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D. P. Kiryukhin G. A. Kichigina P. P. Kushch V. G. Kuryavyi V. M. Buznik 《Russian Chemical Bulletin》2013,62(7):1659-1665
The kinetics of radiation telomerization of tetrafluoroethylene in a series of fluorine-containing solvents was studied. A comparative analysis of their reactivity was carried out. The structure and some properties of the telomeres were studied by IR spectroscopy, thermogravimetric and elemental analysis, and electron microscopy. 相似文献
13.
Yu. M. Shul’ga V. N. Vasilets S. A. Baskakov M. A. Smirnov V. P. Tarasov V. I. Volkov G. A. Kichigina P. P. Kushch D. P. Kiryukhin 《High Energy Chemistry》2013,47(6):291-294
By solid-state magic angle-spinning nuclear magnetic resonance spectroscopy (NMR), differential scanning calorimetry (DSC), and IR spectroscopy, polytetrafluoroethylene (PTFE) samples obtained by low-temperature (T = ?196°C) postradiation polymerization of tetrafluoroethylene (C2F4) and C2F4 mixtures with a 3D graphene material formed by the microwave exfoliation of graphite oxide films (MEGO) have been investigated. It has been shown that the melting point of PTFE in the PTFE-MEGO composite is 332.5°C, which is 8.8°C above the melting point of pure PTFE obtained under the same conditions. According to the measured values of specific enthalpy of melting ΔH m (51.5 and 45.4 J/g), the degrees crystallinity (x c) of 0.63 and 0.55 have been calculated for the pure polymer and the composite, respectively. It has been also found that none of the PTFE-containing samples examined has terminal CF3 groups typical of PTFE prepared by conventional suspension polymerization. 相似文献
14.
Kiryukhin D. P. Kichigina G. A. Kushch P. P. Vasilets V. N. Kabachkov E. N. Shulga Yu. M. 《High Energy Chemistry》2022,56(3):184-189
High Energy Chemistry - The influence of monomer concentration on the properties of radiation-synthesized tetrafluoroethylene telomers in perfluoro-1,3-dimethylcyclohexane has been studied by... 相似文献
15.
G. A. Kichigina A. I. Bol’shakov P. P. Kushch D. P. Kiryukhin 《Russian Journal of Applied Chemistry》2014,87(4):518-524
The kinetics of radiation-initiated telomerization of tetrafluoroethylene in a 1,2-dibromotetrafluoroethane solution at a constant concentration (pressure) of the monomer in the reactor was studied. The properties, molecular structure, and morphology of the telomers were studied by IR spectroscopy, scanning electron microscopy, and elemental and thermal gravimetric analyses. The synthesized telomers show promise for the development of fluoropolymeric nanocomposites and protective hydrophobic and antifriction coatings. 相似文献
16.
Kichigina G. A. Kushch P. P. Kiryukhin D. P. 《Russian Journal of Applied Chemistry》2020,93(2):212-218
Russian Journal of Applied Chemistry - Hydrophobization of highly porous heat-shielding ceramic materials based on quartz fibers was studied. Radiation-synthesized tetrafluoroethylene telomers... 相似文献
17.
Kartsovnik MV Grigoriev PD Biberacher W Kushch ND Wyder P 《Physical review letters》2002,89(12):126802
Slow oscillations of the interlayer magnetoresistance observed in the layered organic metal beta-(BEDT-TTF)(2)IBr(2) are shown to originate from the slight warping of its Fermi surface rather than from independent small cyclotron orbits. Unlike the usual Shubnikov-de Haas effect, these oscillations are not affected by the temperature smearing of the Fermi distribution and can therefore become dominant at high enough temperatures. We suggest that the slow oscillations are a general feature of clean quasi-two-dimensional metals and discuss possible applications of the phenomenon. 相似文献
18.
Fixation of platinum from H2PtCl6 on fullerene black through non-conjugate double bonds or hydroxyl groups created on their base in the presence of an organic base with postreduction by formate ions allows platinum particles of size 3–4 nm to be obtained. These compositions catalyze 1-decene and nitrobenzene hydrogenation and exceed in activity the traditional catalyst Pt/C with platinum particle size of 70–80 nm. The average size of the fixed platinum particles affects the catalytic activity stronger than the specific surface area and the electron conduction of the carrying agent. 相似文献
19.
V. I. Kushch 《International Applied Mechanics》1995,31(2):155-159
Institute of Superhard Materials, National Academy of Sciences of Ukraine, Kiev. Translated from Prikladnaya Mekhanika, Vol. 31, No. 2, pp. 86–92, February, 1995. 相似文献
20.
The kinetics of radiation-initiated telomerization of tetrafluoroethylene in dichlorodimethylsilane and chlorotrimethylsilane have been studied, and the molecular structure and properties of the telomers have been revealed. It has been shown that the introduction of ~3.5 wt % product telomer into aluminoborosilicate glass fabric gives a fluorinated glass-reinforced polymer material with good hydrophobicity. 相似文献