New Process for Recovery of Zinc Sulfate and Sulfuric Acid from Zinc Electrowinning Bleed Solutions

Acid-base couple extractants extract sulfuric acid and zinc sulfate efficiently, selectively and reversibly. Their properties allowed development of a new, solvent extraction process for treating zinc electrowinning waste streams. In this process, about 95% of the sulfuric acid and 95% of the zinc can be recovered at concentrations high enough to be directly recycled to zinc production. Lime consumption and gypsum formation are substantially reduced. Only one extractant is used in the process, and zinc is recovered as zinc sulfate.     

One‐Step Solvent‐Free Synthesis and Characterization of Zn1−xMnxSe@C Nanorods and Nanowires

The carbon‐encapsulated, Mn‐doped ZnSe (Zn_1−xMn_xSe@C) nanowires, nanorods, and nanoparticles are synthesized by the solvent‐free, one‐step RAPET (reactions under autogenic pressure at elevated temperature) approach. The aspect ratio of the nanowires/nanorods is altered according to the Mn/Zn atomic ratio, with the maximum being observed for Mn/Zn = 1:20. A 10–20 nm amorphous carbon shell is evidenced from electron microscopy analysis. The replacement of Zn by Mn in the Zn_1−xMn_xSe lattice is confirmed by the hyperfine splitting values in the electron paramagnetic resonance (EPR) experiments. Raman experiments reveal that the Zn_1−xMn_xSe core is highly crystalline, while the shell consists of disordered graphitic carbon. Variable‐temperature cathodoluminescence measurements are performed for all samples and show distinct ZnSe near‐band‐edge and Mn‐related emissions. An intense and broad Mn‐related emission at the largest Mn alloy composition of 19.9% is further consistent with an efficient incorporation of Mn within the host ZnSe lattice. The formation of the core/shell nanowires and nanorods in the absence of any template or structure‐directing agent is controlled kinetically by the Zn_1−xMn_xSe nucleus formation and subsequent carbon encapsulation. Mn replaces Zn mainly in the (111) plane and catalyzes the nanowire growth in the [111] direction.     

Extracellular Vesicle MicroRNA That Are Involved in β-Thalassemia Complications

Beta thalassemia major (βT) is a hereditary anemia characterized by transfusion-dependency, lifelong requirement of chelation, and organ dysfunction. MicroRNA (miRNA) can be packed into extracellular vesicles (EVs) that carry them to target cells. We explored EV-miRNA in βT and their pathophysiologic role. Circulating EVs were isolated from 35 βT-patients and 15 controls. EV miRNA was evaluated by nano-string technology and real-time quantitative polymerase chain reaction (RT-qPCR). We explored effects of EVs on cell culture proliferation, apoptosis, and signal transduction. Higher amounts of small EV (exosomes) were found in patients than in controls. The expression of 21 miRNA was > two-fold higher, and of 17 miRNA < three-fold lower in βT-EVs than control-EVs. RT-qPCR confirmed differential expression of six miRNAs in βT, particularly miR-144-3p, a regulator of erythropoiesis. Exposure of endothelial, liver Huh7, and pancreatic 1.1B4 cells to βT-EVs significantly reduced cell viability and increased cell apoptosis. βT-EV-induced endothelial cell apoptosis involved the MAPK/JNK signal-transduction pathway. In contrast, splenectomized βT-EVs induced proliferation of bone marrow mesenchymal stem cells (BM-MSC). In summary, the miR-144-3p was strongly increased; βT-EVs induced apoptosis and decreased endothelial, pancreatic, and liver cell survival while supporting BM-MSC proliferation. These mechanisms may contribute to βT organ dysfunction and complications.     

Maturity determination of fresh dates by near infrared spectrometry

In Israel, fresh dates are normally harvested unripe and stored in a controlled environment until marketed. Proper ripening depends on maturity at harvest time. Sugar and water contents of the dates are considered important maturity attributes. Decision‐making on the harvesting schedule for each section in a plantation of fresh dates (variety Hayani) is one of the major problems for the growers. In order to estimate the optimum harvest time, conventional laboratory methods have been used to assess the maturity of samples of dates; methods which by nature are destructive, manual and time consuming. A semi‐automatic system for maturity determination of fresh dates has been developed, tested and operated. It combines a near infrared (NIR) spectrometer with a step‐wise cell conveyor, both of which are controlled by a PC. The NIR models were based on measuring the water and total soluble solids (TSS) contents. The calibration models and the prediction results had a standard error of prediction (SEP) of 1% for TSS and water contents. The correlation coefficient R between TSS and water contents as predicted by NIR models and as measured in routine laboratory destructive tests was 0.9. The system was capable of testing 100 dates in 3 min. © 1999 Society of Chemical Industry     

国际电工委员会(IEC)百年寄语

今年是国际电工委员会（IEC）为电工电子领域、为世界各国、以及全人类服务的第100个年头。我们将安排许多特殊的活动来纪念百年庆典。     

Effects of rating format on goal-setting dimensions: A field experiment.

Atotal of 10 managers and their 62 subordinates participated in a field experiment that examined the effects of performance appraisal feedback deriving from two rating formats—behavioral observation scales (BOS) and graphic rating scales—on three goal-setting dimensions. Multivariate analyses of variance and a priori t tests revealed, as hypothesized, that the BOS format yielded significantly higher levels of goal clarity, goal acceptance, and goal commitment, the three goal-setting dimensions. Results are discussed in terms of systemic characteristics, that is, a "built-in" focus on specific behaviors, rather than a translation of generic performance dimensions into specific work behaviors. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Proposed thermodynamic method to determine the vortex mass in layered superconductors

We describe a simple method to study vortex dynamics that can determine or set an upper limit on the vortex mass. The specific heat of the vortex lattice in layered superconductors has a classical limit of 1 k_B per pancake vortex if the vortex mass is zero. If the vortex mass m_v is finite, a new Einstein branch of normal modes will appear with a crossover temperature E m_v ^–1, and the specific heat will saturate at a new classical limit of 2 k_B per pancake vortex.This work was supported in part by AFOSR under project F49620-92-C-0004 and by NSF under grant DMR 91-20361. We acknowledge helpful discussions with Shoucheng Zhang and S. R. Patel.     

Decidable fragments of many-sorted logic

Many natural specifications use types. We investigate the decidability of fragments of many-sorted first-order logic. We identified some decidable fragments and illustrated their usefulness by formalizing specifications considered in the literature. Often the intended interpretations of specifications are finite. We prove that the formulas in these fragments are valid iff they are valid over the finite structures. We extend these results to logics that allow a restricted form of transitive closure.     

Reflexive transitive invariant relations: A basis for computing loop functions

Invariant assertions play an important role in the analysis and verification of iterative programs. In this paper, we introduce a related but distinct concept, namely that of invariant relation. While invariant assertions are useful to prove the correctness of a loop with respect to a specification (represented by a precondition/ postcondition pair) in Hoare’s logic, invariant relations are useful to derive the function of the loop in Mills’ logic.     

Biological sensing and interface design in gold island film based localized plasmon transducers

Discontinuous, island-type gold films (typically < or = 10 nm nominal thickness) prepared by evaporation of the metal on transparent substrates show a localized surface plasmon resonance (LSPR) extinction in the visible-to-NIR range and can be used as optical transducers for monitoring local refractive index change. Such transducers, operated in the transmission configuration, provide an effective scheme for label-free biological sensing using basic spectrophotometric equipment. Optimization of the sensitivity of LPSR transducers requires consideration of the distance between the metal island surface and the bound analyte, strongly affecting the optical response due to the fast decay of the evanescent field of localized plasmons. In the present work Au island based LSPR transducers were used to monitor antibody-antigen interactions, demonstrating the effect of the biorecognition interface thickness. Evaporated Au island films derivatized with IgG or hCG antigens were used as biological recognition elements for selective sensing of antibody binding, distinguishing between specific and nonspecific interactions. The LSPR results are supported by XPS and ellipsometry data as well as by AFM and HRSEM imaging, the latter providing actual visualization of the two protein binding steps. Increase of the recognition interface thickness leads to a concomitant decrease in the extinction and wavelength sensitivity, generally conforming to a model of an exponentially decaying surface plasmon (SP) evanescent field.