全文获取类型
收费全文 | 53573篇 |
免费 | 4804篇 |
国内免费 | 2451篇 |
学科分类
工业技术 | 60828篇 |
出版年
2024年 | 197篇 |
2023年 | 919篇 |
2022年 | 1542篇 |
2021年 | 2289篇 |
2020年 | 1801篇 |
2019年 | 1524篇 |
2018年 | 1684篇 |
2017年 | 1931篇 |
2016年 | 1636篇 |
2015年 | 2312篇 |
2014年 | 2859篇 |
2013年 | 3512篇 |
2012年 | 3754篇 |
2011年 | 4029篇 |
2010年 | 3460篇 |
2009年 | 3207篇 |
2008年 | 3102篇 |
2007年 | 2814篇 |
2006年 | 2885篇 |
2005年 | 2493篇 |
2004年 | 1666篇 |
2003年 | 1326篇 |
2002年 | 1178篇 |
2001年 | 1031篇 |
2000年 | 1098篇 |
1999年 | 1191篇 |
1998年 | 906篇 |
1997年 | 789篇 |
1996年 | 762篇 |
1995年 | 616篇 |
1994年 | 499篇 |
1993年 | 384篇 |
1992年 | 307篇 |
1991年 | 210篇 |
1990年 | 176篇 |
1989年 | 145篇 |
1988年 | 128篇 |
1987年 | 82篇 |
1986年 | 69篇 |
1985年 | 37篇 |
1984年 | 38篇 |
1983年 | 30篇 |
1982年 | 45篇 |
1981年 | 20篇 |
1980年 | 31篇 |
1979年 | 16篇 |
1978年 | 11篇 |
1977年 | 16篇 |
1976年 | 9篇 |
1974年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
采用正硅酸乙酯(TEOS)和3-氨丙基三乙氧基硅烷(APTES)通过共缩聚法合成介孔二氧化硅(MCM-41)。首先对其氨基修饰,再通过有机合成接枝—R基团(—R:—CHO、—OH、—CH3、—COOH),制备得到Me-Ph-NH-MCM-41、OHC-Ph-NH-MCM-41、HO-Ph-NH-MCM-41、HOOC-Ph-NH-MCM-41四种不同的药物载体。利用FT-IR、Zeta电位、XRD和SEM对其结构和形貌表征,结果表明NH2-MCM-41改性成功。以罗丹明B(RhB)为模型进行载药性能测试,并考察了此释药系统在模拟不同pH的体液下的敏感释药行为,同时探究了不同—R基团对释药的影响。结果显示,四种载体在中性条件下几乎不发生药物释放,通过改变环境体系pH可以有效控制药物释放,其释药行为可以用Korsmeyer-Peppas动力学模型来描述。实验表明,释药量:RhB@HOOC-Ph-NH-MCM-41>RhB@OHC-Ph-NH-MCM-41>RhB@HO-Ph-NH-MCM-41>RhB@Me-Ph-NH-MCM-41,不同—R基团的药物载体的pH响应性不同,其中RhB@HOOC-Ph-NH-MCM-41释药量在pH=1.2时可达57.87%,在用于药物智能控释材料方面具有一定的应用潜力。 相似文献
32.
欺骗式干扰通过发射与真实卫星信号相似的信号误导接收机产生错误的定位结果,具有极大的危害。该文针对转发式欺骗干扰,提出一种基于信号重构的单天线欺骗干扰抑制方法。该方法首先通过参数估计方法估计出欺骗信号载波频率和码相位,然后构建欺骗信号子空间正交投影矩阵以抑制干扰。仿真实验结果表明该方法对欺骗干扰具有良好的抑制效果,能够保障接收机在干扰环境中实现有效定位,并具有较低的运算复杂度。 相似文献
33.
Shouguang Wang Mengdi Gan Mengchu Zhou Dan You 《IEEE/CAA Journal of Automatica Sinica》2015,2(4):345-352
As a powerful analysis tool of Petri nets, reachability trees are fundamental for systematically investigating many characteristics such as boundedness, liveness and reversibility. This work proposes a method to generate a reachability tree, called ωRT for short, for a class of unbounded generalized nets called ω-independent nets based on new modified reachability trees (NMRTs). ωRT can effectively decrease the number of nodes by removing duplicate and ω-duplicate nodes in the tree, and verify properties such as reachability, liveness and deadlocks. Two examples are provided to show its superiority over NMRTs in terms of tree size. 相似文献
34.
35.
Elucidation of colour development and microstructural characteristics of Allium sativum fumigated with acetic acid 下载免费PDF全文
Li Li Dan Wang Xihong Li Yu Wang Xiaofeng Ju 《International Journal of Food Science & Technology》2015,50(5):1083-1088
It has been well known that the greening of Allium sativum cloves could be formed after immersed in acetic acid solution. Nonetheless, no investigation was reported on colour development of A. sativum in response to acetic acid vapour until now. In this study, the brief exposure of A. sativum to acetic acid vapour (200–400 ppm) was combined with controlled atmosphere (5%, 20% and 80% CO2) packaging storage to break cell membrane and green garlic. The garlic bulbs were fumigated with acetic acid before controlled CO2 atmosphere packaging for 25 days at 4 °C. Fumigation with 200 ppm acetic acid followed by high CO2 atmosphere packaging (80% CO2) facilitated the garlic greening. It was also verified that γ‐glutamyl transpeptidase was involved in garlic greening in present study, and the compromise of glacial acetic acid vapour fumigation and CO2 gas atmosphere in package stored at low temperature could result in garlic greening as well. 相似文献
36.
针对郭庄煤业选煤厂振动筛振动筛分方式可靠性差、筛分效率低下、物料筛分率低的难题,本文提出了三种新的振动筛分方案,对不同筛分方案的实际应用效果进行了分析。结果表明三移动一摆动的振动筛分方式对物料的综合分散度最高,稳定性好,该筛分方案已在郭庄煤业选煤厂煤炭筛分过程中得到了全面的应用。 相似文献
37.
Peng Jiang Jiafeng Lu Kun Li Xiquan Chen Ruiqi Dan 《Fullerenes, Nanotubes and Carbon Nanostructures》2020,28(5):381-386
AbstractPreparation condition can affect the structure and the properties of nanofiber membrane. In order to explore suitable conditions to prepare the Fe3O4/PVDF nanofiber membrane with good hydrophobicity, the hydrophobicity of Fe3O4/PVDF nanofiber membranes obtained by electrospinning was investigated by changing preparation conditions like weight percentage of Fe3O4 nanoparticles, blending quality concentration of poly (vinylidene fluoride) (PVDF) and Fe3O4 nanoparticles, and positive voltage. And the variations of hydrophobicity of Fe3O4/PVDF nanofiber membranes modified by 1H, 1H, 2H, 2H-perfluorodecyl trimethoxysilane were studied. The results show that the hydrophobicity of Fe3O4/PVDF nanofiber membranes has changed under different preparation conditions. The contact angles of samples increased after a modification by 1H, 1H, 2H, 2H-perfluorodecyl trimethoxysilane, which indicates that the hydrophobicity of Fe3O4/PVDF nanofiber membranes has been enhanced. 相似文献
38.
39.
Machine Intelligence Research - This paper proposes an image encryption algorithm LQBPNN (logistic quantum and back propagation neural network) based on chaotic sequences incorporating quantum... 相似文献
40.
WeiJia Luo LingXia Li Shihui Yu Qianyu Guo Bowen Zhang Zheng Sun 《Ceramics International》2018,44(11):12414-12419
Low-loss (Zn1-xNix)ZrNbTaO8 (0.02?≤?x?≤?0.10) ceramics possessing single wolframite structure are initiatively synthesized by solid-state route. Based on the results of Rietveld refinement, complex chemical bond theory is used to establish the correlation between structural characteristics and microwave performance in this ceramic system. A small amount of Ni2+ (x?=?0.06) in A-site with the fixed substitution of Ta5+ in B-site can effectually raise the Q?×?f value of ZnZrNb2O8 ceramic, embodying a dense microstructure and high lattice energy. The dielectric constant and τf are mainly affected by bond ionicity and the average octahedral distortion. The (Zn0.94Ni0.06)ZrNbTaO8 ceramic sample sintered at 1150?°C for 3?h exhibits an outstanding combination of microwave dielectric properties: εr =?27.88, Q?×?f?=?128,951?GHz, τf =?–39.9?ppm/°C. Thus, it is considered to be a candidate material for the communication device applications at high frequency. 相似文献