New Acceleration Principle of Charged Particles for Electronic Applications. The General Hierarchic Description

A new principle of acceleration of changed particles and quasineutral plasma beams is proposed and theoretically substantiated. The essence of this new acceleration principle is die utilization of EH-undulated fields, which resemble those of EH free-electron laser pumping systems. Here the charged particles are moving in a superposition of crossed magnetic and electric vortex undulated fields (EH-accelerator). The advantage of such systems is that both negative (electrons) and positive (ions) charged particles are accelerated simultaneously in the same longitudinal direction. In addition to the concept of the EH-accelerators, a new theoretical approach (the theory of hierarchic oscillations and waves) is given further development here. This approach has been used as a basis for the general nonlinear theory of the EH-accelerators and some other similar isochronous electronic devices with long-time interactions. In addition, several new calculation methods are presented, including the method for nonlinear current density calculations (called the averaged current-density equation hierarchic method) and two versions of hierarchic asymptotic algorithms for the integration of Maxwell's equations.     

Should Russia increase domestic prices for natural gas?

Previous analyses of Russia's dual pricing system and hidden subsidies for natural gas, have neglected to assess the dual pricing system as a domestic environmental policy. If dual pricing is considered as a policy to reduce conventional air pollutants, it is more than economically justified in Russia on the basis of avoided health risks. In the short term, the substitution of coal for natural gas may result in significant additional human health risk, which translates into economic damage. An alternative abatement possibility is expensive and unlikely enforceable, due to weak environmental regulation. The authors conclude that while the price differential can be expected to diminish over time, as Russia increasingly moves to a market economy, in the near-term, dual pricing of natural gas remains the most efficient environmental policy for Russia.     

High-Gain Chemically Gated Organic Electrochemical Transistor

Organic electrochemical transistors (OECTs) have exhibited promising performance as transducers and amplifiers of low potentials due to their exceptional transconductance, enabled by the volumetric charging of organic mixed ionic/electronic conductors (OMIECs) employed as the channel material. OECT performance in aqueous electrolytes as well as the OMIECs’ redox activity has spurred a myriad of studies employing OECTs as chemical transducers. However, the OECT's large (potentiometrically derived) transconductance is not fully leveraged in common approaches that directly conduct chemical reactions amperometrically within the OECT electrolyte with direct charge transfer between the analyte and the OMIEC, which results in sub-unity transduction of gate to drain current. Hence, amperometric OECTs do not truly display current gains in the traditional sense, falling short of the expected transistor performance. This study demonstrates an alternative device architecture that separates chemical transduction and amplification processes on two different electrochemical cells. This approach fully utilizes the OECT's large transconductance to achieve current gains of 10³ and current modulations of four orders of magnitude. This transduction mechanism represents a general approach enabling high-gain chemical OECT transducers.     

Gerfried Zeichen — Aus Anlass seiner Emeritierung

Ohne Zusammenfassung     

On Chiroptical Spectroscopy of Turbid Media with Optically Soft, Large Spherical Particles

The influence of the size of particles on the circular dichroism and optical rotatory dispersion spectra of turbid layers with globules of chiral substances is studied. Simple equations for large chiral particles with the refractive index close to the refractive index of the surrounding medium are obtained and analyzed. Formulae derived can be used for the solution of the inverse problem, namely for obtaining intrinsic spectra of substances inside small particles from measurements of spectra for turbid layers.     

Bioinspired Magnetite Crystallization Directed by Random Copolypeptides

Control over magnetite (Fe₃O₄) formation is difficult to achieve in synthetic systems without using non‐aqueous media and high temperatures. In contrast, Nature employs often intrinsically disordered proteins to tightly tailor the size, shape, purity, and organization of the nanocrystals to optimize their magnetic properties. Inspired by such “flexible polyelectrolytes,” here random copolypeptides having different amino acid compositions are used as control agents in the bioinspired coprecipitation of magnetite through a ferrihydrite precursor, following a recently developed mineralization protocol. Importantly, the copolypeptide library is designed such that the amino acid composition can be optimized to simultaneously direct the size of the nanoparticles as well as their dispersibility in aqueous media in a one‐pot manner. Acidic amino acids are demonstrated to regulate the crystal size by delaying nucleation and reducing growth. Their relative content thus can be balanced to tune between the superparamagnetic and ferrimagnetic regimes, and high contents of negatively charged amino acids result in colloidal stabilization of superparamagnetic nanoparticles at high pH. Conversely, with positively charged lysine‐rich copolypeptides ferrimagnetic crystals are obtained which are stabilized at neutral pH and self‐organize in chains, as visualized by cryo‐transmission electron microscopy. Altogether, the presented findings give important insights for the future development of additive‐mediated nanomaterial syntheses.     

Engineering Gold Nanotubes with Controlled Length and Near‐Infrared Absorption for Theranostic Applications

Important aspects in engineering gold nanoparticles for theranostic applications include the control of size, optical properties, cytotoxicity, biodistribution, and clearance. In this study, gold nanotubes with controlled length and tunable absorption in the near‐infrared (NIR) region have been exploited for applications as photothermal conversion agents and in vivo photoacoustic imaging contrast agents. A length‐controlled synthesis has been developed to fabricate gold nanotubes (NTs) with well‐defined shape (i.e., inner void and open ends), high crystallinity, and tunable NIR surface plasmon resonance. A coating of poly(sodium 4‐styrenesulfonate) (PSS) endows the nanotubes with colloidal stability and low cytotoxicity. The PSS‐coated Au NTs have the following characteristics: i) cellular uptake by colorectal cancer cells and macrophage cells, ii) photothermal ablation of cancer cells using single wavelength pulse laser irradiation, iii) excellent in vivo photoacoustic signal generation capability and accumulation at the tumor site, iv) hepatobiliary clearance within 72 h postintravenous injection. These results demonstrate that these PSS‐coated Au NTs have the ideal attributes to develop their potential as effective and safe in vivo imaging nanoprobes, photothermal conversion agents, and drug delivery vehicles. To the best of knowledge, this is the first in vitro and in vivo study of gold nanotubes.     

3GPP LTE‐Assisted Wi‐Fi‐Direct: Trial Implementation of Live D2D Technology

This paper is a first‐hand summary on our comprehensive live trial of cellular‐assisted device‐to‐device (D2D) communications currently being ratified by the standards community for next‐generation mobile broadband networks. In our test implementation, we employ a full‐featured 3GPP LTE network deployment and augment it with all necessary support to provide real‐time D2D connectivity over emerging Wi‐Fi‐Direct (WFD) technology. As a result, our LTE‐assisted WFD D2D system enjoys the required flexibility while meeting the existing standards in every feasible detail. Further, this paper provides an account on the extensive measurement campaign conducted with our implementation. The resulting real‐world measurements from this campaign quantify the numerical effects of D2D functionality on the resultant system performance. Consequently, they shed light on the general applicability of LTE‐assisted WFD solutions and associated operational ranges.