Lateral Performance of Full-Scale Bridge Abutment Wall with Granular Backfill

Bridge abutments typically contain a backwall element that is designed to break free of its base support when struck by a bridge deck during an earthquake event and push into the abutment backfill soils. Results are presented for a full-scale cyclic lateral load test of an abutment backwall configured to represent the dimensions (1.7?m height), boundary conditions, and backfill materials (compacted silty sand) that are typical of California bridge design practice. An innovative loading system was utilized that operates under displacement control and that assures horizontal wall displacement with minimal vertical displacement. The applied horizontal displacement ranged from null to approximately 11% of the wall height (0.11H). The maximum earth pressure occurred at a wall displacement of 0.03H and corresponded to a passive earth pressure coefficient of Kp = 16.3. The measured force distribution applied to the wall from hydraulic actuators allowed the soil pressure distribution to be inferred as triangular in shape and the mobilized wall-soil interface friction to be evaluated as approximately one-third to one-half of the soil friction angle. Post-test trenching of the backfill showed a log-spiral principal failure surface at depth with several relatively minor shear surfaces further up in the passive wedge. The ultimate passive resistance is well estimated by the log-spiral method and a method of slices approach. The shape of the load-deflection relationship is well estimated by models that produce a hyperbolic curve shape.     

Enclosure size and hormonal state affect timing of nest return in female meadow voles (Microtus pennsylvanicus).

We investigated 2 aspects of the hormonal regulation of maternal behavior in meadow voles (Microtus pennsylvanicus): (a) when the transition in maternal responsiveness from primarily hormonal control to regulation by pup cues occurs; and (b) the effect of housing enclosure size on maternal nest attendance in voles injected with a prolactin suppressant, cysteamine hydrochloride (150 mg/kg) on Postnatal Day 2. In Experiment 1, meadow voles required 96 hr of pup contact to finish the transition from hormonal to pup-mediated maternal behavior; a period longer than found in other rodents. In Experiment 2, females housed in larger enclosures spent less time with pups after drug injection, primarily because they increased the amount of time they stayed away from the nest each time they left. In contrast, drug-treated females in standard cages showed no change in their patterns of nest attendance, possibly due to the presence of salient cues from nearby pups. Under naturalistic conditions, a female vole’s hormonal state may regulate nest approach, and help establish the necessary alternation between leaving the nest (e.g., to forage) and attending pups. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Sorption of phosphorous to Filtralite-P--the effect of different scales

Sorption of P to the filter material Filtralite-P was examined at a small, medium and large scale. In the small- and meso-scale laboratory models, the sorbed amount of total phosphorus (P) was heterogeneously distributed with more P sorbed in the inlet zone and the bottom layers. The full-scale system had, on the other hand, the highest sorbed concentration in the outlet region. The overall P sorption capacity of the material was 8030, 4990 and 521 mg P kg(-1) Filtralite-P for Box 1, Box 2 and meso scale, respectively. This equals 4.4, 2.8 and 0.29 kg P m(-3) material, respectively. However, the maximum sorption capacities found were 2500, 3887 and 4500 mg P kg(-1) Filtralite-P for the two small-scale box systems and the meso-scale container, respectively. In the full-scale system the overall P sorption capacity of the material was 52 mg P kg(-1) Filtralite-P (0.029 kg P m(-3) Filtralite-P with a maximum sorbed amount of P of 249 mg P kg(-1). Results from both the small- and meso-scale system show that when a constructed wetland (CW) is saturated, i.e. when the outlet concentration has reached its maximum allowed concentration of 1.0 mg P l(-1), only parts of the filter material will have reached the sorption capacity. Sequential extractions of Filtralite-P showed that the loosely bound P, Ca-P and Al-P were the primary P sorption pools both in the small-scale models and in the full-scale CW. However, the proportion of these three fractions varied with time and change in pH. A white product precipitated in the outlet zone of both the small-scale box models as well as the onsite CW. The surface of these precipitation particles was identified by X-ray diffraction and SEM method as CaCO3 and precipitated Ca- and Mg-phosphates.     

The use of desorbing agents in electrodialytic remediation of harbour sediment

Electrodialytic removal of Cu, Zn, Pb and Cd from contaminated harbour sediment was made with the emphasis of testing the effectiveness of different desorbing agents: HCl, NaCl, citric acid, lactic acid, ammonium citrate and distilled water. Extraction experiments with the desorbing agents were made prior to the electrodialytic experiments. The extractions showed that HCl was most efficient for metal desorption, probably due to the low pH and complexation with chloride. The metals were not extracted by distilled water. However, in the electrodialytic experiments, the removal was high when using distilled water and the desorbing agents did generally not enhance the heavy metal removal compared to distilled water. The only exception was with lactic acid, where the Cu removal was 20% higher compared to the other desorbing agents. The removal was 48% Cu, 80% Zn, 96% Pb and 98% Cd, when using distilled water. Metal speciation with the different desorbing agents was simulated with the geochemical model Visual MINTEQ version 2.15. Variations in the Cl concentration were found to be of crucial importance since it influences the formation of metal chlorocomplexes, especially uncharged species. All the acidic desorbing agents were predicted to form mostly cationic species, which was in agreement with the removal direction in the electrodialytic remediation experiments.     

Projection of hazardous air pollutant emissions to future years

Projecting a hazardous air pollutant (HAP) emission inventory to future years can provide valuable information for air quality management activities such as prediction of program successes and helping to assess future priorities. We have projected the 1999 National Emission Inventory for HAPs to numerous future years up to 2020 using the following tools and data: the Emissions Modeling System for Hazardous Air Pollutants (EMS-HAP), the National Mobile Inventory Model (NMIM), emission reduction information resulting from national standards and economic growth data. This paper discusses these projection tools, the underlying data, limitations and the results. The results presented include total HAP emissions (sum of pollutants) and toxicity-weighted HAP emissions for cancer and respiratory noncancer effects. Weighting emissions by toxicity does not consider fate, transport, or location and behavior of receptor populations and can only be used to estimate relative risks of direct emissions. We show these projections, along with historical emission trends. The data show that stationary source programs under Section 112 of the Clean Air Act Amendments of 1990 and mobile source programs which reduce hydrocarbon and particulate matter emissions, as well as toxic emission performance standards for reformulated gasoline, have contributed to and are expected to continue to contribute to large declines in air toxics emissions, in spite of economic and population growth. We have also analyzed the particular HAPs that dominate the source sectors to better understand the historical and future year trends and the differences across sectors.     

Creating and using the urgent metadata catalogue and thesaurus

The Urban Regeneration and the Environment Research Programme (URGENT) required a system for cataloguing its datasets and enabling its scientific community to discover what data were available to it. This community was multidisciplinary in nature and therefore needed a range of facilities for searching. Of particular importance were facilities to help those unfamiliar with specialist terminology. To meet these needs, four applications were designed and developed: a Metadata Capture Tool for describing datasets in compliance with the National Geospatial Data Framework (NGDF) standard, a Term Entry Tool for creating an ISO compliant thesaurus, a Thesaurus Builder for merging thesauri and a Search Tool. To encourage users to help in cataloguing data, the capture tools were written as stand alone applications, which users could keep and use to build their own metadatabases. The tools contained export and import facilities that allowed the URGENT Data Centre to build a central database and publish it upon the web. During the development work, it was found necessary to extend the NGDF standard as it could not adequately describe time variant or 3-D atmospheric datasets. The four applications met their design objectives. However, a number of ergonomic issues will need to be addressed if the system is to meet the needs of the much larger up coming programmes. The main challenges will be moving from the NGDF standard to the ISO standard, hence bringing the work into line with the recommendations of the INSPIRE Project, and merging the metadatabase with the scientific database, which enable metadata maintenance to be semi-automated.     

Housing intermediary services in China: the rise and fall of ‘Fang Wu Yin Hang’

Housing reforms in China are often conceived to have engendered a gradual shift towards a market system. New institutions have been introduced to enable decentralized, monetarized and privatized allocation of housing units. This study explores the emergence, growth and downfall of an intermediary service (known as ‘fang wu yin hang’) created spontaneously by real estate agents to facilitate housing transactions in the Chinese cities. Although this new institution looked capable of strengthening the rationality, efficiency, transparency and impersonality of China’s housing market, it was abandoned soon after its inception. The failure of this transient service suggests the presence of some social institutions, which could have blocked China’s progress towards a full-fledged market system in the housing sector.

Epoxide Hydrolase‐Catalysed Kinetic Resolution of a Spiroepoxide,a Key Building Block of Various 11‐Heterosteroids

Two microbial epoxide hydrolases – i.e., Aspergillus niger (AnEH) and Rhodococcus erythropolis (the so‐called “Limonene EH”: LEH) were used to achieve, for the first time, the biocatalysed hydrolytic kinetic resolution (BHKR) of spiroepoxide rac‐ 1 . This compound is a strategic key building block allowing the synthesis of 11‐heterosteroids. Interestingly enough, the two enzymes exhibited opposite and therefore complementary enantioselectivity allowing us to isolate the residual (R,R)‐ 1 (from AnEH) and the residual (S,S)‐ 1 (from LEH) in nearly enantiopure forms (>98 %). Their absolute configurations were determined by X‐ray crystallography. An opposite regioselectivity of the oxirane ring opening for both enantiomers of substrate 1 , determined using H₂¹⁸O labelling and chiral GC‐MS analysis, was also observed, corresponding to an attack at the less substituted carbon atom using AnEH, and at the most substituted carbon atom using LEH. A chemical process‐improving methodology was also developed. This allowed us to obtain both enantiomers of the substrate in high enantiomeric purity (99 %) and optimised quantity. In the case of the AnEH, the use of a biphasic (water/isooctane) reaction medium allowed us to increase the global substrate concentration up to 200 g/ L. The preparation of both enantiomers of 1 clearly paves the way to the preparative scale synthesis and biochemical evaluation of the corresponding 11‐heterosteroid enantiomers.     

Landscape as framework for integrating local subsistence and ecotourism: a case study in Zimbabwe

Ecotourism can be a solution for mitigating the negative environmental and socio-economic impacts of new developments in fragile environments. Before planning an ecotourist project, it is necessary to consider an area that not only covers the margins of the development zone, but also a wider perimeter of physically and culturally related landscape parts. This paper describes an approach to the demarcation and analysis of an expanded zone around a new reservoir near Bulawayo, larger than an originally designated narrow natural fringe. The concept gains in many ways, in landscape diversity, in cultural assets and in interaction with local residents to whom ecotourisms should be profitable in the first place.