Thermal,Structural, and Enhanced Photoluminescence Properties of Eu3+‐doped Transparent Willemite Glass–Ceramic Nanocomposites

The precursor glass in the ZnO–Al₂O₃–B₂O₃–SiO₂ (ZABS) system doped with Eu₂O₃ was prepared by the melt‐quench technique. The transparent willemite, Zn₂SiO₄ (ZS) glass–ceramic nanocomposites were derived from this precursor glass by a controlled crystallization process. The formation of willemite crystal phase, size, and morphology with increase in heat‐treatment time was examined by X‐ray diffraction (XRD) and field‐emission scanning electron microscopy (FESEM) techniques. The average calculated crystallite size obtained from XRD is found to be in the range 18–70 nm whereas the grain size observed in FESEM is 50–250 nm. The refractive index value is decreased with increase in heat‐treatment time which is caused by the partial replacement of ZnO₄ units of ZS nanocrystals by AlO₄ units due to generation of vacancies. Fourier transform infrared (FTIR) reflection spectroscopy was used to evaluate its structural evolution. Vickers hardness study indicates marked improvement of hardness in the resultant glass‐ceramics compared with its precursor glass. The photoluminescence spectra of Eu³⁺ ions exhibit emission transitions of ⁵D₀→⁷F_j (j = 0, 1, 2, 3, and 4) and its excitation spectra show an intense absorption band at 395 nm. These spectra reveal that the luminescence performance of the glass–ceramic nanocomposites is enhanced up to 17‐fold with the process of heat treatment. This enhancement is caused by partitioning of Eu³⁺ ions into glassy phase instead of into the willemite crystals with progress of heat treatment. Such luminescent glass–ceramic nanocomposites are expected to find potential applications in solid‐state red lasers, phosphors, and optical display systems.     

Development and long-term in vivo evaluation of a biodegradable urethane-doped polyester elastomer

We have recently reported upon the development of crosslinked urethane-doped polyester (CUPE) network elastomers, which was motivated by the desire to overcome the drawbacks presented by crosslinked network polyesters and biodegradable polyurethanes for soft tissue engineering applications. Although the effect of the isocyanate content and post-polymerization conditions on the material structure-property relationship was examined in detail, the ability of the diol component to modulate the material properties was only studied briefly. Herein, we present a detailed report on the development of CUPE polymers synthesized using diols 4, 6, 8, 10, or 12 methylene units in length in order to investigate what role the diol component plays on the resulting material's physical properties, and assess their long-term biological performance in vivo. An increase in the diol length was shown to affect the physical properties of the CUPE polymers primarily through lowered polymeric crosslinking densities and elevated material hydrophobicity. The use of longer chain diols resulted in CUPE polymers with increased molecular weights resulting in higher tensile strength and elasticity, while also increasing the material hydrophobicity to lower bulk swelling and prolong the polymer degradation rates. Although the number of methylene units largely affected the physical properties of CUPE, the choice of diol did not affect the overall polymer cell/tissue-compatibility both in vitro and in vivo. In conclusion, we have established the diol component as an important parameter in controlling the structure-property relationship of the polymer in addition to diisocyanate concentration and post-polymerization conditions. Expanding the family of CUPE polymers increases the choices of biodegradable elastomers for tissue engineering applications.     

Loading Rate Effect on Nanohardness of Soda-Lime-Silica Glass

To understand how hardness, the key design parameter for applications of brittle solids such as glass concerning contact deformation, is affected by loading rate variation, nanoindentation with a Berkovich tip was used to measure the nanohardness of a 330-μm-thick soda-lime-silica glass as a function of loading rate (1 to 1000 mN·s⁻¹). The results showed for the very first time that, with variations in the loading rate, there was a 6 to 9 pct increase in the nanohardness of glass up to a threshold loading rate (TLR), whereafter it did not appreciably increase with further increase in loading rate. Further, the nanohardness data showed an indentation size effect (ISE) that obeyed the Meyer’s law. These observations were explained in terms of a strong shear stress component developed just beneath the nanoindenter and the related shear-induced deformation processes at local microstructural scale weak links. The significant or insignificant presence of shear-induced serrations in load depth plots and corresponding scanning electron microscopic evidence of a strong or mild presence of shear deformation bands in and around the nanoindentation cavity supported such a rationalization. Finally, a qualitative picture was developed for different deformation processes induced at various loading rates in glass.     

Enhancement of convective cooling using oscillating fins

Tailoring the local flow field around a fin can substantially enhance the forced convection heat transfer from a conventional heat sink. A fin is set into oscillation leading to rupture of the thermal boundary layer developed on either side of the fin. This enhancement in heat transfer is demonstrated through an increase in the time-averaged Nusselt Number (Nu) on the fin surfaces. Nu has been found to be strongly dependent on the flow Reynolds Number (Re), the frequency and amplitude of the fin oscillations. A threshold amplitude and frequency is identified beyond which Nu improvements are observed for fixed Re.     

Intergranular Critical Current Density in Polycrystalline (Bi-Pb)-2223 High Temperature Superconductor by ac Susceptibility Measurements

The field dependence of real () and imaginary () component of ac susceptibility of superconductors within the critical state model can conveniently be used for evaluating the critical current when field amplitude is larger than the penetration field. A method to analyze the real () and imaginary () component of fundamental ac susceptibility with the objective of extracting the temperature dependence of critical current density J _c(T) is reported. The procedure makes use of the ac susceptibility data of two polycrystalline (Bi-Pb)-2223 samples measured with different excitation amplitudes below and close to the critical temperature. The temperature dependence of J _c is extracted using the isothermal scan over and data. Results obtained from this procedure are found to be in fair agreement with J _c(T) calculated from traditional loss-maximum data.     

Spent fuel reprocessing: A vital link in Indian nuclear power program

The success of the three stage Indian nuclear energy program is inter-linked with the establishment of an efficient closed fuel cycle approach with recycling of both fissile and fertile components of the spent fuel to appropriate reactor systems. The Indian reprocessing journey was started way back in 1964 with the commissioning of a plant based on PUREX technology to reprocess aluminum clad natural uranium spent fuel from the research reactor CIRUS. After achieving the basic skills, a power reactor reprocessing facility was built to reprocess spent fuel from power reactors. Adequate design and operating experience was gained from these two plants for mastering the reprocessing technology. The first plant, being the maiden venture, based on indigenous technology had to undergo many modifications during its operation and finally needed refurbishment for continued operation. Decommissioning and decontamination of this plant was carried out meticulously to allow unrestricted access to the cells for fresh installation. A third plant was built for power reactor spent fuel reprocessing to serve as a design standard for future plants with the involvement of industry. Over the years, spent fuel reprocessing based on PUREX technology has reached a matured status and can be safely deployed to meet the additional reprocessing requirements to cater to the expanding nuclear energy program. Side by side with the developments in the spent natural uranium fuel reprocessing, irradiated thoria reprocessing is also perused to develop THOREX into a robust process. The additional challenges in this domain are being addressed to evolve appropriate technological solutions. Advancements in the field of science and technology are being absorbed to meet the challenges of higher recovery combined with reduced exposure and environmental discharges.     

Scour Downstream of an Apron Due to Submerged Horizontal Jets

The results of an experimental investigation on scour of noncohesive sediment beds (uniform and nonuniform sediments) downstream of an apron due to a submerged horizontal jet issuing from a sluice opening are presented. Attempts are made to explain the similarity existing in the scour process and profiles (including dune in the downstream of the scour hole). The scour profiles at different times follow a particular geometrical similarity and can be expressed by the combination of two polynomials. Using experimental scour depth at different times, the time variation of scour depth is scaled by an exponential law, where time scale increases linearly with densimetric Froude number. The equilibrium scour depth, related to the sediment size relative to the sluice opening, decreases with increase in sediment size and sluice opening. On the other hand, the equilibrium scour depth increases with increase in densimetric Froude number. The variation of equilibrium scour depth with tailwater depth indicates a critical tailwater depth corresponding to a minimum equilibrium scour depth. The effect of sediment gradation on scour depth is pronounced for nonuniform sediments, which reduce scour depth significantly due to formation of an armor layer, and therefore prompted study of the reduction of scour depth by a launching apron placed downstream of the rigid apron. The results show that the average reduction of scour depth by placing a launching apron was 39%, having a maximum of 57.3% and a minimum of 16.2%. The characteristic parameters affecting maximum equilibrium scour depth are identified based on the physical reasoning and dimensional analysis. Equation of maximum equilibrium scour depth obtained empirically agrees well with the experimental data.     

Thermal Transport in BPSCCO System Between 20 and 170 K

Thermal conductivity of superconducting (Bi,Pb)2223 pellet in the temperature range 20–170 K is reported. Electronic contribution to thermal conductivity in the normal state is estimated to be 25%. Considering both phonon and phonon + electron approach, we attempted to examine the observed nature of the temperature dependence of thermal conductivity. Our analysis strongly supports the role of phonons as well as electrons in the origin of the thermal conductivity peak in the superconducting state. Some of the microscopic quantities evaluated from the best-fit parameters obtained from phonon + electron approach give reasonable values.     

Thermoelectric Power Studies on YBa2?xCaxCu3O7?δ System

The temperature dependence of the thermoelectric power of calcium substituted YBa_2–x Ca _x Cu₃O_7– pellets with 0x1.5 is presented between 60 K and 300 K. A metal–insulator transition was reported earlier by us in this system and was attributed to the ionic size-dependent localization effect. While the sign of thermoelectric power of all the calcium substituted samples was found to be positive, its magnitude increases significantly with calcium content in YBCO. The normal state thermoelectric power data of substituted YBa_2–x Ca _x Cu₃O_7– (0x1.5) are discussed in light of a two-band model originally proposed by Gottwick et al. for heavy fermion systems and later modified by Forro et al.     

A note on the linear instability of the Blasius flow

Summary It is found that in a ribbon-excited Blasius boundary layer, a wave Reynolds number defined here on the basis of phase speed and wave number of the disturbance remains nearly independent of the local mean flow Reynolds number, and so also of the streamwise distance, under the parallel flow approximation. Consequently, a limited similarity feature of the Orr-Sommerfeld equation has been found to exist for the streamfunction in the outer region of the boundary layer.