The effects of reclamation on a thermotropic liquid crystalline polymer

In previous work, a process was developed to reclaim a thermotropic liquid crystalline polymer (DuPont HX8000) from composites comprised of polypropylene (PP) reinforced with HX8000. The reclamation was accomplished by chemically degrading the PP and then dissolving the PP away in heated mineral oil. From this work, it was found that there were significant drops in dynamic and steady shear viscosity for the reclaimed HX8000, but that there were no losses in mechanical properties when the recovered HX8000 was used to generate PP–HX8000 injection-molded composites. In the present work, the reclaimed HX8000 was analyzed to understand the contradiction between rheological and mechanical properties. The effects of the reclamation process on the recovered HX8000 were investigated by using pycnometry (density), thermogravimetric analysis (TGA), parallel plate rheometry, mechanical testing, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2517–2524, 1999     

Elongational rheology of polymer melts and solutions

Elongational rheological properties of polymer melts and solutions may be measured using nonlubricated flow characteristics through a semihyperbolic converging die. The effects of body forces related to developing orientation in the fluid during converging extensional flow are so strong that the shearing contribution become negligible in comparison, eliminating the need for lubrication to achieve an essentially pure elongational flow. The effective elongational viscosities of polypropylene melts and lyocell solutions correlated with shear-flow determinations were used to estimate the enthalpy and entropy changes as function of processing conditions. The flow of lyocell solutions through a converging die had, as a result, not only phase separation and cellulose crystallization, but also microfibers formation and high orientation. © 1998 John Wiley & Sons, Inc. J. Appl. Polym. Sci. 69: 2357–2367, 1998     

Functional analysis of the Saccharomyces cerevisiaeUBC11 gene

UBC11 is the Saccharomyces cerevisiae gene that is most similar in sequence to E2-C, a ubiquitin carrier protein required for the destruction of mitotic cyclins and proteins that maintain sister chromatid cohesion in animal cells and in Schizosaccharomyces pombe. We have disrupted the UBC11 gene and found it is not essential for yeast cell viability even when combined with deletion of UBC4, a gene that has also been implicated in mitotic cyclin destruction. Ubc11p does not ubiquitinate cyclin B in clam cell-free extracts in vitro and the destruction of Clb2p is not impaired in extracts prepared from Δubc11 or Δubc4Δubc11 cells. These results suggest Ubc4p and Ubc11p together are not essential for mitotic cyclin destruction in S. cerevisiae and we can find no evidence to suggest that Ubc11p is the true functional homologue of E2-C. © 1998 John Wiley & Sons, Ltd.     

In situ slip estimation for mobile robots in outdoor environments

Accounting for wheel–terrain interaction is crucial for navigation and traction control of mobile robots in outdoor environments and rough terrains. Wheel slip is one of the surface hazards that needs to be detected to mitigate against the risk of losing the robot's controllability or mission failure occurring. The open problems in the Terramechanics field addressed are (1) the need for in situ wheel-slippage estimation in harsh environments using low-cost/power and easy to integrate sensors, and (2) removing the need for prior information of the soil, which is not always available. This paper presents a novel slip estimation method that utilizes only two proprioceptive sensors (IMU and wheel encoder) to estimate the wheel slip using deep learning methods. It is experimentally shown to be real-world feasible in outdoor, uneven terrains without prior soil information assumptions. Comparison with previously used machine learning algorithms for continuous and discrete slip estimation problems show more than 9% and 14% improvement in estimation performance, respectively.     

Lead-Free,Luminescent Perovskite Nanocrystals Obtained through Ambient Condition Synthesis

Heterovalently substituting toxic lead is an increasingly popular design strategy to obtain environmentally sustainable variants of the exciting material class of halide perovskites. Perovskite nanocrystals (NCs) obtained through solution-based methods exhibit exceedingly high optical quality. Unfortunately, most of these synthesis routes still require reaction under inert gas and at very high temperatures. Herein a novel synthesis routine for lead-free double perovskite (LFDP) NCs is presented. An approach based upon the hot injection and ligand-assisted reprecipitation (LARP) methods to achieve a low-temperature and ambient atmosphere-based synthesis for manganese-doped Cs₂NaBiCl₆ NCs is presented. Mn incorporation is critical for the otherwise non-emissive material, with a 9:1 Bi:Mn precursor ratio maximizing the bright orange photoluminescence (PL) and quantum yield (QY). Higher synthesis temperatures slightly increase the material's performance, yet NCs synthesized at room temperature are still emissive, highlighting the versatility of the synthetic approach. While the material's indirect bandgap limits its appeal for optoelectronics, this feature could benefit photocatalysis due to longer carrier lifetimes. Moreover, the developed synthesis is facile and can rapidly be adapted to other more viable material compositions and up-scaled to realize applications directly.     

Liquid Crystals as Multifunctional Interfaces for Trapping and Characterizing Colloidal Microplastics

Identifying and removing microplastics (MPs) from the environment is a global challenge. This study explores how the colloidal fraction of MPs assemble into distinct 2D patterns at aqueous interfaces of liquid crystal (LC) films with the goal of developing surface-sensitive methods for identifying MPs. Polyethylene (PE) and polystyrene (PS) microparticles are measured to exhibit distinct aggregation patterns, with addition of anionic surfactant amplifying differences in PS/PE aggregation patterns: PS changes from a linear chain-like morphology to a singly dispersed state with increasing surfactant concentration whereas PE forms dense clusters at all surfactant concentrations. Statistical analysis of assembly patterns using deep learning image recognition models yields accurate classification, with feature importance analysis confirming that dense, multibranched assemblies are unique features of PE relative to PS. Microscopic characterization of LC ordering at the microparticle surfaces leads to predict LC-mediated interactions (due to elastic strain) with a dipolar symmetry, a prediction consistent with the interfacial organization of PS but not PE. Further analysis leads to conclude that PE microparticles, due to their polycrystalline nature, possess rough surfaces that lead to weak LC elastic interactions and enhanced capillary forces. Overall, the results highlight the potential utility of LC interfaces for rapid identification of colloidal MPs based on their surface properties.     

Building more resilient communities with a wildfire preparedness drill in the U.S.: Individual and community influences and communication practices

When a wildfire strikes, it impacts entire communities. Yet it can be challenging to get communities to take the lead in becoming more prepared, and thus build lasting resilience. Guided by theoretical preparedness models, and using a case study design, this study examines the planning, execution, and subsequent sensemaking around one of the first community-led wildfire evacuation drills in the United States. Findings illustrate the interplay between individual preparedness, communication, and community involvement as the neighbourhood studied conducted their drill in partnership with multiple emergency response organizations. Our model explains 39% of the variance in individuals' preparedness, finding that people with higher self-efficacy, more involved with the community, and who felt strong social norms around preparedness had more items prepared for a wildfire. The community's desire to share the preparedness organizing process with external audiences is a unique and important contribution in understanding how communication can be used to sustain community resilience.     

Formation of nanoparticle aggregates and agglomerates in polymer nanocomposites and their distinct impacts on the mechanical properties

In this study, the different effects of nanoparticle aggregates and agglomerates on the mechanical properties of polymer nanocomposites are comprehensively investigated. To this end, a specific strategy, based on the equilibrium between the dispersion and cohesion energies in the mixing stage, is proposed using which the content and size of aggregates/agglomerates can be defined. The aggregated/agglomerated networks are considered to place in constrained volumes (CVs), having co-continuous morphology. An equivalent box model (EBM), corresponding to the system, is used to predict the tensile modulus of the nanocomposite. Different test results of HDPE nanocomposite samples, containing 1–3 wt.% of surface-modified silica nanoparticles, prepared by a semi-industrial single screw extruder, are applied to validate the model. Moreover, other data from the literature are also used to further evaluate the accuracy and capability of the proposed analytical method.     

Separation of a thermotropic liquid crystalline polymer from polypropylene composites

This work is concerned with determining how to effectively recycle wholly thermoplastic composites comprised of a polypropylene (PP) matrix reinforced with a thermotropic liquid crystalline polymer (TLCP). A novel reclamation process was developed in which the TLCP could be recovered from the PP matrix. Reactive extrusion was used to reduce the molecular weight of the PP (Montell 6523) and to facilitate phase separation. The melt was then extruded into a heated mineral oil bath, which separated the TLCP (DuPont HX8000) from the matrix by dissolving the PP. It was found that greater than 70 wt% of the TLCP could be reclaimed from the PP matrix at a purity of greater than 96 wt%. In order to determine the ability to reuse the reclaimed HX8000, injection molded in situ composites were generated and their mechanical properties were determined. When the neat HX8000 component was partially replaced with reclaimed HX8000, the injection molded TLCP/PP composites showed no discernible difference in mechanical properties.