Clean seas: a North Sea test site

The Clean Seas project focused on the role that existing Earth observing satellites might play in monitoring marine pollution. Results are presented here from August 1997, for the North Sea test site, using sea surface temperature (SST), colour and synthetic aperture radar (SAR) images in conjunction with a hydrodynamic model. There was good correlation between data sources, e.g. between SST and ERS-2 SAR images. Both datasets showed the development of fine plume structures close to the Rhine outflow, apparently associated with the outflow, and possibly caused by tidal pulsing of the Rhine Plume.

The model reproduced general temperature and sediment distributions well, but fine structures were not reproduced. Model sediment distribution patterns were verified using ‘chlorophyll concentration’ data from colour sensors, representative of sediment concentration in turbid water. In conjunction with the visible channels of the Advanced Very High Resolution Radiometer and Along-Track Scanning Radiometer, they give an uncalibrated measure of the sediment load. The model gives a more complete picture of the temporal dispersion of the Rhine Plume over time than is evident from the remotely sensed data alone.     

Monodisperse Metal Nanoparticle Catalysts: Synthesis, Characterizations, and Molecular Studies Under Reaction Conditions

We aim to develop novel catalysts that exhibit high activity, selectivity and stability under real catalytic conditions. In the recent decades, the fast development of nanoscience and nanotechnology has allowed synthesis of nanoparticles with well-defined size, shape and composition using colloidal methods. Utilization of mesoporous oxide supports effectively prevents the nanoparticles from aggregating at high temperatures and high pressures. Nanoparticles of less than 2?nm sizes were found to show unique activity and selectivity during reactions, which was due to the special surface electronic structure and atomic arrangements that are present at small particle surfaces. While oxide support materials are employed to stabilize metal nanoparticles under working conditions, the supports are also known to strongly interact with the metals through encapsulation, adsorbate spillover, and charge transfer. These factors change the catalytic performance of the metal catalysts as well as the conductivity of oxides. The employment of new in situ techniques, mainly high-pressure scanning tunneling microscopy (HPSTM) and ambient-pressure X-ray photoelectron spectroscopy (APXPS) allows the determination of the surface structure and chemical states under reaction conditions. HPSTM has identified the importance of both adsorbate mobility to catalytic turnovers and the metal substrate reconstruction driven by gaseous reactants such as CO and O₂. APXPS is able to monitor both reacting species at catalyst surfaces and the oxidation state of the catalyst while it is being exposed to gases. The surface composition of bimetallic nanoparticles depends on whether the catalysts are under oxidizing or reducing conditions, which is further correlated with the catalysis by the bimetallic catalytic systems. The product selectivity in multipath reactions correlates with the size and shape of monodisperse metal nanoparticle catalysts in structure sensitive reactions.     

Mechanistic investigation and selectivity of the grafting onto C60 of macroradicals prepared by cobalt-mediated radical polymerization

The grafting mechanism of poly(vinyl acetate) macroradicals prepared by cobalt-mediated radical polymerization onto C₆₀ is investigated. The experimental conditions directly impact the nature and stability of the PVAc/C₆₀ adducts. In the presence of residual initiating radicals that can compete with PVAc° macroradicals for addition onto C₆₀, mixtures of PVAc/C₆₀ adducts having between one and eight polymer chains per C₆₀ are formed. PVAc/C₆₀ adducts prepared with low [PVAc]:[C₆₀] ratios may contain weak C₆₀–C₆₀ bonds that further dissociate and account for the instability of the products. The formation of such dimers can be lessened by increasing the temperature from 30 °C to 100 °C. The temperature increase also allows a complete dissociation of the PVAc-Co dormant species into PVAc° macroradicals and an almost quantitative grafting of eight PVAc chains onto C₆₀, leading to well-defined C₆₀(PVAc)₈ octa-adducts. These results might shed new light on the grafting onto C₆₀ of macroradicals prepared by other CRP techniques.     

PLLA/Flax Mat/Balsa Bio-Sandwich—Environmental Impact and Simplified Life Cycle Analysis

In the present paper the environmental impact of biocomposites and bio-sandwich materials production are evaluated, using simplified Life Cycle Analysis (LCA) following the procedure recommended in the ISO 14044 standard. The materials are dimensioned and evaluated by comparing with reference materials, glass mat reinforced unsatured polyester and glass mat/unsatured polyester/balsa sandwich. The results indicate that bio-sandwich materials are very attractive in terms environmental impact. However further improvements in biocomposite and bio-sandwich mechanical strength are necessary if they are to be used in transport application compared to glass/polyester and glass/polyester/balsa sandwich.     

Steam reforming of methanol over ruthenium impregnated ceria,alumina and ceria–alumina catalysts

The wet impregnation method was used to prepare different ruthenium promoted Ce–Al catalysts. These catalysts were used in the steam reforming of methanol reaction (SRM). The effects of the reaction temperature (200–400 C) and the catalyst composition were studied for optimization reasons. The steam to methanol molar ratio was kept constant (S/M = 2). The promotion of cerium/aluminum oxides with Ru enhanced their catalytic activity. The catalytic test results showed that the Ru/Ce combination was the most beneficial. The synergy between Ru and cerium oxide led to the formation of active sites with excellent redox properties. For high active phase content, the 5 RuCe catalyst exhibited the highest hydrogen production amount with no CO formation. This catalyst was kept under stream for 5 days at 400 C, and no significant deactivation was observed. Copyright © 2016 John Wiley & Sons, Ltd.     

CoopStor: a cooperative reliable and efficient data collection protocol in fault and delay tolerant wireless networks

Wireless Networks - Internet of things consist in the deployment of constrained and battery-powered devices with a radio interface. Most industrial applications require to respect strict...     

Ultra-high performance concrete and fiber reinforced concrete: achieving strength and ductility without heat curing

Ultra-high performance concrete (UHPC) and ultra-high performance fiber reinforced concrete (UHP-FRC) were introduced in the mid 1990s. Special treatment, such as heat curing, pressure and/or extensive vibration, is often required in order to achieve compressive strengths in excess of 150 MPa (22 ksi). This study focuses on the development of UHP-FRCs without any special treatment and utilizing materials that are commercially available on the US market. Enhanced performance was accomplished by optimizing the packing density of the cementitious matrix, using very high strength steel fibers, tailoring the geometry of the fibers and optimizing the matrix-fiber interface properties. It is shown that addition of 1.5% deformed fibers by volume results in a direct tensile strength of 13 MPa, which is 60% higher than comparable UHP-FRC with smooth steel fibers, and a tensile strain at peak stress of 0.6%, which is about three times that for UHP-FRC with smooth fibers. Compressive strength up to 292 MPa (42 ksi), tensile strength up to 37 MPa (5.4 ksi) and strain at peak stress up to 1.1% were also attained 28 days after casting by using up to 8% volume fraction of high strength steel fibers and infiltrating them with the UHPC matrix.     

Jet Mixing in Direct-Chill Casting of Aluminum: Crater Effects and its Consequence on Centerline Segregation

Recent reports have demonstrated the possibility of mitigating macrosegregation during the Direct-Chill casting of rolling slab ingots using an impinging jet. Herein, an analytical model is presented to predict the shape of the crater formed due to the impact of the jet on the slurry region. The model takes into account alloy composition, physical dimension, and casting speed on the distribution of forces and crater shape. The calculated shape of the crater profile is used to explain the centerline depletion in the impingement region previously reported.