in-line were introduced to increase measurement accuracy and provide an interesting approach to determine particle concentration in-line. The UVP-PD methodology presented may serve as an in-line tool for non-invasive, real-time monitoring and process control.     

Polystyrene/Polyolefin Elastomer Blends Loaded with Halloysite Nanotubes: Morphological,Mechanical, and Gas Barrier Properties

Herein, a simple melt-blending method is utilized to disperse of halloysite nanotubes (HNTs) in polystyrene/polyolefin elastomer (PS/POE) blends. Based on morphological studies, the PS/POE/HNT nanocomposite containing up to 3 phr HNTs shows excellent nanofiller dispersion, while those filled with 5 phr HNTs exhibit nanofiller aggregation. To overcome the nanofiller aggregation issue, the polypropylene-grafted-maleic anhydride (PP-g-MA) compatibilizer is added to the PS/POE/HNT nanocomposite, which results in improved mechanical properties for the nanocomposite sheets. Furthermore, the addition of compatibilized HNTs to the PS/POE blends leads to decreased O₂ and N₂ gas permeabilities. Besides, incorporating POE, HNTs, and PP-g-MA leads to a decrease in water vapor transmission of PS. In the end, the experimentally-determined mechanical properties and gas permeabilities of the nanocomposite sheets are compared to those predicted by prevalent theoretical models, revealing a good agreement between the experimental and theoretical results. Molecular-dynamics simulations are also carried out to calculate the gas diffusion coefficients in the different sheets to further support the experimental findings in this study. Overall, the PS/POE/HNT/PP-g-MA nanocomposite sheets fabricated in this work demonstrate excellent mechanical and gas barrier properties; and hence, can be used as candidate packaging materials. However, the strength of the resulting PS/POE blend may be inferior to that of the virgin PS.     

A new hybrid approach to discrete multiple facility location problem

Locating certain facilities in predetermined sites is named the multiple facility location problems (MFLP). The objective of these kinds of problems is locating facilities to serve a given set of customers so that candidate sites and requirements are known. When the new facility sites have to be selected from a given set of candidate sites, the mentioned location problem becomes a discrete multiple facility location problem (DMFLP). In this paper, a special approach of DMFLP is considered where different multiple facilities have to be placed (location decision) and also customers have to be assigned to these facilities (allocation or assignment). The mathematical model of the proposed problem is developed, and with respect to the complexity of solving the mathematical model, especially in large scale, a new hybrid approach is proposed based on tabu search algorithm to solve the problem at each scale. Computational results on several randomly generated problems in comparison with a new proposed lower bound obtained from Lagrangian relaxation indicate that the proposed hybrid approach is both accurate and efficient.